• Composites Research
• /
• v.13 no.2
• /
• pp.72-80
• /
• 2000

Effect of graphite powder addition on the mechanical properties of carbon fiber reinforced carbon composites (C/C composites) was investigated. Greenbody (G/B) with 0~30wt.% graphite powder addition to phenol resin was prepared and carbonized at $1000^{\circ}C$ to make C/C composites. Flexural strengths of 20wt.% graphite powder additions showed maximum values in the both case of G/B and C/C composites. But, at the graphite addition over 20wt.%, there was negative effect due to the matrix inhomogeneity. Flexural strength of cured resin without graphite Powder was higher than that with graphite. However, flexural strength of carbonized resin with graphite increased three times as much as that of carbonized resin without graphite. Because the addition of graphite powder effects the restraint of shrinkage after carbonization and the deflection of crack path. In Mode II ENF test, energy release rates($G_{II}$) of G/B and C/C composites with the 20w1.% addition of graphite were both increased. But, the addition of graphite was more effective to the increase of $G_{II}$ in C/C composites than that in G/B.

• Korean Journal of Materials Research
• /
• v.6 no.10
• /
• pp.1034-1042
• /
• 1996

본 연구에서는 인산코팅된 것과 되지 않은 OXI-PAN섬유를 사용하여 제조된 무질서 배향의 OXI-PAN/페놀수지 복합재료를 불활성분위기의 여러 열처리온도에서 탄화하였을 때, 섬유표면에 인화합물의 존재 유.무가 복합재료의 물리적특성 및 미세구조 변화에 미치는 영향을 조사하였다. 두 종류 복합재료의 물리적특성 변화를 탄화온도 영향에 대한 섬유와 매트릭스 및 그 계면에서의 미세구조 거동변화와 기공형성의 관점에서 해석하였다. 열처리시 온도상승에 따라 섬유와 매트릭스 계면에서의 화학반응에 의해서 그 구분이 점차 사라지면서 국부적으로 치밀하고 균일한 상을 이루고 있는 것으로 조사되었다. 또한, 탄화 조건에서도 인산코팅은 OXI-PAN 섬유의 직경의 감소를 억제하고 열안정성을 향상시키므로 복합재료의 부피수축률을 줄이고 탄화수율을 증가시키는데도 어느정도 기여할 수 있으리라 판단되었다.

• Polymer(Korea)
• /
• v.26 no.4
• /
• pp.477-482
• /
• 2002

In order to control the micro-pore structure of glassy carbon (GC), an activation agent of KOH was introduced as the glassy carbon was prepared from phenolic resin with a curing agent of phosphoric acid. The yield and properties of GC were investigated as a function of KOH content. Although the GC produced without KOH had nonporous structure except the trace of bubble formation, the GC with KOH had very porous structure. The surface area of GC with KOH increased continuously up to 870 $m^2$/g with the increase of KOH content. The carbonization yield and apparent density measured in water reduced from 40 to 15% and iron 1.5 to 0.9 g/$cm^3$, respectively, and the electrical resistivity increased from $50{\times}10^{-4}$ to $60{\times}10^{-4}$$\Omega$.cm with the increase of KOH content.

• Journal of the Korean Wood Science and Technology
• /
• v.35 no.6
• /
• pp.108-117
• /
• 2007

This research was performed to investigate the feasibility of bamboo as a raw material for the manufacture of plywood. Wood veneer-bamboo zephyr composite boards (WBCB) were manufactured using keruing (Dipterocarpus sp.) veneers and hachiku bamboo (Phyllostacbys nigra var. henonis Stapf) using various adhesives, and the effect of the method and amount of resin spread on the mechanical properties of the composites were investigated. The WBCB manufactured using polymeric isocyanate (PMDI) showed the best mechanical properties, followed by phenol-formaldehyde resin (PF), phenol-melamine-formaldehyde resin, urea-melamine-formaldehyde resin, and urea-formaldehyde resin. However, considering the operation feasibility as well as mechanical properties, PF resin proved to be the appropriate adhesive for the practical purpose. As the amount of resin spread increased, the mechanical properties of 5-ply WBCB with 12 mm thicknesses manufactured using PF resin tended to increase, and more failure occurred at the interface between veneer and bamboo zephyr than at the interface among bamboo zephyrs. This result suggests that penetration of resin into bamboo zephyr could be the important factor. In this research, the appropriate amount of resin amount was $320g/m^2$. 5-ply WBCBs were manufactured using various methods of resin spread but the effect of the methods on the mechanical properties showed no little difference, which meant that the method of resin spread could be chosen considering the manufacturing conditions and operation feasibility.

• Fire Science and Engineering
• /
• v.31 no.1
• /
• pp.42-49
• /
• 2017

The present article reports the tracking characteristics of phenolic resin insulation material due to accelerated degradation. For assessing insulation degradation of the phenolic resin insulation material, experiment samples with equivalent years of 0, 10, 20, 30, and 40 years were produced by conducting accelerated degradation experiments using Arrhenius equation. Subsequently, tracking experiments according to KS C IEC 60112 standard were conducted for the experiment samples that were previously subjected to accelerated degradation. According to the measured results for tracking characteristics of phenolic resin subjected to accelerated degradation, upon dropping of 0.1% ammonium chloride, the risks were shown to increase by 1.38 times for the equivalent life of 10 years; 1.45 times for 20 years; 1.62 times for 30 years; and 1.94 times for 40 years based on the equivalent life of 0 year. Upon dropping of 0.01% ammonium chloride, the risks were shown to increase by 1.39 times for the equivalent life of 10 years; 1.52 times for 20 years; 1.99 times for 30 years; and 5.30 times for 40 years. According to the experimental results, the tracking risk was shown to be higher for longer-duration insulation degradation due to aging. In particular, the risk was observed to be greatly increased in the case of the equivalent life of 40 years. Therefore, it is proposed that the occurrence possibility and the risk of electric fires could be minimized through institutional preparation of recommended replacement period by considering risks such as insulation degradation, etc. due to aging.

