• Journal of the Korean Chemical Society
• /
• v.46 no.3
• /
• pp.187-193
• /
• 2002

The reaction rates of substituted 6-chloroquinoline with p-substituted benzoyichorides $p-CH_3,$ p-H, $p-NO_2$ have been measured by conductometry in acetonitrile, and the constants are determined at various temperatures (10, 15, 20, $25^{\circ}C$) and pressures (1, 200, 500, 1000 bar). From the values of rate constants, the activation parameters (Ea, ${\Delta}V^{\neq}$, ${\Delta}H^{\neq}$, ${\Delta}S^{\neq}$, ${\Delta}G^{\neq}$) and the pressure dependence of Hammett p values were determined. The rate constants increased with increasing temperatures and pressures, and are further increased to introduction to the electron donor substiuents in substrate $(p-NO_2)$ with 6-chloroqinoline. When the activation volume and the activation entropy are all negative And the Hammett p values are positive for the substrate over the pressure and temperature range studied. The results of kinetic studies for pressure and substituent show that thease reactions proceed in typical $S_N2$ reaction mechanism and "associative $S_N2$" in bond formation favored with increasing pressures.

• Journal of the Microelectronics and Packaging Society
• /
• v.15 no.3
• /
• pp.53-58
• /
• 2008

In this study, we fabricated embedded IC (Double Pole Double throw switch chip) polymer substrate and evaluate it for 2.4 GHz WiFi application. The switch chips were laminated using FR4 and ABF(Ajinomoto build up film) as dielectric layer. The embedded DPDT chip substrate were interconnected by laser via and Cu pattern plating process. DSC(Differenntial Scanning Calorimetry) analysis and SEM image was employed to calculate the amount of curing and examine surface roughness for optimization of chip embedding process. ABF showed maximum peel strength with Cu layer when the procuring was $80\sim90%$ completed and DPDT chip was laminated in a polymer substrate without void. An embedded chip substrate and wire-bonded chip on substrate were designed and fabricated. The characteristics of two modules were measured by s-parameters (S11; return loss and S21; insertion loss). Insertion loss is less than 0.55 dB in two presented embedded chip board and wire-bonded chip board. Return loss of an embedded chip board is better than 25 dB up to 6 GHz frequency range, whereas return loss of wire-bonding chip board is worse than 20 dB above 2.4 GHz frequency.

• Journal of the Institute of Electronics Engineers of Korea SC
• /
• v.42 no.5 s.305
• /
• pp.27-34
• /
• 2005

Ventricular fibrillation(VF) is generally caused by chaotic behavior of electrical propagation in heart and may result in sudden cardiac death. In this study, we proposed a ventricular fibrillation detection algorithm based on support vector machine classifier, which could offer benefits to reduce the teaming costs as well as good classification performance. Before the extraction of input features, raw ECG signal was applied to preprocessing procedures, as like wavelet transform based bandpass filtering, R peak detection and segment assignment for feature extraction. We selected input features which of some are related to the rhythm information and of others are related to wavelet coefficients that could describe the morphology of ventricular fibrillation well. Parameters for SVM classifier, C and ${\alpha}$, were chosen as 10 and 1 respectively by trial and error experiments. Each average performance for normal sinus rhythm ventricular tachycardia and VF, was 98.39%, 96.92% and 99.88%. And, when the VF detection performance of SVM classifier was compared to that of multi-layer perceptron and fuzzy inference methods, it showed similar or higher values. Consequently, we could find that the proposed input features and SVM classifier would one of the most useful algorithm for VF detection.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.7 no.1
• /
• pp.141-150
• /
• 1987

The Soyanggang Dam completed in 1973 was well instrumented during construction period. The measured results for stresses and movements of the embankment have already been published elsewhere, but theoretical analyses have not been made until now. This study intends to analyze the stress and deformation behavior of the embankment numerically which have been subjected to the load of materials during construction and water load during impounding. The constitutive law used for the analyses is hyperbolic model developed by Duncan et al., and a nonlinear incremental finite element analysis simulating its contruction steps is. used in this study. Hyperbolic parameters for each Zone are estimated from literature. The results obtained from the theoretical analyses clearly show deformation characteristics and stress vectors in arbitrary section of the dam. The analytical results ate well agreed with the measured deformations at the maximum cross section, however, there are some discrepancy in horizontal movements and in stresses generated in the core zone. From the numerical analyses and its comparison with the measured values, it is charaterized that relatively large construction settlements occurred in core zone, overburden pressure in the core zone was considerably reduced by arching effect, and tension zones might occur near both abutments because of the large horizontal displacement.

• Journal of the KSME
• /
• v.27 no.6
• /
• pp.504-514
• /
• 1987

복잡한 전자부품의 조립시에 필요한 열적 디자인에 관한 정보는 오래전부터 실험을 통하여 얻어지고 있다. 실험적 데이터를 이용하여 무차원 파라미터로 표시된 실험결과는 꼭 같지는 않지만 현상적으로는 비슷한 상황에 응용될 수 있다. 여기서는 학술문헌에 나타나 있는 자연대류에 관한 실험적인 상관관계식들과 프레임에 수직으로 꽂혀있는 균일가열 전자회로기판의 모델에서 얻어진 무차원 자료들을 비교하고자 한다. 대부분의 자료들은 수정채널 Rayleigh수(Ra")가 15~100범위에 속하며, 이러한 범위는 부품이 조밀하게 배치된 기관이 서로 좁은 채널을 이루고 있으며, 동시에 상당한 전력을 소비하고 있는 경우에 해당한다. Wirt와 Stutzman, Bar-Cohen과 Rohsenow의 일반상관관계식은 AT'||'&'||'T Bell 연구소에서 개발된 전자기기를 이용하여 수집한 실험데이터를 잘 표현하고 있으며 10 < Ra" <1,000범위에서 추천될 수 있다. 두개의 유사한 상관관계식과 비교할 때 상당히 좋은 예측을 보였으며 또한 Sparrow와 Gregg의 연구결과와도 잘 일치하므로 Ra" < 10인 경우에 Aung의 완전발달층류의 채널유동방식, Ra" > 1,000인 경우에는 Aung등의 단일 수직평판 근사식이 추천될 수 있다. Coyne의 알고리즘에 의한 계산치는 10

