• Journal of the Korea Organic Resources Recycling Association
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• v.18 no.4
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• pp.31-37
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• 2010

Livestock manures have a potential to be a valuable resource with an efficient treatment. In Korea, 42 million tons of livestock manure were generated in 2008, and 84 % of them were used for compost and liquid fertilizer production. Recently recycling of livestock manure for biogas production through anaerobic digestion is increasing, but its utilization in agriculture is still uncertified. In this study, there was applied co-digestate to the paddy for rice cultivation based on N supplement. Co-digestate was fertilizer fermented with pig slurry and food waste combined with the ratio of 70:30(v:v) in its volumetric basis. For assessing the safety of co-digestate, it was monitored the contents of co-digestate for seasonal variation, resulted in no potential harm to the soil and plant by heavy metals. The results showed that soil applied with co-digestate was increased in exchangeable potassium, copper and zinc mainly due to the high rate of pig slurry in co-digestate applied. Considering high salt content due to the combination with food waste, strict quality assurances are needed for safe application to arable land though it has valuable fertilizer nutrient. Leachate after treatment showed that the concentration of nitrate nitrogen washed out within two weeks. Considering the salt accumulation results in soil, it is highly recommended that the application rate of co-digestate should not exceed the crop fertilization rate based on N supplement. With these results, it was concluded that co-digestate could be used as an alternative fertilizer for chemical fertilizer. More study is needed for the long-term effects of co-digestate application on the soil and water environment.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.476-481
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• 2005

2004년말 현재 국내에서 발생되는 음식물쓰레기의 재활용량은 전체 발생량의 $87.7\%$인 10,015톤/일이며, 전체 재활용량의 $6.47\%$인 640톤/일 정도가 혐기성소화 방법에 의해 처리 및 자원화 되고 있다. 국내에서 적용되고 있는 음식물쓰레기 혐기성소화 기술의 대부분은 습식소화(Wet digestion) 공법이며, 처리 방법별로 2상 혐기성소화(Two-phase anaerobic digestion)와 하수슬러지 흑은 축산분뇨와 함께 혼합처리 하는 통합소화(Co-digestion) 공정으로 구분되고 있다. 음식물쓰레기의 자원화 방법에 있어 혐기성소화는 사료화, 퇴비화에 비하여 폐기물의 효과적인 감량화와 자원화 효과뿐만 아니라 유용 에너지원인 메탄가스의 회수가 가능하기에 최근에 주목을 받는 biotechnology중의 하나로 자리매김 하고 있으며, 또한 유기성폐기물의 자원순환형 관리 시스템 구현에 있어 적절한 대안으로 고려되고 있다.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.65 no.4
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• pp.508-517
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• 2020

This study aimed to determine the minimum period of aeration treatment of co-digestate to develop it as liquid fertilizer and the chemical changes that occur in the aerobic liquefying process. The co-digestates were divided into three types depending on their additives: swine slurry anaerobic digestate (SS AD), swine slurry 70% + cow slurry 30% anaerobic digestate (SS + CS AD), and swine slurry 70% + apple pomace 30% anaerobic digestate (SS + AP AD). The pH of all co-digestates increased rapidly after 3 days of aerobic treatment, but had slightly decreased in SS AD after 9 days and in SS + CS AD and SS + AP AD after 15 days. All co-digestates showed a strongly reduced pH between 27 and 36 days of aeration treatment. SS AD had lower pH value, dissolved oxygen (DO), NH₄-N, and NO₃-N content under aerobic conditions than other co-digestates. To assess the fully decomposed liquid fertilizer, a germination test was performed on the undiluted and diluted co-digestate using the liquid fertilizer germination index (LFGI) method. The relative germination ratio, relative root elongation, and germination index of SS AD were higher than those of the others. When the LFGI method was used for the germination test, all co-digestates showed an appropriate germination index of 70 after 60 days of aeration treatment. Thus, we suggest that the minimum period of aeration treatment for co-digestates might be 60 days to develop the fully decomposed liquid fertilizer.

