• Korean Journal of Soil Science and Fertilizer
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• v.11 no.2
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• pp.75-80
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• 1979

Ammonium desorption from 16 soils treated with $(NH_4)_2HPO_4$ solution (2000 ppm $NH_4$) was investigated by seven extractions with 0.01M $CaCl_2$. 1. There were 2 to 4 steps alternately appeared with fast and slow mode. 2. Desorption equation, log y=b-ax where y is desorption amount, b a constant indicating adsorption maximum, a retention constant, and x extraction number, was held for each step. 3. Desorption rate (100${\times}$desorption / adsorption) was 65% for the average of 15 soils, maximum 87% in Gimcheon series, minimum 32% in Samgag series. Yongho series (a peat soil) showed 156% indicating the release of large quantity of indigenous soil ammonium. 4. Desorption rate was negatively correlated with initial adsorption and in this relation the tested soils were classified into 3 groups. 5. The cumulative desorption curve was approaching almost to maximum in all tested soils with seven extractions. The final retention amount, ranged from 25% of CEC (Gimhae series) to 502% (Samgag Series). 6. Amount and rate of desorption did not have any significant relation with Langmuir adsorption maxima of ammonium, CEC and contents of clay, available phosphorus and organic matter. 7. The above results may indicate that adsorption and desorption of ammonium is closely related with iron, aluminum silicate and adsorption and desorption characteristics of accompanied anions.

• Journal of Radiation Protection and Research
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• v.15 no.2
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• pp.7-16
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• 1990

The sorption of radioactive cobalt and ruthenium on alumina, silica gel, zeolite 3A, kaolin and Na-bentonite has been studied as a function of pH. nuclide concentration and ionic strength. Retardation factor for cobalt and ruthenium on soil minerals was determined through porosity measurement. Hydrolysed species, cobalt and ruthenium interact with solid surfaces by physical adsorption processes. Freundlich sorption isotherms for cobalt and ruthenium are effectively linear. The sorption decreases with increasing ionic strength for cobalt and ruthenium. The effect of increasing porosity on the retardation factor countered the effect of a significant increase in the distribution coefficient.

• Proceedings of the KSEEG Conference
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• 2002.04a
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• pp.34-36
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• 2002

• Proceedings of the Korea Water Resources Association Conference
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• 2004.05b
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• pp.713-718
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• 2004

우리나라의 경우 재해영향평가 제도가 실시된 이후 모든 재해영향평가에서는 토양침식량을 산정하고 있다. 유역에서 토양침식량을 산정하기 위한 많은 모형들이 있지만, 분포형 모형들은 토양침식의 산정에 많은 비용과 시간을 요구한다. 그래서, 가장 널리 실무에서 쓰이고 있는 모형은 범용토양침식공식(USLE, Universal Soil Equation)이다. USLE은 연 토양 침식량 산정을 위한 경험공식으로, 토양침식은 강우강도, 토양의 종류, 토지 피복과 토지이용, 사면경사와 경사길이, 그리고 토양보전을 위한 시설의 영향을 받는다. 이러한 모든 변수들은 공간적으로 분포되어 있기 때문에, 이러한 변수들을 추정하기 위해 지형정보시스템(GIS)을 사용하면 보다 빠르고 정확한 변수들을 산정 할 수 있다. 또한, 유역에 내리는 강우는 토양침식뿐만 아니라 유기물의 흡착에 따른 비점오염원의 유출을 발생시킨다. 침식토에 흡착된 유기물의 양은 부유의 개념을 도입하여 산정 할 수 있다. 따라서 본 연구에서는 지형정보시스템(GIS)과 범용토양손실 공식을 연계하여 태풍루사의 강우에 의한 보청천 유역에서의 토양 침식량과 그와 함께 유출되는 유기질소(Organic N)의 양을 산정 하였다.

• Journal of Korea Soil Environment Society
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• v.5 no.3
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• pp.25-33
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• 2001

The study was performed to examine the influence of sea tide on a tideland composition by Saemankeum reclamation and to evaluate a correlation between the characteristics of physical and the pollution level of heavy metals. Also, it was investigated the characteristics of heavy metal adsorption through a batch experiment and applied to adsorption isotherm equations. In the results, the flow of sea tide occurred to accumulation action and had an effect on the content of heavy metals. It suggests that influence factors for the content of heavy metals in the tidal flat be grain size, cation exchange capacity and organic matter content. Adsorption capacity of heavy metals occurs to 90% adsorption rate for injection concentration within 30 minutes. The flow patterns in Saemankeum area will undergo a change for soil size distribution. In result, this soil size changed will effect the adsorption capacity of heavy metals.

