• Applied Chemistry for Engineering
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• v.30 no.5
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• pp.597-605
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• 2019

In order to improve the adhesion of water-based adhesive, gemini type nonionic reactive surfactants were synthesized and applied to water-based adhesives. The surfactants were synthesized by using maleic acid and polyoxyethylene cetyl ether having different length of ethylene oxide and confirmed by FT-IR and $^1H-NMR$. Their appearance was light yellow wax. The cloud point of the compound was more than $78^{\circ}C$. The measured critical micelle concentration (c.m.c) was $1.0{\times}10^{-4}{\sim}7.0{\times}10^{-4}mol/L$ and surface tension at c.m.c was 25.9~32.0 mN/m. As the number of ethylene oxide increased, the emulsifying power was improved. The foaming height of each compound by Ross-Miles method was 1.4~4.5 cm. The synthesized surfactants was then used as an emulsifier in emulsion polymerization of water-based adhesives and its physical properties were evaluated. The solid contents of prepared adhesives was 59%. The average particle size and initial tackiness of the prepared adhesives were 164~297 nm and ball no. of 20~32, respectively. The peel strength was $1.8{\sim}2.1kg_f/mm$. The retention rate of adhesives viscosity was evaluated to 99% during 30 days. Therefore, synthesized gemini type nonionic reactive surfactants are expected to be applied as an emulsifier for the high adhesive force.

• Journal of the Korean Magnetics Society
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• v.5 no.6
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• pp.928-936
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• 1995

In this research, the processing control of NiCuZn Ferrite has been developed. The mixing and the size reduction of raw materials have been proceeded. In order to produce NiCuZn Ferrite, highly concentrated slurry with fixed ratio and wet ball milling were used. First, the dispersion behavior of raw mixture at the region of pH4~pH11 has been studied. Using wet ball milling operation, the best conditions of mixing and size reduction have been determined. Further more, the most suitable conditions, such as, dispersant kind, dispersant amount, milling time, and slurry concentration have been studied. The poly acrylic ammonium salt (PAN) was chosen as a suitable dispersant to have effective dispersion in basic region. The slurry of raw mixture without dispersant, showed high viscosity and poor grindability. As 0.7 wt% of PAN was added, the concentrated slurry (up to 55 vol%) was possible, and showed well grindability. After 18 h ball milling of 30 vol% of mixture slurry with 0.7 wt% of PAN, the average particle size and specific surface area of raw mixture were $0.54\mu\textrm{m}$ and $12.92m^{2}/cc$, respectively. The ball milled raw mixture, calcined at $700^{\circ}C$ for 3h, was totally changed into NiCuZn Ferrite with spinel phase.

• Journal of the Korean Magnetics Society
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• v.8 no.6
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• pp.350-356
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• 1998

$Y_{3-x}La_xFe_5O_{12}$ (x=0.0, 0.25, 0.5, 0.75, 1.0) powders and thin films were fabricated by a sol-gel method and their magnetic properties and crystal structure were investigated by using X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and Mossbauer spectroscopy. XRD and Mossbauer spectroscopy measurements show that garnet powders annealed at 900 $^{\circ}C$ for 8 hours were single-phased and that thin films fired at 800 $^{\circ}C$ for 2 hours were crystallized without any preferred direction. X-ray diffraction patterns of $Y_{3-x}La_xFe_5O_{12}$ powders annealed at 1000 $^{\circ}C$ had only peaks of the garnet structure in case of x$\leq$0.75 but those of $Y_2LaFe_5O_{12}$ powders consisted of peaks from garnets and $LaFeO_3$. Mossbauer sepectra of garnet powders grown by the sol-gel method had a similar shape of those of powders grown by a conventional ceramic method. Grain sizes of garnet powders were 200~300 nm and the averaged surface roughness was 3.17 nm. Results of VSM measurements show the powders and thin films had soft magnetic properties and that the garnet powders had the largest saturation magnetization, 30 emu/g, and the lowest coercivity, 52 Oe.

