• Journal of the Korean GEO-environmental Society
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• v.12 no.9
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• pp.63-69
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• 2011

The objective of this study is to investigate the change of physicochemical properties of humic acid, surfactants and water by pulsed electric field treatment. Critical micelle concentration(CMC) of surfactants and physicochemical properties of water were determined by the conductivity measurement, FT-IR and NMR, respectively. In electric field processing, structural changes of C-N complex and C=O were founded by FT-IR analysis. The increase of Hertz wave was in the range of 2.3 to 9.9 Hz in NMR analysis. CMC of cation and anion surfactant decreased to 1.3% and 9.2%, respectively, while the value of UV-vis increased. UV-vis of humic acid decreased by pulsed electric field. Therefore, application of pulsed electric field systeme was directly indicated to influence the physicochemical properties of water and organic compounds.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.6
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• pp.861-867
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• 2011

Wastewater from crude oil reserve base usually contains large amount of non-biodegradable contaminants. The conventional wastewater treatment progress can hardly meet the regulation of wastewater effluent quality. This study investigated the removal of non-biodegradable organic contaminants in wastewater from crude oil reserve base using a pulse UV treatment. The modified process incorporating pulse UV process was set up to treat the wastewater from crude oil reserve base. The treatment process is composed with coagulation and flocculation, micro-bubble flotation, sand filter, pulse UV system, and GAC filter. The results show CODMn was effectively removed by the process with pulse UV system and it can meet the wastewater effluent regulation. The single effect of pulse UV process in CODMn removal was not significant(9~15% based on sand filtered effluent), however with the subsequent activated carbon filter the removal ratio CODMn was increased up to 28% compared to the process without pulse UV syetem.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.2
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• pp.219-228
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• 2012

Problems due to the taste and odor in drinking water are common in treatment facilities around the world. Taste and odor are perceived by the public as the primary indicators of the safely and acceptability of drinking water, and are mainly caused by the presence of two semi-volatile compounds-2-methylisoborneol(2-MIB) and geosmin. Conventional treatment processes in water treatment plants, such as coagulation, sedimentation and chlorination have been found to be ineffective for the removal of 2-MIB and geosmin. Pulse UV system is a new UV irradiation system that is a non-mercury lamp-based alternative to currently used continuous wave systems for water disinfection. This study shows pulse UV system to be effective in treatment of these two compounds. Geosmin removal efficiency of UV process alone achieved approximately 70% at 10sec contact time. 2-MIB removal efficiency of UV only process achieved approximately 60% at 10sec contact time. The addition of $H_{2}O_{2}$ 7mg/L increased geosmin and 2-MIB removal efficiency upto approximately 94% and 91%, respectively.

• Korean Journal of Optics and Photonics
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• v.12 no.3
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• pp.219-224
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• 2001

Spectral phase interferometry for direct electric-field reconstruction (SPIDER) was fabricated and used to characterize pulses from a Ti:sapphire oscillator. In the SPIDER apparatus, two replicas of the input pulse were generated with a time delay of 200 fs and were upconverted by use of sum-frequency generation with a strongly chirped pulse using a 8-cm-long SFIO glass block at a 30-11m-thick type II BBO (p-BaBz04) crystal. The resulting interferogram was recorded with a UV-enhanced CCD array in the spectrometer. The spectral phase was retrieved by SPIDER algorithm in combination with independently measured pulse spectrum and the corresponding temporal intensity profile was reconstructed with a duration of 19 fs. As an independent cross-check of the accuracy of the method, we compared the interferometric autocorrelation (lAC) signal calculated from the SPIDER data with a separately measured lAC. The conventional, but unjustified, method of fitting a sechz pulse to the autocorrelation deceivingly yielded a pulse duration of 15 fs. This systematic underestimation of the pulse duration affirms the need for a complete characterization method. From the consideration in this paper, we concluded that the SPIDER could provide an accurate characterization of femtosecond pulses. ulses.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.45 no.5
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• pp.44-51
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• 2008

UV lamp systems have been used for cleaning of display panels of TFT LCD or Plasma Display Panel (PDP). However, the needs for high efficient cleaning and low cost made high voltage plasma cleaning techniques to be developed and to be improved. Dielectric-Barrier Discharges (DBDs), also referred to as barrier discharges or silent discharges have been exclusively related to ozone generation for a long time. In this paper, a 6kW high voltage plasma power supply system was developed for LCD cleaning. The 3-phase input voltage is rectified and then inverter system is used to make a high frequency pulse train, which is rectified after passing through a high-power transformer. Finally, hi-directional high voltage pulse switching circuits are used to generate the high voltage plasma. Some experimental results showed the usefulness of atmospheric plasma for LCD panel cleaning.

