• The Korean Journal of Pesticide Science
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• v.8 no.1
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• pp.38-45
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• 2004

To elucidate the photolysis characteristics of the insecticide imidacloprid in the environment, $[^{14}C]$imidacloprid was treated into water and paddy soil-water system. In water system, the amount of $^{14}C$-radioactivity distributed in aqueous phase was rapidly increased up to 80% of total $^{14}C$ in water during 7 days of exposure to sunlight. Also, the amounts of imidacloprid in water at day 0 and 3 days after treatment were 1.2461 and 0.8594 mg/kg, respectively, not being detected 7 days after treatment, indicating rapid degradation of imidacloprid in water by sunlight. One photodegradation product, imidacloprid urea, in which the $N-NO_2$ moiety of imidacloprid was replaced by oxygen, was detected from water in water and water-paddy systems. The amount of the metabolite detected from water in water system was 0.0112 mg/kg 1 day after treatment and reached the top concentration of 0.0391 mg/kg 7 days after treatment. In case of water-paddy system, its amount was 0.0117 mg/kg 1 day after treatment and reached the highest concentration of 0.0259 mg/kg 3 days after treatment. Rapid transformation of imidacloprid into polar compounds continued until 7 days after treatment, considering that 80% of $^{14}C$ in water distributed in aqueous phase 7 days after treatment, amount of imidacloprid was 1.6538 mg/kg at day 0 and 0.8785 mg/kg 1 day after treatment, not being detected after 15 days, indicating rapid degradation of imidacloprid in water-paddy soil system by sunlight. The direct degradation of imidacloprid to imidacloprid urea would be a major photodegradation pathway in water and water-paddy soil systems.

• Korean journal of applied entomology
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• v.60 no.2
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• pp.201-202
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• 2021

We confirmed the convenient bioassay method for the black cutworm, Agrotis ipsilon in semi-field conditions. And we surveyed the susceptibility to commercial pesticides of A. ipsilon, which feeds Chinese cabbage through this bioassay process. As a result of the test, six soil mixing insecticides and eight soil drenching insecticides showed more than 90% insecticidal activity.

• Korean Journal of Weed Science
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• v.7 no.2
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• pp.186-199
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• 1987

This study was carried out to investigate the growth of Korean lawn grass (Zoysia japonica Steud.), penncross bentgrass (Agrostis palustris Huda) and seaside bentgrass (Agrostis spp.) under application of 21 pre- and post-emergence herbicides and the weeding effect of 14 annual and 4 perennial weeds with them for the purpose of the systematic chemical weed control in turf. The results obtained were as follows; 1. Napropamide, napropamide + triclopyr and benefin were safe for Korean lawn grass and two kinds of bentgrasses when they were treated at 4 and 25 days after transplanting of turfgrasses. Simazine, lenacil and bentazon inhibited the growth of bentgrasses, but not Korean lawn grass. 2. The preemergence application of simazine, benefin and napropamide + simazine showed excellent control for Digitaria sanguinalis, Cyperus amuricus, Chenopodium album, Portulaca oleracea and Centipeda minima. Lenacil was excellent for control of all the tested weeds except Chenopodium album, napropamide excellent for them except Cyperus amuricus and Portulaca oleraces, and bentazon good for them except Digitaria sanguinalis. When simazine was treated with either napropamide or triclopyr at preemergence of weeds, weeding effect increased without inhibition of lawn growth. 3. The postemergence application of mecoprop, bentazon, benefin + dicamba and benefin + mecoprop was safe to bentgrasses. All the tested postemergence herbicides except simazine + atrazine did not inhibit the growth of Korean lawn grass. 4. Other postemergence herbicides mecoprop and triclopyr were excellent for the control of Echinochloa crusgalli and those except benefin and mecoprop excellent for Kummerovia striata. Digitaria sanguinalis was controlled by treating with all the tested post emergence herbicides and Cyperus amuricus controlled only by bentazon. 5. The growth rates of bentgrasses treated with simazine, lenacil and napropamide + simazine were lower than that of hand-weeded check, and those of benefin, bentazon, napropamide, napropamide + triclopyr, stomp, bensulide and triclopyr were higher than that one when applied at spring season. Korean lawn grass growth appeared to be good under application of all the tested preemergence herbicides at spring. Lanacil and bentazone showed poor control of Echinochloa crusgalli, and bensulide showed poor control of Erigeron canadensis. Also, napropamide and bentazon were not good for Kummerovia striata control. However, at the respective rates of all the tested herbicides, these three weeds were greatly controlled by 85-100% of weeding effect. 6. At the application of autumn season, bentazon, napropamide, pendimethalin, benefin, napropamide + triclopyr, bensulide and triclopyr seemed to be safe against three kinds of turfgrasses. But simazine, napropamide + simazine inhibited the growth of bentgrasses except Korean lawn grass. In terms of weed control performance, triclopyr was poor for controlling Echinochloa crusgalli and bentazon and stomp for Poa annua, napropamide, benefin and bensulide for Stellaria medico. Stellaria uliginosa and Cerastium caespitosum were well controlled by all the tested preemergence herbicides. 7. Korean lawn grass was safe when paraquat and glyphosate were treated at the dormanant season of turfgrass. These herbicides showed excellent controll of Poa annua but poor control of perennials in order of Trifolium repens < Miscanthus sinensis < Calystegia japonica < Artemisia asiatica. 8. In field test, all of 19 herbicides seemed to be safe when treated at Korean lawn grass. All of 10 preemergence herbicides were excellent for controlling annual weeds, but poor for perennial ones. All of 9 postemergence herbicides showed a excellent control for broad-leaf weeds.

