• Journal of the Korean Chemical Society
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• v.25 no.2
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• pp.75-84
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• 1981

Ultraviolet spectrophotometric investigations have been carried out on the systems of mesitylene with iodine, bromine, iodine monochloride and iodine monobromide in carbon tetrachloride. The results reveal the formation of the charge transfer complexes of the type, $C_6H_3(CH_3)_3{\cdot}X_2$ or $C_6H_3(CH_3)_3{\cdot}IX$ (X denotes halogen atoms). The equilibrium constants were obtained in consideration of that absorption maxima due to the formation of the charge transfer complexes shift to blue with the increasing temperatures. Thermodynamic parameters, ${\Delta}H$, ${\Delta}G$ and ${\Delta}S$ for the formation of the charge transfer complexes were calculated from these values. These results indicate that the relative stabilities of the mesitylene complexes at each temperature decrease in the order, ICl > IBr > $I_2$ > $Br_2$. This order may be a measure of their relative acidities toward mesitylene, which is explaned in terms of the relative polarizabilities of halogen molecules and the relative electronegativities of halogen atoms. These results combined with previous study of this series indicated that the relative stabilities of the polymethylbenzene complexes with iodine increase in the order Benzene < Toluene < Xylene < Mesitylene Thus, analysis of these findings is discussed.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.8 no.6
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• pp.445-452
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• 2015

Software reliability in the software development process is an important issue. Software process improvement helps in finishing with reliable software product. Infinite failure NHPP software reliability models presented in the literature exhibit either constant, monotonic increasing or monotonic decreasing failure occurrence rates per fault. In this paper, proposes the reliability model with log and power intensity function (log linear, log power and exponential power), which made out efficiency application for software reliability. Algorithm to estimate the parameters used to maximum likelihood estimator and bisection method, model selection based on mean square error (MSE) and coefficient of determination($R^2$), for the sake of efficient model, was employed. Analysis of failure, using real data set for the sake of proposing log and power intensity function, was employed. This analysis of failure data compared with log and power intensity function. In order to insurance for the reliability of data, Laplace trend test was employed. In this study, the log type model is also efficient in terms of reliability because it (the coefficient of determination is 70% or more) in the field of the conventional model can be used as an alternative could be confirmed. From this paper, software developers have to consider the growth model by prior knowledge of the software to identify failure modes which can be able to help.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.21 no.5
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• pp.465-474
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• 2008

The real-time hybrid testing method(RT-HYTEM) is a structural testing technique in which the numerical integration of the equation of motion for a numerical substructure and the physical testing for an experimental substructure are performed simultaneously in real-time. This study presents the quantitative evaluation of the seismic performance of a building structure installed with an passive and semi-active MR damper by using RT-HYTEM. The building model that was identified from the force-vibration testing results of a real-scaled 5-story building is used as the numerical substructure, and an MR damper corresponding to an experimental substructure is physically tested by using the universal testing machine(UTM). The RT-HYTEM implemented in this study is validated because the real-time hybrid testing results obtained by application of sinusoidal and earthquake excitations and the corresponding analytical results obtained by using the Bouc-Wen model as the control force of the MR damper respect to input currents were in good agreement. Also for preliminary study, some semi-active control algorithms were applied to the MR damper in order to control the structural responses optimally. Comparing between the test results of semi-active control using RT-HYTEM and numerical analysis results show that the RT-HYTEM is more resonable than numerical analysis to evaluate the performance of semi-active control algorithms.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.4
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• pp.489-494
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• 2015

This research focused on minimizing the response of fixed cylindrical offshore structures to a ship impact considering the seawater fluid part. A collision between a ship and offshore structure is generally a complex problem and it is often impractical to perform rigorous finite element analyses to include all the effects and sequences during the collision. The structural behavior of a fixed cylindrical type offshore substructure with a seawater fluid part has a simpler response and small deformation due to the dissipation of impact energy. Upon applying the impact force of a ship to the cylindrical structure, the maximum acceleration, internal energy, and plastic strain are calculated for each load cases using Ls-dyna finite element software. In the maximum cases 2.0 m/s velocity, the response result for the structure was carried out to compare between having a fluid region and no fluid region. Fluid-structure interaction analysis was performed using the ALE method, which make it possible to apply a fluid region on the impact problem. The case of a fixed cylindrical type offshore structure without a seawater fluid part can be a more conservative design.

• Journal of the Korean Association of Geographic Information Studies
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• v.15 no.3
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• pp.13-22
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• 2012

The spatial structure analysis using the existing space syntax has a weakness only to apply the road factor. Hence, it is necessary to perform a new spatial structure analysis considering the regional characteristics factor as well as the road factor. The purpose of this study is to propose a modified spatial structure analysis which adopts road and regional characteristics factors using the existing space syntax and GIS and then to apply it to the spatial structure analysis of the urbanized areas in Hapdeok town. For the new analysis, the experts' survey has been conducted to derive the spatial structure factors of the area and their relative weights. Specifically, it drew the road factor as well as the regional characteristics factors such as road, district, land value, and building density. This study shows that the existing spatial structure analysis considering only the road factor does not reflect the actual spatial structure but the modified spatial structure analysis considering the road factor and the regional characteristics factors more accurately analyzes the spatial structure of Hapdeok town. Hapdeok is not an area where road networks were developed along main development axis and its centrality was changed, but an area where road networks were developed by effectiveness and equity and its centrality was changed by downtown decline. The towns like Hapdeok is more suitable for applying the modified spatial structure analysis method considering the regional characteristics factors. Further research is required for selecting characteristics factors and appropriate parameters in the modified spatial structure analysis. Further case studies await in other cities for conducting its verification.

