• Title/Summary/Keyword: 팽창물질

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Preparation and Properties of CSA Type Expansive Cement Using Industrial By-products (산업부산물을 이용한 CSA계 팽창시멘트의 제조 및 특성)

  • 송종택;조진상;전준영
    • Journal of the Korean Ceramic Society
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    • v.38 no.2
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    • pp.183-192
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    • 2001
  • 산업부산물을 이용하여 3CaO.3Al$_2$O$_3$.CaSO$_4$(C$_4$A$_3$S) 클링커를 합성하였다. 이때, 원료 물질은 산업부산물로 플라이 애쉬, 고로 수쇄 및 괴재슬래그를 $Al_2$O$_3$원으로 그리고 부산석고를 SO$_3$원으로 이용하였으며, CaO원으로 천연석회석을 사용하였다. 제조된 $C_4$A$_3$S 클링커를 CaSO$_4$, CaO를 배합하여 CSA계 팽창재를 제조하였으며, 일반 포틀랜드 시멘트(OPC)에 10 wt.% 첨가하여 수화 및 물성 특성을 조사하였다. 주요 수화생성상은 에트링자이트 및 수산화칼슘이었다. 수화시 에트링자이트의 생성으로 인해 팽창 및 경화체가 치밀화되어 건조수축이 감소되었고, 강도(압출, 인장, 휨)가 향상되었다.

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Analysis of Pressure Rise in Gas Circuit Breakers Considering Nozzle Ablation (노즐용삭을 고려한 초고압 가스차단기의 압력상승 해석)

  • Kim H.K.;Song K.D.;Park K.Y.;Bae C.Y.;Jung H.K.;Park S.K.;Lee B.H.
    • Proceedings of the KIEE Conference
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    • summer
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    • pp.1100-1102
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    • 2004
  • 열팽창 방식의 가스차단기는 아크 에너지 자체를 이용하여 압력상승을 얻고, 상승된 압력을 이용하여 전류 영점 부근에서 아크 방향으로의 유동을 형성하여 아크를 소호한다. 대전류 구간에서 노즐 폐색현상이 일어나면 노즐 용삭이 크게 일어나며 용삭된 노즐 물질은 팽창실의 압력과 온도를 상승시키게 된다. 따라서 차단 특성해석을 위해서는 노즐 용삭에 의한 압력 상승해석이 필요하다. 본 논문에서는 아크에너지에 따른 노즐 용삭비를 이용하여 용삭되는 노즐량을 계산하고, 이로 인한 back flow현상을 고려한 해석 방법을 제안한다. 개발된 프로그램을 제작한 차단부 모델에 적용한 결과, 열팽창실의 압력상승치는 시험결과와 잘 일치함을 확인하였다.

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Transfer Characteristics of Porous Metallic Salt-Expanded Graphite Reactive Media (금속염-팽창흑연 다공성 반응매체의 전달특성)

  • 한종훈;김상욱;이건홍
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.207-212
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    • 1999
  • 화학반응이 일어나는 고정층 반응기의 성능을 모사하고 해석하기 위해서는 반응베드의 열 및 물질전달 특성을 정확히 아는 것이 중요하다. 본 연구에서는 화학열펌프에 사용되는 금속염-팽창흑연 다공성 반응매체의 유효열전도도와 기체투과도를 측정하였다. 유효열전도도는 전이 일차원 열류기법을 이용하여 측정하였고, 기체투과도는 Darcy's law를 이용하여 측정하였다. 팽창흑연이 함유된 반응베드의 유효열전도도와 기체투과도는 흑연을 기준으로 한 겉보기밀도에 따라 각각 14.1-36.5 W/mK, 8.0x$10^{-15}$-$10^{-12}$ $m^2$의 범위에 있었다.