• Research in Plant Disease
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• v.15 no.1
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• pp.30-35
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• 2009

This study was carried out to determine the causal agents of soil-borne fungal diseases that pose a threat to the muskmelon production in Cheong Yang, Korea and to investigate the potential effects of hot water drenching and three fumigant (metam sodium, dazomet and methyl bromide) on these diseases. As the agents of the diseases, Monosporascus cannonballus, Didymella sp., Fusarium sp., Phytophthora sp., were detected. Hot water and the fumigants were treated on two successive cropping seasons of melon. Soil temperature was measured at 0, 10, 20 and 30 cm soil depth. In 2005, soil sterilization by hot-water was more effective significantly to control of the diseases than by fumigant. yield was the highest in hot-water sterilized plot as $39\;ton{\cdot}ha^{-1}$. Dazomet ($50\;g/m^2$) treated plot was followed as $23\;ton{\cdot}ha^{-1}$. In 2006, hot water sterilized plot showed higher yields than non-treated plots ($14.8\;ton{\cdot}ha^{-1}$). But the other three fumigant contained Dazomet ($50\;g/m^2$) were no difference (P<0.05) in yield.

• Korean Journal of Agricultural Science
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• v.26 no.1
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• pp.1-5
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• 1999

This experiment was carried out to define the development of control method against rhizome rot of ginger. It was difficult to control of rhizome rot of ginger completely by way of only rhizome sterlization. When soil were stenilized with dazomet, and metalacxyl granule was applied, higher than 95% of control value as well as 39% of yield increase compared to control were found. Soil drenching with metalacxyl cupper oxychloride and streptomycin controlled the rhizome rot satisfactorily, but was inferior to the above mentioned combination.

• The Korean Journal of Pesticide Science
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• v.2 no.2
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• pp.108-112
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• 1998

This studies were conducted to investigate the effects of hexaconazole on growth of watermelon(Citrullus lanatus Schrad) and ethylene evolution from gourd(Lagenaria siceraria Standl). While foliar application of hexaconazole exhibited inhibition effect, little or no inhibition was found in the plants treated with soil drench application. The plant height and number of internode in watermelon were significantly inhibited at 7 days after treatment(DAT), but no significant difference was found at 42 DAT. No significant difference was found in site of female flower setting when treated with hexaconazole. The length of branch was significantly inhibited at the 2nd or the 3rd internode. It was suggested that the inhibition of stem elongation was related with application timing of the chemical. Hexaconazole increased ethylene evolution more effectively at earlier stage of gourd, but after 5 DAT ethylene evolution was decreased.

• Applied Biological Chemistry
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• v.26 no.4
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• pp.248-254
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• 1983

The effects of some soil conditions on the degradation rate and decomposing pattern of thiolix were investigated and the obtained results are summarized as follows: Thiolix degraded more rapidly in flood soils than in noon-flooded, and in wet soils than in dry soils under non-flooded soils. The degradation rates in non-flooded soils increased with higher pesticide concentration. Thiolix was more persistent in non-flooded soils under soil sterelization than under non-sterilization and degraded rapidly in glucose application. The metabolites identified from the soils by TLC and GLC include Thiolix alcohol, Thiolix sulfate, Thiolix ether and a unknown metabolite. Soil enzyme, acid phosphatase activity decreased at higher pesticide concentration, lower moisture contents of soil and the activity in glucose application was increased. Soil enzyme, urease and dehydrogenase activity decreased at higher pesticide concentrations.