• Korean Journal of Food Science and Technology
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• v.31 no.2
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• pp.368-374
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• 1999

This study was designed to investigate effects of pulsed electric field (PEF) treatment on physiological changes of microbial cells, using domestically fabricated pilot scale PEF device. The effect of non-thermal PEF treatment on physiological characteristics of microorganisms was determined by salt resistance, the amount of UV absorbents, cell staining, recovery rate of defected cells, and changes in structure of cell membrane. Salt resistance of Escherichia coli, Bacillus subtilis and Rhodotorula minuta was examined after PEF treatment at 40 kV/cm, 84 pulse, $10{\mu}s$ pulse duration. Approximately $1\;log_{10}$ cell number of viable microorganisms was decreased by addition of salt. PEF treatment significantly increased the amount of UV absorbents at 260 and 280 nm because of leakage from damaged cell membrane by PEF treatment. Although three kinds of microorganisms treated by PEF were difficult to be observed due to their cell membrane damage, untreated cells were clearly observed by a microscope. PEF-treated R. minuta was not stained by methylene blue due to cell membrane defect. When E. coli, B. subtilis and R. minuta were cultured after PEF treatment, they showed 5, 4, and 8 hr longer lag phase, respectively, compared to control, but growth rates were not affected.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.390-390
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• 2011

급속한 산업의 발달은 심각한 환경오염 및 에너지 문제를 가져왔다. 이를 해결하기 위하여 무한한 에너지원인 태양에너지를 원천으로 하는 친환경 정화소재로서의 광촉매(photocatalyst)를 통하여 인류의 에너지를 확보하는 것에 대한 관심이 급격하게 증가하고 있는 추세이다. 현재 광촉매로 가장 많이 사용되는 $TiO_2$의 경우 뛰어난 광활성에도 불구하고, 상대적으로 넓은 밴드갭(band gap) 으로 인한 가시광 응답성의 부재로 이를 해결하기 위한 많은 연구가 진행되고 있다. 따라서 본 연구에서는 PIII&D (plasma immersion ion implantation & deposition) 장비를 통하여 -60 kV의 펄스 고전압을 인가해 $TiO_2$에 좁은 band gap을 갖는 반도체를 이온주입하여 가시광 응답성을 갖는 양자점 감응(Quantum dot sensitized)형 광촉매를 제작하였다. 이온주입 후 시료의 chemical state와 crystallinity를 확인하기 위하여 X-ray photoelectron spectroscopy와 X-ray diffraction measurement를 이용하여 분석을 수행하였으며, 이러한 공정을 통해 제작된 양자점 감응형 광촉매의 가시광 응답성을 확인하기 위하여 UV/Vis 스펙트럼을 측정하였다. 또한 광촉매의 효율을 확인하기 위해 물 분해 장치(water splitting device) 를 제작하여 수소와 산소를 생성하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.122-122
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• 2014

수중방전을 환경분야에 적용하기 위한 플라즈마 부상법이 개발되었다. 플라즈마 부상법은 물 속에서 발생시킨 플라즈마가 가지고 있는 주요특성 중 물리적 특징인 쇼크웨이브, UV조사, 버블생성 등과 화학적 특징인 OH라디칼 및 염소산화물 생성 등을 이용하여 물 속에 존재하는 용존성 및 입자성 물질을 부상분리 기법으로 제거하는 공법이다. 유기물을 제거하는 기작으로는 침전, 여과, 분해 등이 있고, 이를 구현하기 위한 공정으로 중력침강법, 부상분리법, 멤브레인법, 미생물법 등이 있다. 이 중에서 가압공기부상법은 침강법에 비해 부지면적을 적게 소모하고 처리시간이 50% 이상 감소되는 특징이 있다. 가압공기부상법은 물 속에 공기를 과포화시킨 후 노즐을 통해 재분사할 때 발생하는 압력차에 의해 미세기포가 발생함을 이용하여 유기물을 분리하는 공법이다. 그러나, 가압용 장비 및 반송수가 필요하고, 미생물분리는 불가능한 단점이 있다. 이에 본 연구에서는 미생물살균과 유기물 분리가 동시에 일어나는 플라즈마를 이용한 부상분리기법을 개발하였다. 본 연구에서는 난분해성 용존유기물인 휴믹산 100 mg/L의 플라즈마 공기부상법에 의한 제거능을 확인하였다. 용존성 휴믹산을 입자성 물질로 전환하여 플록을 형성시키고자 알루미늄설페이트(Al2(SO4) $3{\cdot}18H2O$)를 100 mg/L 주입하였고, 침출수와 같이 염도가 높은 물을 모사하고자 35 g/L의 염화나트륨을 첨가한 상태에서 방전을 실시하였다. 방전에 사용된 전원은 EESYS사에서 제작한 펄스형 고전압 전원장치를 사용하였고 최대 15 kW의 출력 중 6 kW의 전력을 인가하였다. 전극 한 개는 2 mm 텅스텐봉을 세라믹튜브로 감싼 구조로 총 사용전극은 28개이다. 전극 한 개당 대략 200 Watt의 전력이 소모되며 이 때 최대의 버블이 생성됨을 확인하였다. 전극 1개에서 생성되는 버블의 부피는 14 mL/min 로 측정되었다. 버블의 크기는 평균 70 um이고 가압공기부상법에서 최적공기크기로 제시하고 있는 40~80 um 의 버블은 약 80% 가량 생성된다. 본 연구에서 사용된 반응시스템에서의 물의 높이는 약 500 mm 이고 전체 40 L의 수조가 3개의 벽으로 분리되어 4개의 수조로 분리되었다. 각 수조는 하부에 7개의 전극을 포함하고 있다. 플라즈마 발생시 생성되는 기포는 약 1분 방전 후에 포화농도에 도달하며 방전종료 후 약 4분간 수체 내에 남아있게 된다. 이를 공정에 적용하여 1분 방전 및 4분 휴지의 순서로 플라즈마를 인가하였다. 휴믹산 용액의 유량을 2 lpm 으로 운전하였을 때 최종 처리율은 94% 이고 이때의 대장균 살균능은 99%이다.