• Journal of Soil and Groundwater Environment
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• v.9 no.1
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• pp.63-69
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• 2004

Hematite-coated sand was examined for the application of the PRB (permeable reactive barrier) to the arsenic-contaminated subsurface in the metal mining areas. The removal efficiency of As in a batch and a flow system was investigated through the adsorption isotherm, removal kinetics and column experiments. Hematite-coated sand followed a linear adsorption isotherm with high adsorption capacity at low level concentrations of As (＜1.0 mg/L). In the column experiments, high content of hematite-coated sand enhanced the removal efficiency, but the amount of the As removal decreased due to the higher affinity of As (V) than As (III) and reduced adsorption kinetics in the flow system. Therefore. the amount of hematite-coated sand, the adsorption affinity of As species and removal kinetics determined the removal efficiency of As in a flow system.

• Journal of Soil and Groundwater Environment
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• v.10 no.2
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• pp.1-11
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• 2005

This study applied EK method to remediate contaminated soil by lead (Pb), tried increasing efficiency of remediation using adsorbent (apatite and zeolite) as enhanced EK remediation method to overcome the limit of traditional EK remediation method. Adsorption tests on Pb were practiced to extract EK, making different concentration of contaminated soil, voltage condition, operating time etc., transferring Pb-ion into the position of adsorbent, then tried immobilization. On this results, the efficiency of remediation is different on its test conditions. In addition, the efficiency of remediation was not only improved by adding electrode revεrsal and install position of adsorbent but also satisfied TCLP regulation of EPA in USA through the whole sample range. Finally, absorption and immobilization capacity of apatite and zeolite proved on its excellence and confirmed the possibility of application of apatite and zeolite as enhanced EK remediation method.

• Journal of Soil and Groundwater Environment
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• v.13 no.3
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• pp.21-26
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• 2008

Nitrate adsorption from aqueous solutions onto zinc chloride ($ZnCl_2$) treated coconut Granular Activated Carbon (GAC) was studied in a batch mode at two different initial nitrate concentrations (25 and 50 mg/L). The rate of nitrate uptake on prepared media was fast in the beginning, and 50% of adsorption was occurred within 10 min. The adsorption equilibrium was achieved within one hour. The mechanism of adsorption of nitrate on $ZnCl_2$ treated coconut GAC was investigated using four simplified kinetic models : the rate parameters were calculated for each model. The kinetic analysis indicated that pseudo-second-order kinetic with pore-diffusion-controlled was the best correlation of the experimental kinetic data in the present adsorption study.

• Journal of Environmental Science International
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• v.5 no.2
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• pp.243-252
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• 1996

In order to investigate the effects of pH and organic matter content on cadmium adsorption and exchangeable cations desorption in soils, the adsorption isotherms of cadmium and the desorption isotherms of calcium and magnesium on four New jersey soils at four pH values were plotted, and the cadmium partition coefficients (Kd) were also calculated. The slopes of cadmium adsorption isotherms dramatically increased with increasing solution pH. Judging from Langmuir adsorption equations, the maximum adsorption quantities(b) of cadmium at high pH values were much greater than those at low pH values for the same soil. The partition coefficients increased greatly with increasing solution pH. The slopes of regression equations between partition coefficients and pH values were steep in the order of the organic matter content of the soils. The correlation coefficients (r2) between partition coefficient and organic matter content for soils. The correlation coefficients (r2) between partition coefficient and organic matter content for $1\times10^{-4}$M increased from 0.3027 at pH 4.0 to 0.9964 at pH 8.5 and from 0.2093 at pH4.0 at 0.9657 at pH 8.5 for$2\times10^{-4}$M ${Cd(NO_3)}_2$. The desorption quantities of calcium and magnesium decreased with increasing solution pH and increased with- increasing cadmium adsorption.

• Korean Journal of Soil Science and Fertilizer
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• v.17 no.4
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• pp.381-388
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• 1984

Addition of heavy textured red earth is being recommended to improve the texture and nutirent retention capacity of sandy soil in Korea. However, farmers are not favorable to this description because of high transportation cost and hard working. To solve this pending problem a field experiment was carried out to investigate the possibility of application of Zeolite as a foreign earth material to improve the physical and chemical characteristics of sandy soil. The experiment results suggested that Zeolite mixed with the basal N fertilizer would be substituted for other foreign earth materials in aspects of rice yield and nitrogen uptake of rice shoot. On the other hand, ammonium adsorption characteristics of soil and amendments were studied.