• Applied Chemistry for Engineering
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• v.32 no.5
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• pp.562-568
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• 2021

An O/W (oil in water) emulsion, wheat germ oil raw material, was produced by using natural wheat germ oil and composite sugar-ester. The effects of variables such as the hydrophile-lipophile balance (HLB) value, added emulsifier amount, and emulsification time on the average particle size, emulsification viscosity and ESI of O/W wheat germ oil emulsion were investigated. The parameters of the emulsification process produced by the central composite design model of the response surface methodology (CCD-RSM), which is a reaction surface analysis method, were simulated and optimized. The optimum process conditions obtained from this paper for the production of O/W wheat germ oil emulsion were 8.4, 6.4 wt%, 25.4 min for the HLB value, amount of emulsifier, and emulsion time, respectively. The predicted reaction values by CCD-RSM model under the optimum conditions were 206 nm, 8125 cP, and 98.2% for mean droplet size (MDS), viscosity, and ESI, respectively, based on the emulsion after 7 days. The MDS, viscosity and ESI of the emulsion obtained from actual experiments were 209 nm, 7974 cP and 98.7%, respectively. Therefore, it was possible to design an optimization process for evaluating the stability of the emulsion of wheat germ oil raw material by CCD-RSM.

• Korean Journal of Optics and Photonics
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• v.32 no.4
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• pp.163-171
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• 2021

Conventional white light-emitting diodes (LEDs) for lighting applications consist of blue LEDs and yellow phosphors, the spectrum of which lacks deep red. To improve the color-rendering characteristics of white LEDs, a red quantum-dot film was applied to the diffuser plate of LED lighting. The mean free paths of the quantum dots and the concentration of the TiO₂ particles in the diffuser plate were adjusted to optimize the optical structure of the lighting. The color-rendering index (CRI) was greater than 90 for most conditions, which demonstrates that adoption of the red quantum-dot film is an effective way for improving the color-rendering properties of conventional white LEDs. The angular dispersion of color coordinates could be removed by utilizing the optical cavity formed between the diffuser plate and the reflector on the bottom of the lighting, where multiple passages of the light through the quantum-dot film reduced the differences in optical path length depending on the viewing angle.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.12
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• pp.807-818
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• 2020

In this study, hydrophones using acoustic sensors were used to estimate the amount of bedload discharge in a forested watershed. The reaction characteristics were analyzed through hydrophone flume tests and field tests, and the quantitative bedload discharge was calculated and compared with that measured by a pit sampler. The hydrophone reaction changed the pulse according to the flow rate change, but did not react to standard sand. The pulse was different depending on the particle size and weight, and accordingly, there was a specific channel showing a suitable response. For a hydrophone installed in the field, by using an automatic impact device, the reaction characteristics of each channel were analyzed to confirm normal operation of the sensor and the suitability of the output value of each channel. In addition, a suitable channel was selected for the estimation of bedload discharge. The bedload discharge formula was developed using a hydrophone pulse and the average flow rate, and was compared with the measured data in the pit sampler in the study site. As a result of the study, if a hydrophone is used for monitoring the bedload in forested watersheds, it is considered effective in quantitatively estimating the weight of bedload discharge.

• Journal of the Korean earth science society
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• v.43 no.3
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• pp.386-404
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• 2022

From April 29 to 30, 2011, under the influence of Asian dust originated from Mongolia, a high concentration of Asian dust was observed nationwide for 4 days in Korea. This study investigated the causes and characteristics of and weather conditions associated with Asian dust at high concentrations at its source in Mongolia. For analysis, Asian dust weather data, Asian dust monitoring tower data, satellite data, backward trajectory data, observation data (PM₁₀ and OPC data), and ECMWF reanalysis data were used. In the synoptic analysis, it was observed that the intervals of isobars were densely distributed in the central region of Mongolia and the pressure gradient force was strong. It could be inferenced that Asian dust occurred due to strong winds. The temperature was relatively high, above 10℃, just before the occurrence of Asian dust, and it decreased sharply at the onset of the dust. The relative humidity had a low value of less than approximately 40%. After the occurrence of Asian dust, it increased sharply to over 50% and then showed a tendency to decrease. In the aerosol index shown by the COMS satellite, a high concentration value of over 25 was detected in Inner Mongolia, and it was consistent with the observations made with naked eyes. In the 72-hour backward trajectory, the northwest airflow streamed into Korea, and on May 2, Heuksando showed the highest PM₁₀ concentration of 1,025 ㎍ m^-3(times the average). Especially, in kinematic vertical analysis, it was observed that low pressure on the ground was strengthened by cyclonic relative vorticity developed in the upper layer. Also, the vertical velocity development is considered to have played a major role in the occurrence of high concentration Asian dust.

