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Synthesis, Characterization and ESR Studies of New Copper(II) Complexes of Vicinal Oxime Ligands (Vicinal Oxime 리간드의 새로운 구리(II) 착물에 대한 합성, 특성 및 ESR 연구)

  • El-Tabl, Abdou S.;Shakdofa, Mohamad M.E.;El-Seidy, Ahmed M.A.
    • Journal of the Korean Chemical Society
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    • v.55 no.4
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    • pp.603-611
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    • 2011
  • Ethoxylacetyl oxime ligands [HL, (1) and $H_2L^1$, (3)] react with copper(II) acetate monohydrate yield octahedral and square planar complexes, respectively. The complexes have been postulated due to elemental analyses, IR, UVVis. spectra, magnetic susceptibility, conductivity and ESR spectra. Molar conductance of the complexes in DMF indicates a non-ionic character. The ESR spectra of [$(L)_2Cu(H_2O)_2$], (2) complex at room temperature and 77K are characteristic of an axial symmetry ($d_{x2-y2}$) with covalent bond character and have a large line width typical of dipolar interactions. However, [$(L^1)Cu$], (4) complex in the solid state showed spectra of marked broadening and loss of hyperfine splitting confirming spinexchange interactions between the copper(II) sites. The spectrum of the doped copper(II) complex at room temperature showed super-hyperfine splitting from coordinated nitrogen atoms and it has an axial type ($d_{x2-y2}$) with covalent bond character and an essentially square-planar arrangement around the copper(II) ion. The spectrum of [$(L^1)Cu$], (4) in frozen methanol at 77K was characteristic of the triplet state of a dimer species and the distance found between the two copper(II) centers was calculated and is equal to 4.8 ${\AA}$.

Pattern Recognition Improvement of an Ultrasonic Sensor System Using Neuro-Fuzzy Signal Processing (초음파센서 시스템의 패턴인식 개선을 위한 뉴로퍼지 신호처리)

  • Na, Seung-You;Park, Min-Sang
    • Journal of the Korean Institute of Telematics and Electronics S
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    • v.35S no.12
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    • pp.17-26
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    • 1998
  • Ultrasonic sensors are widely used in various applications due to advantages of low cost, simplicity in construction, mechanical robustness, and little environmental restriction in usage. But for the application of object recognition, ultrasonic sensors exhibit several shortcomings of poor directionality which results in low spatial resolution of objects, and specularity which gives frequent erroneous range readings. The time-of-flight(TOF) method generally used for distance measurement can not distinguish small object patterns of plane, corner or edge. To resolve the problem, an increased number of the sensors in the forms of a linear array or 2-dimensional array of the sensors has been used. Also better resolution has been obtained by shifting the array in several steps using mechanical actuators. Also simple patterns are classified based on analyzing signal reflections. In this paper we propose a method of a sensor array system with improved capability in pattern distinction using electronic circuits accompanying the sensor array, and intelligent algorithm based on neuro-fuzzy processing of data fusion. The circuit changes transmitter output voltages of array elements in several steps. A set of different return signals from neighborhood sensors is manipulated to provide enhanced pattern recognition in the aspects of inclination angle, size and shift as well as distance of objects. The results show improved resolution of the measurements for smaller targets.

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Effect of Flame Radiative Heat Transfer in Horizontal-Type HRSG with Duct Burner (덕트 버너 추가에 따른 수직형 HRSG 내 화염 복사 열전달의 영향에 관한 연구)

  • Kim, Daehee;Kim, Seungjin;Choi, Sangmin;Lee, Bong Jae;Kim, Jinil
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.2
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    • pp.197-204
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    • 2013
  • A method was developed for analyzing the radiation heat transfer from the duct burner flame to the heat exchanger in a heat recovery steam generator (HRSG) in order to supplement the existing thermal design process. The burner flame and the heat exchanger were considered to be imaginary planes, and the flame temperature, surface, and emissivity were simplified using an engineering approach. Three analysis cases in which the duct burner position and fuel were changed were considered. The calculated flame radiative heat transfer and local flux on the heating surface were compared with those of 3-atomic gas radiation and convection. In all analysis cases, heat transfer by 3-atomic gas radiation was very small. The ratio of the flame radiative heat transfer to the convection heat transfer on the heating surface was estimated to be as high as 8-41%. Moreover, the local heat flux on the heating surface centerline was dominated by flame radiative heat flux.