• Journal of the Korean Society for Nondestructive Testing
• /
• v.34 no.4
• /
• pp.277-282
• /
• 2014

Recently, much attention has been paid to nonlinear ultrasonic technology as a potential tool to assess hidden damages that cannot be detected by conventional ultrasonic testing. One nonlinear ultrasonic technique is measurement of the resonance frequency shift, which is based on the hysteresis of the material elasticity. Sophisticated measurement of resonance frequency is required, because the change in resonance frequency is usually quite small. In this investigation, the nonlinear electromagnetic acoustic resonance (NEMAR) method was employed. The NEMAR method uses noncontact electromagnetic acoustic transducers (EMATs) in order to minimize the effect of the transducer on the frequency response of the object. Aluminum plate specimens that underwent three point bending fatigue were tested with a shear wave EMAT. The hysteretic nonlinear parameter ${\alpha}$, a key indicator of damage, was calculated from the resonance frequency shift at several levels of input voltage. The hysteretic nonlinear parameter of a damaged sample was compared to that of an intact one, showing a difference in the values.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.16 no.4
• /
• pp.401-406
• /
• 2010

Vessel Operator has been navigating with subjective sate distance in accordance with night & daytime, fore & aft, port & stbd abeam and visibility situation. This sate distances may different depending on inside & outside harbor limit, current, wind and visibility situation. By now, the concept of proper sate distance between navigating vessels has been adopted in Korea, using the early 1980's foreign data. And the safe distance is being used with the same value without any consideration of inside & outside harbor and the kind of vessel. So it is necessary to evaluate or search proper distance concept based on different sate consciousness of Korean manners. This paper aims to develop the basic model for marine traffic evaluation and the new model of marine traffic congestion. Also this paper proposes the basic control guideline of vessel traffic service center. The result of this study showed that minimum sate distance should be 4.4L forward, 3.1L aft and 26L abeam in case of good visibility in daytime, considering various parameters such as visibility, day and night. Some differences Here found between the existing minimum sate distance and the new minimum sate distance derived from the result of this study.

• Journal of Navigation and Port Research
• /
• v.29 no.3 s.99
• /
• pp.189-194
• /
• 2005

The berthing/deberthing manoeuvring operation is the peculiar work owned to the marine pilot and the dock master. So, in the port or the shipyard, the berthing/deberthing manoeuvring operation requires considerable concentration and bears dangerousness. In that situation, a tug utilization is getting increased and the external forces have an effect on the own ship because of moving with low advance speed. In this study, we constructed the 2-dimensional virtual ship manoeuvring simulator system with which we can carry out the berthing/deberthing manoeuvring operation by using tugs in the external forces such as strong wind. And then, we propose the objective indexes by which the degree of manoeuvring difficulty evaluated. Using the present system, we carry out manoeuvring simulation experiment in order to grasp correlation between the objective indexes proposed here and the def{ree of manoeuvring difficulty felt by operator. Lastly, we discuss the evaluation technique of manoeuvring difficulty.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.30 no.8
• /
• pp.120-125
• /
• 2002

In the preceding tests using the KSR-III Sub.(I) engines, it was observed that the heat resistant capability of the engines was not enough for the mission. So Sub.(I) Mod. engines were designed and tested. The Sub.(I) Mod. engines have three major design parameters - the arrangement of main injectors, the impinging angle of main injectors and thermal barrier coating. More than twenty experiments were carried on to evaluate engine performance and heat resistance capability with respect to design parameters. In this study, the test results are introduced. Analysing the result of Sub.(I) engine tests, it is found that decreasing the impinging angle, adopting the H-type arrangement(rather than radial type arrangement) and adopting the thermal barrier coating can increase heat resistance capacity substantially. Also, engine performance evaluation is conducted using specific impulse and characteristic velocity parameter. The results show that the performance variation is small(about 5%) and the performance is better in the case of radial arrangement. It is suspected that these phenomena are caused by the change of flame structure atomization mixing characteristic of sprays and the distortion of recirculation zone. Also from the low frequency instability point of view, it is observed that reducing the impinging angle and adopting the H type arrangement can increase the instability characteristics.

• Journal of Satellite, Information and Communications
• /
• v.1 no.2
• /
• pp.8-15
• /
• 2006

Under Resolution 122 (Rev. WRC-03), ITU-R is invited to study, as a matter of urgency, power limitations applicable for HAPS ground stations to facilitate sharing with space station receivers in the bands 47.2-47.5 GHz and 47.9-48.2 GHz. However, there have been no studies on this issue. Recommendation ITU-R SF.1481-1 which was developed during past study period, provides methodology and system characteristics for analyzing the sharing feasibility between systems in the FS using HAPS and systems in the FSS. System characteristics for a typical HAPS in the bands above are also given in Recommendation ITU-R F.1500. This paper provides the results on power limitations applicable for HAPS ground stations in accordance with Resolution 122 (Rev. WRC-03). As already shown in ITU-R Recommendation the results show that a sufficient separation distance is required for sharing between HAPS ground stations and FSS satellite systems. We obtain some examples of the sharing conditions considering reducing the power level of HAPS ground stations and using the antenna beam pattern with the low sidelobe to decrease the interference level affecting FSS satellite receiver.