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Effect of Nitrogen Injection Pressure on Lqiufied Engine Performance (질소 분사 압력이 액화질소 엔진의 성능 특성에 미치는 영향)

  • Shin, Donggil
    • Journal of Energy Engineering
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    • v.26 no.1
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    • pp.28-33
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    • 2017
  • A liquid nitrogen engine is a highly clean power engine, which does not emit any hazardous substances in its fumes. Additionally, it has an advantage over electric vehicles, as its energy density is larger than that of a battery. The use of an existing liquid nitrogen engine is typically limited to the reciprocation type. In this study, the concept of a nitrogen engine equipped with a scroll expander is introduced. The engine's efficiency was shown to increase when the scroll expander was utilized in the engine, while also adding to the simplification of the structure. Therefore, compared to the existing reciprocation-type engine, the engine with the scroll expander has the potential to be both technically and economically more competitive. In this study, the performance of a liquid nitrogen engine equipped with a scroll expander was analyzed while altering the injection pressure profile of liquid nitrogen.

Study on Sebsea Pipeline Thermal Expansion (해저송유관의 열팽창 고찰)

  • 조철희;홍성근
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.11 no.1
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    • pp.1-6
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    • 1999
  • Nearshore and offshore pipelines are often applied to carry oil, gas, water and combined products. The thermal and pressure gradients of the fluid inside pipeline cause pipeline expansion. This expansion produces stress to connecting structures with pipeline. Should this stress exceeds the yield strength of connecting components or the allowable displacement of the system, a damage can occur. As most pipelines contain hazardous and toxic fluids, the damage usually leads to fatal accidents involving great economic loss as well. Even subsea pipelines can be easily applied to transport liquid type fluid without time and space constraint, they should be designed and maintained carefully to be functional safely during design lifetime. In this paper, various theories estimating pipeline thermal expansion are investigated and the effects of pipe components to expansion are studied.

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A Study on the Reactivity Effect due to Expansion of Diagrid and Pad (Diagram와 Pad의 팽창에 의한 반응도 효과에 대한 연구)

  • Young In Kim;Keun Bae Oh;Kun Jong Yoo;Mann Cho
    • Nuclear Engineering and Technology
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    • v.16 no.2
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    • pp.70-79
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    • 1984
  • With the help of the nuclear computational system for a large LMFBR (KAERI-26 group cross section library/1DX/2DB), the reactivity coefficients for the diagrid expansion and the pad expansion at the beginning of cycle of the equilibrium core of SUPER-PHENIX I are calculated and reviewed. the core is described using R-Z geometry model, and a two-dimensional multigroup diffusion theory is used. For reference cases, reactivity calculations for radial and axial uniform expansion are performed, and also calculated are reactivity variations due to changes in material density and core volume. The reactivity coefficient for the diagrid expansion is calculated to be -0.553pcm/mil. The temperature coefficient corresponding to the above value is -1.0766pcm/$^{\circ}C$ and is well in accord with the French datum of -1.09pcm/$^{\circ}C$ within 1.2% difference. With the use of 4he calculational method for the diagrid expansion effect, reactivity calculations for the pad expansion bringing about nonuniform expansion are performed, which show that the calculational method is very useful in the analysis of the pad expansion effect. The reactivity coefficients for the pad expansion are calculated to be -0.2743 pcm/mil and -0.2786pcm1mi1 for the averaged expansion model and for the integrated pancake model, respectively. Under the assumption of the free expanding core the temperature reactivity coefficients for each model are obtained to be -0.5766pcm/$^{\circ}C$ and -0.5858pcm/$^{\circ}C$, both of which agree with the French datum of -0.574pcm/$^{\circ}C$ within 2% difference.