• Journal of the Korea Organic Resources Recycling Association
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• v.19 no.4
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• pp.66-73
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• 2011

Objective of this study was to investigate the effect of biogas production to different systems and feeding stocks. For the biogas production through operating the temperature phase anaerobic digestion(TPAD) with different feeding stocks, the stage state of biogas production with 70% of methane concentration in the thermophilic digestion tank with co-digestion of food waste and swine manure(40 : 60) was delayed at 3.5 times, but its mesophilic tank was short for 5 days as relative to the swine manure. The cumulative methane production in the thermophilic digestion tank with co-digestion of food waste and swine manure was started with greater than its swine manure at 60 days after digestion periods. However, its mesophilic tank with swine manure was great at 3 days after digestion periods. For aspect of anaerobic digestion processes with swine manure, it was appeared that the stage state of biogas production rate in TPAD was shorter than the two phase anaerobic digestion system.

• Journal of the Korea Organic Resources Recycling Association
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• v.19 no.1
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• pp.123-130
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• 2011

Objectives of this study were to compare the environmental effects of digestates produced in bioenergy village on the rice paddy field for recycling. Digestates were applied to the soils and the soil properties and the crop responses were analyzed according to the standard methods of soil evaluation. Plant height and the number of tiller showed similar results in both the conventional and digestate treated field, and the yield of rough rice was higher in the field treated with digestates than that with chemical fertilizer. The amounts of nitrogen absorbed in straw and grain were larger in the digestates-treated field than chemical fertilizer-treated one, and efficiency of nitrogen applied was shown to be the highest in 100% treated digestate of the pig manure. Exchangeable cation and pH increased in the soil treated with digestate after harvesting, but salt was not accumulated. With these results, it was concluded that resource recycling in green town can be facilitated through the securement of arable lands for the application of digestates and the proper use of these fertilizers. Long-term effects of digestate application on the soil environment should be sustainingly studied.

• Resources Recycling
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• v.26 no.1
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• pp.59-68
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• 2017

This study has been conducted to evaluate the effects of a single stage anaerobic co-biogasification of food waste and primary sewage sludge mixture (1 : 5 V/V%) according to mixing ratio (0% : CAP0, 0.5% : CAP0.5, 1%: CAP1.0) in red pepper powder, which was reported as the material anti-bacterial and anti-fungi, under mesophilic condition ($35^{\circ}C$). during 31 days. It showed that red pepper powder effected anaerobic bacteria, Especially, Hydrolytic bacteria and methanogenic bacteria was inhibited much more than Acetogenic bacteria with red pepper powder. at CAP0, Experimental cumulative methane yield (ECMY) and Experimental bio-energy production (EBEP) were 0.17 L $CH_4/g$ $VS_{fed}$ and 1,465 cal/g $VS_{fed}$ individually as the highest value during 31 days.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.895-902
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• 2011

Objective of this research was to investigate the characteristics of biogas production in anaerobic digestion reactor with different mixing ratio of food waste and swine manure. It was observed that the highest removal efficiency of organic material was 80% at 60 : 40 of mixing ratio (livestock manure : food waste). And also biogas yield was varied due to different mixing ratio of them. The cumulative biogas yield was highest at 60 : 40 of mixing rate (livestock manure : food waste). For use of the liquefied fertilizer as effluent from anaerobic digester, it was the limited ratio for 30% of co-digested food waste based on its salt content.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.251-251
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• 2011