X-Band 6-Way Waveguide Power Divider Using Inductive Post (유도성 포스트를 활용한 X-Band 6-Way 도파관 전력 분배기)

  • Kim, Dong-Hyun;Oh, Soon-Soo;Min, Kyeong-Sik;Kang, Suk-Youb
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.4
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    • pp.417-426
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    • 2010
  • This paper describes the 6-way power divider to be used as a feeding structure of the waveguide array antenna generating the plane wave at the near distance. The SMA connector has been connected at the center of the power divider in order to feed the radiating element. The six output ports made of waveguide are positioned on the peripheral of the divider. This paper proposes the method utilizing the inductive post in order to decrease the return loss. The height of the feeding pin, the diameter of the inductive post, and the distance between the feeding pin and inductive post have been investigated, and as a result, the power divider has been optimized. The simulated and measured results show the low return loss of about -40 dB. The calculated and measured transmission coefficients are -7.78 dB and -8.06 dB, respectively. The output power of the six waveguide port show equal-amplitude and equal-phase distribution. Since the power divider proposed in this paper can be expanded to the divider having several output ports, it could be easily applied to the various array antennas.

A Study of Dual-Frequency Microstrip Patch Antenna (이중공진 마이크로스트립 패치 안테나에 관한 연구)

  • 장준영;김준모;윤영중;엄순영;전순익
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.9 no.4
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    • pp.515-525
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    • 1998
  • In this paper, for both transmission and reception with single antenna system of satellite communication, dual-frequency antennas which operate simultaneously at 12.5 GHz and at 14.25 GHz are designed, constructed and measured. Also by using dual feeding structure, the problems of single-fed dual-frequency antenna such as the separation of transmitting and receiving signals and single polarization, are solved. Microstrip patch as a radiation element of dual-fed dual-frequency antenna has width and length which are the resonance lengths of the corresponding frequencies for transmission and reception, respectively. The effects of the feed line on the other frequency feeding are minimized with the optimal matching scheme for the feed lines. For solving the space problems of dual-fed two-dimensional array antennas, microstrip-line and coaxial probe feedings are used for each frequency and a two-dimensional $2\times2$ array antenna was designed and measured their characteristics. The experimental results show that errors of resonance frequencies are less than 1.44%, the return losses are less than -21 dB and the isolations between two feeding ports are less than -21 dB. The characteristics of radiation patterns of dual frequency microstrip antenna are measured and evaluated. The directivities, sidelobe levels and cross polarizations are also measured and compared with the simulations. The results show some errors due to the misalignment of coaxial probe feeding.

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Fabrication of complete denture using 3D printing: a case report (3D 프린팅을 이용한 양악 총의치 제작 증례)

  • Lee, Eunsu;Park, Chan;Yun, Kwidug;Lim, Hyun-Pil;Park, Sangwon
    • The Journal of Korean Academy of Prosthodontics
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    • v.60 no.2
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    • pp.202-210
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    • 2022
  • Recently with the advance in digital dentistry, the fabrication of dentures using computer-aided design and computer-aided manufacturing (CAD-CAM) is on the rise. The denture designed through a CAD software can be produced in a 3-dimensional manufacturing process. This process includes a subtractive processing method such as milling and an additive processing method such as 3D printing and in which it can be applied efficiently in more complex structures. In this case, complete dentures were fabricated using Stereolithography (SLA)-based 3D printing to shorten the production time and interval of visits in patient with physical disabilities due to cerebral infarction. For definitive impression, the existing interim denture was digitally replicated and used as an individual tray. The definitive impression obtained with polyvinyl siloxane impression material was including information about the inclination and length of the maxillary anterior teeth, vertical dimension, and centric relation. In addition, facial scan data with interim denture was obtained so that it can be used as a reference in determination of the occlusal plane and in arrangement of artificial teeth during laboratory work. Artificial teeth were arranged through a CAD program, and a gingival festooning was performed. The definitive dentures were printed by SLA-based 3D printer using a FDA-approved liquid photocurable resin. The denture showed adequate retention, support, and stability, and results were satisfied functionally and aesthetically.

