Browse > Article
http://dx.doi.org/10.14478/ace.2019.1062

Preparation and Properties of Water-based Adhesive Using Gemini Type Nonionic Reactive Surfactants  

Shin, Hye-Lin (Department of Engineering Chemistry, Chungbuk National University)
Jeong, Noh-Hee (Department of Engineering Chemistry, Chungbuk National University)
Publication Information
Applied Chemistry for Engineering / v.30, no.5, 2019 , pp. 597-605 More about this Journal
Abstract
In order to improve the adhesion of water-based adhesive, gemini type nonionic reactive surfactants were synthesized and applied to water-based adhesives. The surfactants were synthesized by using maleic acid and polyoxyethylene cetyl ether having different length of ethylene oxide and confirmed by FT-IR and $^1H-NMR$. Their appearance was light yellow wax. The cloud point of the compound was more than $78^{\circ}C$. The measured critical micelle concentration (c.m.c) was $1.0{\times}10^{-4}{\sim}7.0{\times}10^{-4}mol/L$ and surface tension at c.m.c was 25.9~32.0 mN/m. As the number of ethylene oxide increased, the emulsifying power was improved. The foaming height of each compound by Ross-Miles method was 1.4~4.5 cm. The synthesized surfactants was then used as an emulsifier in emulsion polymerization of water-based adhesives and its physical properties were evaluated. The solid contents of prepared adhesives was 59%. The average particle size and initial tackiness of the prepared adhesives were 164~297 nm and ball no. of 20~32, respectively. The peel strength was $1.8{\sim}2.1kg_f/mm$. The retention rate of adhesives viscosity was evaluated to 99% during 30 days. Therefore, synthesized gemini type nonionic reactive surfactants are expected to be applied as an emulsifier for the high adhesive force.
Keywords
Water-based adhesive; Gemini type nonionic reactive surfactants; Critical micelle concentration; Solid contents; Peel strength;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
연도 인용수 순위
1 J. Cheon, Technology trend of high functional adhesive material, Adhesion and Interface, 17(2), 72-76 (2016).
2 J. Han, D. Lee, and K. W. Cho, Adhesion science and technology, J. Ind. Eng. Chem., 7(4), 43-58 (2004).
3 H. J. Kim and D. J. Kim, Development trends of pressure sensitive adhesives, J. Ind. Eng. Chem., 5(5), 10-17 (2002).
4 H. Han, Adhesive characteristics of water-paint and silane adhesive mixture, J. Korea Acad. Ind. Coop. Soc., 16(8), 5721-5727 (2015).   DOI
5 W. Choi, H. Kim, K. Cho, D. Lee, and K. Min, The effect of chemical properties of comonomer on adhesion properties of acrylic pressure sensitive adhesives, Polymer (Korea), 31(5), 369-373 (2007).
6 N. Jeong, J. Park, and Y. Kang, Synthesis and characterization of polymerizable acryl's emulsifier to prepare green glue, J. Korean Oil Chem. Soc., 33(1), 51-57 (2016).   DOI
7 S. Song, Y. Kim, and U. Cho, A study on synthesis of starch-acryl pressure sensitive adhesive by soap-free emulsion polymerization, Elastomers and Composites, 44(4), 429-435 (2009).
8 E. Choi, Y. Jeon, J. Lee, and N. Jeong, Synthesis and properties of gemini type's diethylene glycol dicarboxylates, J. Korean Oil Chem. Soc., 27(3), 257-265 (2010).
9 C. Kim, Y. Kim, J. Lee, K. Lee, and K. Koo, Effect of nonionic surfactant type on oil removal from soil, J. Korean Ind. Eng. Chem., 12(1), 88-93 (2001).
10 H.-K. Kwun, H. Hwang, J. Lee, and N. Jeong, Synthesis of reactive surfactant of polyoxyethylene derivatives, J. Ind. Sci. Technol. Inst. (Chungbuk National University, Korea), 21(2), 119-124 (2007).
11 X. Zhong, J. Guo, L. Feng, X. Xu, and D. Zhu, Cationic gemini surfactants based on adamantane: synthesis, surface activity and aggregation properties, Colloids Surf. A, 441, 572-580 (2014).   DOI
12 A. Berthod, S. Tomer, and J. G. Dorsey, Polyoxyethylene alkyl ether nonionic surfactants: Physicochemical properties and use for cholesterol determination in food, Talanta, 55, 69-83 (2001).   DOI
13 W. C. Griffin, Classification of surface active agents by HLB, J. Cosmet. Sci., 1, 311-326 (1949).
14 T. Tamura, Y. Kaneko, and M. Ohyama, Dynamic surface tension and foaming properties of aqueous polyoxyethylene n-dodecyl ether solutions, J. Colloid Interface Sci., 173, 493-499 (1995).   DOI
15 P. H. Elworthy and C. B. Macfarlane, surface activity of a series of synthetic non-ionic detergents, J. Pharm. Pharmacol., 14(S1), T16-131T (1962).   DOI
16 L. Zhen, D. Huang, and R. Li, Ultrasonic-microwave synthesis of polyoxyethylenated stearyl ether maleic acid diester gemini surfactants, Res. Chem. Intermediates, 41(12), 9773-9783 (2015).   DOI
17 J. Yoon, W. Park, J. Park, S. Choi, B. Kim, and S. Oh, A study on the adhesion performance of acrylate using tack rolling ball test, J. Korea Inst. Build. Constr., 18(2), 173-174 (2018).
18 J. Oh, D. Lim, S. Kim, and H. Kim, Environmental friendly adhesives using natural materials, Adhesion and Interface, 9(3), 34-42 (2008).