해양 투기가 금지되면서 혐기소화를 통해 최종적으로 발생되는 폐기물 양을 줄이고 메탄 등의 바이오 가스를 얻어 이를 에너지로 얻기 위한 많은 공정들이 현장에 적용되고 있다. 하지만 혐기 소화 과정을 마친 후 유출되는 유출액은 고농도의 유기물질 및 암모니아성 질소, 인산염 등을 다량으로 함유하고 있어 적은 양이라도 하천이나 호수 등에 유입되면 수질 악화와 부영양화를 초래할 위험성이 크다. 이번 연구에서는 음식물류 폐기물로부터 바이오가스를 생산하기 위한 혐기소화 공정에서 발생하는 유출액의 방류수 수질기준 확보와 경제성을 만족시킬 수 있는 처리공정의 상용화 기술을 개발하기 위해 생물학적 처리， 물리 화학적 처리를 통합한 공정을 적용하였다. P건설사 혐기소화 유출액 pilot plant(1 ton/day) 운전 결과 50~70% 로 $NO_2$-N 이 약 1,000 mg/$\ell$정도로 축적되는 현상을 보였으며 상대적으로 $COD_{Cr}$의 농도는 400~600 mg/$\ell$로 C/N 비가 낮아 탈질이 어려울 것으로 판단하였다. 이에 실험실 규모에서의 실험을 진행하였다. $NO_2$-N와 $NO_3$-N을 기준으로 McCarty 양론비 기준 80% 에서 300%까지 메탄올을 주입해 제조 폐수와 실제폐수로 실험을 진행하였고 제조폐수로 실행된 실험에서 아질산 탈질의 효율을 확인하였다. 미생물이 메탄올에 순응 후 완전 탈질에 걸리는 시간은 약 2.5 일로 확인 되었으며 메탄올이 추가로 주입되지 않은 반응조의 $NO_2$-N의 탈질량은 메탄올이 이론값 100% 주입 된 반응조에 비해 30% 이하의 처리 효율을 나타냈다. 이론값을 기준으로 메탄올이 100% 주입된 반응조는 약 96.1%의 탈질 효율을 보였으며 메탄올 순응 후에 약 1.5 일의 HRT가 단축되었기 때문에 메탄올에 장시간 순응 시 탈질 효율이 더 좋아질 것으로 보인다. 아질산탈질에 대한 실험실 규모 연구결과를 토대로 pilot plant에서 재현성 검토를 목적으로 운전을 수행하였다. 무산소조의 HRT는 2.7 일 이었으며 호기조의 HRT는 4.1 일 이었다. 유입수의 평균 $COD_{Cr}$ 농도는 2,878 mg/L, T - N 농도는 2,723 mg/L로 나타났으며 $NO_2$-N 기준 C/N비 1.2-1.8의 메탄올을 주입하였을 때 96% 이상의 탈질율을 보였다.

• Journal of the Korea Organic Resources Recycling Association
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• v.16 no.4
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• pp.43-49
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• 2008

Objective of this study was to monitor the hydrogen sulfide production rate and concentration in anaerobic co-digestion of swine manure and food waste for biogas production in order to alternate the petroleum based energy. Anaerobic co-digestion for biogas production was performed in serum bottles at 2% volatile solids (VS) concentration and various mixing ratios of two substrates(swine manure: food waste = 100:0 ~ 0:100). Although hydrogen sulfide production rates were varied with digestion periods at different treatments, it was observed that hydrogen sulfide produced in the swine manure alone was lower at 2.4 fold than that of food waste. For effects of hydrogen sulfide concentration in the different mixing ratios of swine manure to food waste, the higher food waste ratio the higher hydrogen sulfide concentration. Also its average concentrations were varied from 0.1452% in the swine waste only to 0.3420% in the food waste alone. For the composition ratio of bio-gas in their anaerobic co-digestion, it appeared that there was 53.2% of $CH_4$, 23.9% of $CO_2$, 0.3% of $H_2S$ and 22.7% of miscellaneous gases including moisture.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.3
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• pp.64-73
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• 2013

The application of the Life Cycle Assessment (LCA) methodology to analyze the environmental impact to different swine waste treatment systems was investigated. The first part of LCA is to organize an inventory of parameters and emissions released due to the system under investigation. In the following step of the Life Cycle Impact Assessment, the inventory data were analyzed and aggregated in order to finally get one index representing the total environmental burden. For the Life Cycle Impact Assessment (LCIA) the Eco-indicator 95 method has been chosen because this is well documented and regularly applied impact method. Two different swine waste treatment systems such as aerobic and anaerobic digestion systems were chosen as an example for the life cycle impact analysis. For establishing the parameters to be assessed the agricultural environmental effects to above swine waste treatment systems, it has been observed that there was high at T-P emission in anaerobic digestion system and $CO_2$ emission in aerobic digestion system. For Eco-indicator values per environmental effect for swine waste treatment systems related to one tonne of swine waste, it was shown that there was a negative index for global warm potential and soil acidification in aerobic digestion system, but relatively high positive index for eutrophication in anaerobic digestion system.