• Journal of the Korean Institute of Intelligent Systems
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• v.21 no.6
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• pp.749-754
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• 2011

In this study, we propose the design of optimized pRBFNNs-based face recognition system using two-dimensional Image and ASM algorithm. usually the existing 2 dimensional face recognition methods have the effects of the scale change of the image, position variation or the backgrounds of an image. In this paper, the face region information obtained from the detected face region is used for the compensation of these defects. In this paper, we use a CCD camera to obtain a picture frame directly. By using histogram equalization method, we can partially enhance the distorted image influenced by natural as well as artificial illumination. AdaBoost algorithm is used for the detection of face image between face and non-face image area. We can butt up personal profile by extracting the both face contour and shape using ASM(Active Shape Model) and then reduce dimension of image data using PCA. The proposed pRBFNNs consists of three functional modules such as the condition part, the conclusion part, and the inference part. In the condition part of fuzzy rules, input space is partitioned with Fuzzy C-Means clustering. In the conclusion part of rules, the connection weight of RBFNNs is represented as three kinds of polynomials such as constant, linear, and quadratic. The essential design parameters (including learning rate, momentum coefficient and fuzzification coefficient) of the networks are optimized by means of Differential Evolution. The proposed pRBFNNs are applied to real-time face image database and then demonstrated from viewpoint of the output performance and recognition rate.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.2
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• pp.155-162
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• 2008

Inventories to be disposed of, reference turnup, and source terms for CANDU spent fuel were evaluated for geological disposal system design. The historical and projected inventory by 2040 is expected to be 14,600 MtU under the condition of 30-year lifetime for unit 1 and 40-year lifetime for other units in Wolsong site. As a result of statistical analysis for discharge burnup of the spent fuels generated by 2007, average and stand deviation revealed 6,987 MWD/MtU and 1,167, respectively. From this result, the reference burnup was determined as 8,100 MWD/MtU which covers 84% of spent fuels in total. Source terms such as nuclide concentration for a long-term safety analysis, decay heat, thermo-mechanical analysis, and radiation intenity and spectrum was characterized by using ORIGEN-ARP containing conservativeness in the aspect of decay heat up to several thousand years. The results from this study will be useful for the design of storage and disposal facilities.

• Journal of the Korean Electrochemical Society
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• v.22 no.4
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• pp.139-147
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• 2019

Lithium-ion battery (LiB) with high energy density and efficiency has been utilized for the electric vehicle (EV) and energy storage system (ESS) as well as portable devices. However, as explosion accidents have frequently happened till lately, all-solid-state lithium secondary battery (ALSB) began to get in a spotlight because it can secure a very high safety and energy density by substituting flammable organic liquid electrolyte to nonflammable inorganic solid electrolyte. In spite of ALSB's certain merits, it has shown much poorer performance of cells than one of LiB due to some challenges, which have been small or never dealt with in the LiB system. Hence, although plenty of studies made progress to solve them, an approach about design of all-solid-state electrode (ASSE) has been limited on account of difficulty of ALSB's experiments. That is why the virtual 3D structure of an all-solid-state electrode has to be built and used for the prediction of cell performance. In this study, we elucidate how to form the 3D ASSE structure and what to be needed for the simulation of characteristics on ALSB. Furthermore, the ultimate orientation of 3D modeling and simulation for the study of ALSB are briefly suggested.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.5
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• pp.557-565
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• 2021

Path-following control is considered as one of the most fundamental skills to realize autonomous navigation of marine vessels in the ocean. This study addresses with the path-following control for a ship in which there are environmental disturbances in the directions of the surge, sway, and yaw motions. The guiding principle and back-stepping method was utilized to solve the ship's tracking problem on the reference path generated by a virtual ship. For path-following control, error dynamics is one of the most important skills, and it extends to the research fields of automatic collision avoidance and automatic berthing control. The algorithms for the guiding principles and error variables have been verified by numerical simulation. As a result, most error variables converged to zero values with the controller except for the yaw angle error. One of the most interesting results is that the tracking errors of path-following control between two ships are smaller than the existing safe passing distances considering interaction forces from near passing ships. Moreover, a trade-off between tracking performance and the ship's safety should be considered for determining the proper control parameters to prevent the destructive failure of actuators such as propellers, fins, and rudders during the path-following of marine vessels.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.2
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• pp.741-749
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• 2019

A hydraulic breaker attached to an excavator is a kind of constructuion equipment which is used for the disassembling of buildings, crashing road pavement, breaking rocks at quarry and etc. Therefore, the performance of the hydraulic breaker is mainly evaluated by the impact quantity and impact efficiency, which is an important factor for both the manufacturer and the user. In this paper, modeling and simulation for the prediction of the impact of the hydraulic breaker was conducted according to hydraulic pressure area and operating conditions of the hydraulic valve and piston using the commercial tools SimulationX for the 20ton hydraulic breaker which is mainly used in construction site. In order to verify the reliability of modeling and simulation, the results of previous experimental studies were compared and verified. The results of this study are expected to be useful for predicting the impact of the hydraulic breaker at the design stage before manufacturing and for studying parameters for improving the impact quantity. In addition, the manufacturer predicts that the development time and cost will be reduced through trial and error prevention by predicting the impact of the hydraulic breaker through the results of this paper.