• Polymer(Korea)
• /
• v.24 no.1
• /
• pp.97-104
• /
• 2000

PAN-based activated carbon fibers/phenolic resin matrix composites (ACFCs) were manufactured via molding process with oxidized carbon fabrics (plain-type) and phenolic resin (resole-type) compounded by 70 : 30 wt%. The green body (as molded) was submitted to carbonization (at 100$0^{\circ}C$) in an inert environment and activation (at 700, 800, 900 and 100$0^{\circ}C$) in a $CO_2$ environment. In this work, the influence of activation temperatures was investigated in surface properties, such as pH, acid- and base-values by titration method, and in adsorption properties, i.e., specific surface area and pore structures by BET-method of the composites. Also, the pressure drops of the specimens were calibrated by ASTM. As a result, the activation temperature influenced the surface property of ACFCs. When the activation temperature was higher than 90$0^{\circ}C$, the surface was gradually developed in basic nature. And, the evolutions of specific surface area, total pore volume and pore size distribution of ACFCs could be easily confirmed the dependence on the activation temperature. Among them, well-developed pore structure from adsorption characteristics was changed of the ACFCs activated at 90$0^{\circ}C$. Also, the pressure drop was slightly decreased with increasing the temperature due to increasing the burn-off with heat treatment temperature of ACFCs.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.32 no.3
• /
• pp.89-95
• /
• 2022

In this study, glassy carbon coating was performed on the graphite using a phenolic resin and a curing agent was mixed with ethylene glycol as an additive to form the uniform surface. The phenolic resin was dried and cured under the environments of hot air, then converted into a glassy carbon layer by pyrolysis at 500~1,500℃. FTIR, XRD, SEM analysis, and density/porosity/contact angle measurement were performed for characterization of glassy carbon. The pyrolysis temperature for high-quality glassy carbon was optimized to be about 1,000℃. As the content of the additive increased, the effect of reducing surface defects on the coated surface, reduction of porosity, increase of contact angle, and increase of density were investigated in this study. The method of forming a glassy carbon coating layer through an additive is expected to be applicable to graphite coating and other fields.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.23 no.2
• /
• pp.161-167
• /
• 2009

Organic insulating materials which are utilized as insulating materials for the low voltage show unique carbonization characteristics when they are carbonized by a leakage current. Therefore the use of the carbonization characteristics makes it possible to examine the electrical fire which is caused by a leakage current flowing on the surface of the organic insulating material. In order to understand such carbonization characteristics, in this paper, experiments have been done to carbonize typical organic insulating materials such as phenol resin, PVC, and acrylic resin, and the carbonization patterns and the IR absorption spectrum of specimens have been analyzed. According to the analysis of the carbonization patterns, the phenol resin shows the so-called 'spider-leg' carbonization pattern due to a thermosetting property. In contrast to the phenol resin, the thermoplastic property makes it difficult to observe a clear carbonization pattern to verify carbonizing causes on the surfaces of PVC and acrylic resins. In this case, the IR absorption spectrum can be analyzed to examine the specimen carbonized by a leakage current. The analysis result shows that absorption peaks appear at the wave numbers of $3,400[cm^{-1}]$ and $1,618[cm^{-1}]$, which can be an important factor to verify the carbonizing causes.

• The tire
• /
• s.3
• /
• pp.23-27
• /
• 1967

• Korean Chemical Engineering Research
• /
• v.51 no.2
• /
• pp.279-284
• /
• 2013

The phenolic beads in macrosize range were obtained by suspension polymerization at $98^{\circ}C$ from phenol and formaldehyde in the presence of basic catalyst with a phenol to formaldehyde (P/F) range of 1:1~1:4, and they were carbonized to spherical carbon beads under nitrogen at $700^{\circ}C$. Thermal analysis on spherical phenolic beads obtained by suspension polymerization showed that the postcuring process is essential. In order to optimize the suspension polymerization, the effects of the P/F molar ratio, the pH of catalyst, and the molecular weight of stabilizer on the size distribution and yield of spherical phenol beads were examined separatively. The particle size was increased whereas the yield was decreased with P/F molar ratio. The increasing basicity of catalyst made the particle size to increase, while the molecular weight of stabilizer had more effect on the yield rather than on the particle size distribution. The thermal stability of the spherical phenolic beads obtained through postcure was also examined by TGA. The phenol beads of high P/F ratio still showed the weight loss at $220^{\circ}C$ even after postcure due to the high possibility of dibenzyl ether, while those of low P/F ratio showed the steady decrease in weight during $220^{\circ}C$ to $400^{\circ}C$, which showed that the optimal P/F ratio was 1:2.