• Korean Journal of Environmental Agriculture
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• v.17 no.3
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• pp.220-226
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• 1998

The effects of metalaxyl(granule), carbofuran(granule) and simazine(water soluble powder) on the soil microflora were conducted at field soil between Iksan and Chonju province. Pesticides were divided into 0.5, 1, 1.5 and 2.0 times of normal of field, respectively. The number of fluorescent Pseudomonas was ranged from $10^3$ to $10^6/g$ in both field soil treated with cabofuran. Pseudomonas concentration of Chonju field soil slowly increased and approached the maximum level at 56 day after treatment(DAT). It showed the higher at 14DAT than other DAT in Iksan field soil treated with metalaxyl or simazine, whereas it increased again at 112 DAT in metalaxyl treatment. Cabofuran treatment of both field soil showed maximum Pseudomonas number at 28 DAT compared to that of other treatments. In Chonju field soil, those Pseudomonads of metalaxyl and simazine treatment increased the highest level at 7 DAT. Simazine treatment decreased it's number from the beginning of experiment. In both soil, metalaxyl treatment decrease the general fungi number at 7 DAT, but increase at 14 and 56 DAT in Iksan field soil. However it increased at 56 DAT in Chonju field soil. Cabofuran treatment of Iksan field soil tended to decrease general fungi number at 28 DAT, but was ranged from 1.0 to $8.6{\times}104/g$ for the rest of experimental period. It started to increase at 56 DAT simazine treatment of Iksan. General bacterial concentration both soil treated with cabofuran was belong to $26.6{\sim}29.6{\times}106$. It was the highest at 56 DAT, but was not significantly different. General actinomyces number was highly increased at 7 and 112 DAT compared to that of other DAT. Pseudomonas putida or P. fluorescens from both field soil was separated and identified 10 to 30 of all 104 Pseudomonas, respectively. All isolated microorganisms showed chemical resistance of 100ppm metalaxyl, cabofuran and simazine treatment.

• Weed & Turfgrass Science
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• v.5 no.4
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• pp.213-218
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• 2016

Timely application and the choice of herbicides are crucial for red pepper production since the yield is significantly reduced by weed occurrence. Experiments were conducted to provide efficient weed control methods in red-pepper fields. The results suggest the followings: 1) in the field of prevalent grass weeds, application of pendimethalin EC as pre-emergence herbicide after transplanting followed by tank-mix with pendimethalin and fluazipfop-P-butyl EC as post-emergence at 3-5 leaf stage of Digitalia species gave a good control for 80 days without crop injury, 2) as for grass and other weeds occurrence, sequential application of tank-mix with glufosinate-ammonium SL and pendimethalin at 30 days after transplanting (DAT) followed by glufosinate-ammonium. at < 20 cm of weed height with 30 days' interval provided better weed control than 2-time application of glufosinate-ammonium. single application for 80 days in this trial. 3) To prevent from drifting of non-selective herbicide spray mist into red-pepper at furrow application, glufosinate-ammonium. should be applied at 15 cm of spray nozzle height at 20 DAT (18 cm tall of red pepper), and the spray nozzle should be placed below 30 cm above ground to keep spray drift minimum to red pepper with > 40 cm plant height at 40 DAT.

• Korean Journal of Environmental Agriculture
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• v.33 no.4
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• pp.290-297
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• 2014

BACKGROUND: The current study purposed to analyse the dissipation levels of a neonicotinoid insecticide and clothianidin in paddy and upland soils and clarify the effects of soil moisture on degradation and persistence of the insecticide. METHODS AND RESULTS: In order to achieve the research purposes, clothianidin 8% SG was applied to the paddy and upland fields at the rate of 0.024 kg a.i./10a, while the analytical standard was treated at 0.25 mg/kg soil under laboratory conditions. Based on the multiple first-order kinetics, total clothianidin in soils was dissipated with $DT_{50}$ of 6.7-16.1 and 6.9-8.2 days in the paddy and upland fields, respectively, whereas the figures under the laboratory condition became larger showing 56.3 and 19.6 days. CONCLUSION: As affected by soil moisture, some differences in degradative pathways were observed. Flooding of soil caused evidently demethylation and delayed cyclization of a major metabolite, thiazolylmethylguanidine (TMG) and methylaminoimidazole(MAI), compared to the aerobic upland condition. More than 80% and 50% of the parent compound was dissipated by the 24th day after the final application in both soils and, transformation products had constituted most of soil residues after that.