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급팽창 금속혼합물(REMM)과 그 반응촉발장치를 이용한 파암공법의 설계 및 시공방법에 관한 연구

  • Kim Il-Jung;Kim Young-Geun
    • Proceedings of the KSEE Conference
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    • 2004.08a
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    • pp.127-149
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    • 2004
  • 건설교통부 표준발파패턴 중 암파쇄굴착공법(pattern-1)에 해당하는 구간에서 적용할 수 있는 공법중의 하나로서 새로운 물질과 반응촉발장치를 이용하는 파암공법이다. 본 공법에 대한 이해를 돕기 위해 새로운 물질의 특성시험, 파암진동과 발파진동과의 비교 고찰하고, 각종 화약류와의 폭발소음을 비교분석 하였으며, 본 공법을 파암현장에 적용함에 있어 암질에 따른 설계기법 및 시공방법 등에 대해 연구하였다.

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Fabrication and Characteristics of Diesel Particulate Filters (I) (Diesel Particulate Filter의 특성 및 제조방법 (I))

  • Yang, Jin
    • Membrane Journal
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    • v.8 no.3
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    • pp.117-129
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    • 1998
  • The atmospheric pollution by diesel emission is mainly attributed to particulate matters and NO$_x$. Their regulation limits have become tighter. This paper reviews the characteristics and the fabrication method of the diesd particulate filter(DPF) which is used to control the particulate matters of diesel emission. First the constituent of particulate matters and the regulation standard are discussed and then the state of the art post-treatment system is reviewed. The materials, the fabrication method and the control of thermal expansion of the ceramic honeycomb filter, which is widely used as the DPF, are also reviewed.

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Resistance of Chloride Penetration into High Strength Concrete Containing Mineral Admixtures according to Curing Conditions (광물질혼화재 혼합 고강도콘크리트의 양생조건에 따른 염화물이온 침투저항성)

  • Moon, Han-Young;Kim, Byoung-Kwon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.2
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    • pp.185-194
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    • 2004
  • In recent years, construction company makes inroads into the world construction market, and receives the order of extra-large concrete structure under marine environment in south-east asia specially. At this point of time, to enhance the quality of concrete, we research the High Strength Concrete (HSC) containing mineral admixtures. In this study, therefore, HSC with various combination of ordinary portland cement(OPC), blast-furnace slag(SG), silica fume(SF), and expansion admixture(SS) are cured 23 and $35^{\circ}C$ considering the site weather, and are cured in water for 3, 7 or 56 days respectively. Test results show that the HSC cured at $35^{\circ}C$ gains higher early-age strength but eventually gains lower later-age strength compare with the HSC cured at $23^{\circ}C$. Especially, HSC with combination of OPC+SG+SF+SS or OPC+SG+SF show very excellent resistance of chloride penetration. The permeability of HSC was therefore enhanced as because of containing the proper content of SG, SF, and SS and making dense micro-structure of HSC.

Preparation and Electrochemical Characterization of Si/C/CNF Anode Material for Lithium ion Battery Using Rotary Kiln Reactor (회전킬른반응기를 이용한 리튬이온전지용 Si/C/CNF 음극활물질의 제조 및 전기화학적 특성 조사)

  • Jeon, Do-Man;Na, Byung-Ki;Rhee, Young-Woo
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.901-908
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    • 2018
  • Graphite is used as a sample anode active material. However, since the maximum theoretical capacity is limited to $372mA\;h\;g^{-1}$, a new anode active material is required for the development of a high capacity lithium ion battery. The maximum theoretical capacity of Si is $4200mA\;h\;g^{-1}$, which is higher than that of graphite. However, it is not suitable for direct application to the anode active material because it has a volume expansion of 400%. In order to minimize the decrease of the discharge capacity due to the volume expansion, the Si was pulverized by the dry method to reduce the mechanical stress and the volume change of the reaction phase, and the change of the volume was suppressed by coating the carbon layers to the particle size controlled Si particles. And carbon fiber is grown like a thread on the particle surface to control secondary volume expansion and improve electrical conductivity. The physical and chemical properties of the materials were measured by XRD, SEM and TEM, and their electrochemical properties were evaluated. In this study, we have investigated the synthesis method that can be used as anode active material by improving cycle characteristics of Si.