Fabrication of complete denture using digital technology in patient with mandibular deviation: a case report (하악 편위 환자에서 디지털 방식을 이용한 총의치 제작 증례)

  • Lee, Eunsu;Park, Juyoung;Park, Chan;Yun, Kwi-Dug;Lim, Hyun-Pil;Park, Sangwon
    • Journal of Dental Rehabilitation and Applied Science
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    • v.38 no.1
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    • pp.34-41
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    • 2022
  • Recently, digital technology and computer-aided design/computer-aided manufacturing (CAD/CAM) environment have changed the clinician treatment method in the fabrication of dentures. The denture manufacturing method with CAD/CAM technology simplifies the treatment and laboratory process to reduce the occurrence of errors and provides clinical efficiency and convenience. In this case, complete dentures were fabricated using stereolithography (SLA)-based 3D printing in patient with mandibular deviation. Recording base were produced in a digital model obtained with an intraoral scanner, and after recording a jaw relation in the occlusal rim, a definitive impression was obtained with polyvinyl siloxane impression material. In addition, facial scan data with occlusal rim was obtained so that it can be used as a reference in determination of the occlusal plane and in arrangement of artificial teeth during laboratory work. Artificial teeth were arranged through a CAD program, and a gingival festooning was performed. The definitive dentures were printed by SLA-based 3D printer using a Food and Drug Administration (FDA)-approved liquid photocurable resin. The denture showed adequate retention, support and stability, and results were satisfied functionally and aesthetically.

A Study on Generating Virtual Shot-Gathers from Traffic Noise Data (교통차량진동 자료에 대한 최적 가상공통송신원모음 제작 연구)

  • Woohyun Son;Yunsuk Choi;Seonghyung Jang;Donghoon Lee;Snons Cheong;Yonghwan Joo;Byoung-yeop Kim
    • Geophysics and Geophysical Exploration
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    • v.26 no.4
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    • pp.229-237
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    • 2023
  • The use of artificial sources such as explosives and mechanical vibrations for seismic exploration in urban areas poses challenges, as the vibrations and noise generated can lead to complaints. As an alternative to artificial sources, the surface waves generated by traffic noise can be used to investigate the subsurface properties of urban areas. However, traffic noise takes the form of plane waves moving continuously at a constant speed. To apply existing surface wave processing/inversion techniques to traffic noise, the recorded data need to be transformed into a virtual shot gather format using seismic interferometry. In this study, various seismic interferometry methods were applied to traffic noise data, and the optimal method was derived by comparing the results in the Radon and F-K domains. Additionally, the data acquired using various receiver arrays were processed using seismic interferometry, and the results were compared and analyzed to determine the most optimal receiver array direction for exploration.

Performance Analysis of MC/DS-CDMA System with Smart Antenna (기지국용 스마트 안테나를 적용한 MC/DS-CDMA 시스템의 성능분석)

  • 박인규;김백현;신승훈;곽경섭
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.27 no.4B
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    • pp.291-297
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    • 2002
  • Due to the increasing demand for high data multimedia service, there has been progressing study of adaptive smart antenna to increase both the performance and capacity using limited wireless resource. IS-95 scheme in the origin of cdma2000 of IMT-2000 standard uses signals of spreading and Walsh-Orthogonal Modulation in reverse link. But, in the case of reverse lint there exists difficulty in synchronous of signals transmitted from users. Therefore, orthogonality between users is not satisfied. So, asynchronous MC-CDMA scheme may yield low performance. In this paper, MC/DS-CDMA scheme to reverse link transmission in adaptive array antenna environment is proposed for spreading the S/P-converted data streams using a given spreading code. Due to frequency diversity effect, simulation results show that the proposed system provides improved BER performance and narrow band interference supple psi on.

Design and Fabrication of Aperture-Coupled Microstrip Patch Antenna for WLL Repeater Using Space Diversity (공간 다이버시티를 이용한 WLL 중계기용 적층형 평판 안테나 설계 및 제작)

  • 한봉희;노광현;박노준;강영진
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.27 no.4B
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    • pp.388-396
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    • 2002
  • In this paper, An aperture-coupled microstrip patch antenna operating at WLL frequency range(Rx : 2.3∼2.33Ghz, Tx : 2.37 ∼2.4Ghz) for WLL repeater is designed and fabricated. FR-4 epoxy substrate with 4.7 relative permittivity is inserted between feed-line and patch plane. Aperture-coupled structure is employed for consideration of bandwidth improvement and gain\`s characteristics. Air gap is arranged at each layer for bandwidth extension and radome is used as a protector in the upper patch. In this paper, both 1 port and 2 port are designed as 1$\times$2 array antenna which uses T-junction and λ$\_$g//4 transformer. Here, 1 port is used as transmitting/receiving antenna and 2 port is used as receiving antenna. Functionally independent two antennas using space diversity arrange slots between two antennas in order to be placed at the same place. As a result, we obtained a excellent isolation below -40dB and return loss is reduced by means of slots arrangement between patch and antenna.