• Economic and Environmental Geology
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• v.55 no.2
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• pp.197-207
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• 2022

This study investigated spectroscopic exploration of Myeonsan formation, the titanium(Ti) ore hostrock, in Joseon supergroup based on machine learning technique. The mineral composition, Ti concentration, spectral characteristics of Myeonsan and non-Myeonsan formation of Joseon supergroup were analyzed. The Myeonsan formation contains relatively larger quantity of opaque minerals along with quartz and clay minerals. The PXRF analysis revealed that the Ti concentration of Myeosan formation is at least 10 times larger than the other formations with bi-modal distribution. The bi-modal concentration is caused by high Ti concentrated sandy layer and relatively lower Ti concentrated muddy layer. The spectral characteristics of Myeonsan formation is manifested by Fe oxides at near infrared and clay minerals at shortwave infrared bands. The Ti exploration is expected to be more effective on detection of hostrock rather than Ti ore because ilmenite does not have characteristic spectral features. The random-forest machine learning classification detected the Myeonsan fomation at 85% accuracy with overall accuracy of 97%, where spectral features of iron oxides and clay minerals played an important role. It indicates that spectral analysis can detect the Ti host rock effectively, and can contribute for UAV based remote sensing for Ti exploration.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.519-524
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• 2022

Domestic building finishing materials are being evaluated according to KS F 2271 standards according to the notification of the Ministry of Land, Infrastructure and Transport, and this test is evaluated using laboratory animals. In this study, experiments were conducted on highly combustible organic insulation materials such as EPS, urethane, and phenolic foam. The purpose of this study was to analyze the cause of the behavioral suspension of the experimental mice by measuring the average behavioral suspension time of the mice caused by the harmful gas generated when these three types of insulation materials were burned. FTIR analysis and smoke density experiment were performed as a cause analysis method for the behavioral suspension of mice, and the experimental results were analyzed by dividing the causes of behavioral suspension into suffocation by particulate matter and toxic inhalation by gaseous substances. As a result of the test, urethane was evaluated as the most harmful insulation material, and as a result of FTIR analysis and smoke density test as a cause analysis for the gas toxicity test results, it is judged that the behavioral stop of the rats by suffocation is higher than the effect of toxic inhalation. This study is a basic study on the cause analysis of harmful gases, and it will be necessary to prepare the toxicity basis and analyze various materials and gases.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.48 no.1
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• pp.77-85
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• 2022

Retinaldehyde (RA), vitamin A derivative, is an intermediate between retinol and retinoic acid and has an excellent wrinkle improving effect. In this study, Drug-in-cyclodextrin-in-liposome (DCL) was used to enhance the stability and skin penetration of RA. The complex of RA and hydroxypropyl-beta-cyclodextrin (HP-β-CD) was prepared by the freeze-drying method, and the presence or absence of inclusion of retinal was confirmed by UV-Vis spectrometer, FT-IR and SEM images. RA was captured in HP-β-CD about 95.6% on 1 : 15 (w/w). The retinal-HP-β-CD complex was encapsulated in liposomes using a homomixer and microfluidizer, with an average particle size of 215 ± 4.2 nm and a zeta potential of -31.2 ± 0.5 mv. In the evaluation of the degradation stability of RA, degradation rate of RA-HP-β-CD-liposomes in water was 1.8% higher than RA-liposome (5.8%), RA-HP-β-CD complex (9.7%) and RA alone (37.6%). RA cream (0.05% RA) including RA-HP-β-CD-liposomes was prepared for clinical test with wrinkle-improving efficacy and skin dermis denseness evaluated for 2 or 4 weeks. RA cream showed a significant wrinkle improving effect without skin irritation. In conclusion, it was confirmed that the double stabilization technology using the DCL system contribu tes to the effect of improving skin wrinkles by increasing the stabilization of retinal.