• Title/Summary/Keyword: 토양화학

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심부시추공 지하수의 심도별 지화학 특성

  • 최현수;고용권;김경수;배대석;김천수
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.229-232
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    • 2002
  • 대전 북부 화강암지역 내 심도 500m까지 굴착한 시추공에 다중패커 시스템(Multi-packer system)을 이용하여 구간별로 지하수 시료채취를 수행하고, 시추공 지하수에 대한 지화학 특성 연구를 수행하였다. 다중패커 시스템에 의해 구간별로 격리된 시추공 지하수의 수리화학자료는 구간별로 특징적인 화학조성을 나타낸다 다중패커 시스탬이 설치된 직후 채취한 지하수 시료와 일정시간이 경과한 후 채취한 시료간에는 시기별로 화학특성의 차이를 보이는데 이는 시추당시 사용된 시추수의 영향 때문인 것으로 사료된다. 또한 심도 115m를 기준으로 상부구간과 하부구간에 지화학 특성에서 큰 차이를 보이고 있는데 이는 시추공 굴착당시 단열대의 붕괴로 인해 시공된 그라우팅의 영향 때문이다. 이상치를 보이는 115m 구간을 제외하고, 시추공 지하수의 지화학 자료는 구간별로 명확히 구별되어 화강암 지역에서 지하수의 유동은 단열분포특성에 영향을 받음이 확인되었다.

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Fe$^{\circ}$/$H_2$$O_2$시스템을 이용한 고농도 유류오염 미세토양의 화학적 산화처리

  • 장윤영;지원현;김지형;황경엽
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.34-37
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    • 2001
  • 폐수처리분야에 널리 사용되어 온 펜톤산화반응을 응용한 Fe$^{\circ}$/$H_2O$$_2$시스템을 이용하여 고농도 유류오염 미세호양(100$\mu\textrm{m}$이하)의 화학적 산화처리 실험을 수행하였다. 반응은 100$m\ell$, 삼각프라스크에 오염토양(5g)과 반응시약을 주입한 후 자석교반기를 이용하여 회분 식으로 진행하였으며 일정 시간(0, 1, 2, 4, 8, 24hr)별로 TPH를 측정하였다. 그리고 각 조건별 시간에 따른 반응특성을 살펴보았다. 일반적으로 알려진 펜톤산화반응의 수요 반응조건인 초기 pH /$H_2O$$_2$ 및 Fe$^{\circ}$의 주입농도, 그리고 초기 디젤오염농도의 조건을 변화하며 각 조건별 처리효과를 알아보았다. 본 연구결과에서 최적 pH조건은 3인 것으로 나타났으며, 분말철(Fe$^{\circ}$)과 $H_2O$$_2$의 주입농도를 증가함에 따라 오염토양의 TPH 제거효율도 비례적으로 향상되었다. 초기오염농도에 따른 최종 처리효율은 큰 차이가 없었으나. 고농도 오염일수록 제거된 디젤의 총량은 크게 나타나. 본 논문에서 제시한 방법이 고농도 오염토양일수록 더 큰 효과를 얻을 수 있음을 보여주었다. 대부분의 반응이 반응개시 후 약 8시간 이내에 이루어졌는데, 반응에 수반되는 pH 상승과 그에 따른 반응성의 저감효과를 일정 pH 조절에 의해 감소시킴으로써 반응성의 향상을 좀 더 높일 수 있을 것으로 판단된다. 결론적으로, Fe$^{\circ}$/$H_2O$$_2$시스템을 이용한 화학적 산화처리방법은 경제성과 처리성능에서 고농도 유류오염 미세토양의 효율적인 처리방안으로서 향후 적용 가능성이 높을 것으로 기대된다.

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Characteristics of the Inorganic Element Contents or the Korean Ginsengs from Various Soils of Keumsan (금산 지역 토양 차이에 의한 인삼 중 무기 원소의 함량 변화)

  • Song, Suck-Hwan;Min, Ell-Sik
    • Journal of Ginseng Research
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    • v.33 no.1
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    • pp.13-25
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    • 2009
  • Geochemical relationships between ginsengs and soils from three representative soil types, shale, phyllite and granite regions, from Keumsan were examined. High elements ere shown at the granite and shale areas of the weathered soils, the phyllite areas of he cultivated soils and the shale areas of the host rocks. T1 was enriched in ginsengs grown in the shale areas, Cs and B in the phyllite areas, and Be and Cd in the granite areas. Positive correlations were dominated by the shale areas. These relationships can be explained for mineral characteristics within the soils, and their behaviors related to the physio-chemical conditions. High elements were shown in the 2 year ginsengs of the hale areas, and 4 year ginsengs of the phyllite and granite areas in comparisons with ginsengs of the different ages from the same areas. These differences can be explained with ages of the ginsengs, solubilities of the minerals and physio-chemical differences within soils. The content differences of high elements such as Cs, T1 and Be were found between soils and ginsengs. Overall, these results suggest that components of ginsengs grown in the granite areas are chemically similar to the soils.

The Change of Soil Physicochemical Properties by Mixture Ratio of Inorganic Soil Amendments (무기성 토양개량제들의 혼합비율에 따른 토양이화학성의 변화)

  • Kim, Young-Sun;Kim, Tack-Soo;Ham, Suon-Kyu
    • Asian Journal of Turfgrass Science
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    • v.23 no.2
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    • pp.271-278
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    • 2009
  • This study was conducted to investigate the effect of the mixture ratio of the inorganic soil amendments on the soil physicochemical properties. In this experiment, three kinds of soil amendments which had similar pH, EC and particle size, the A, B and C, were tested. The mixture ratio of soil amendment were 0%, 3%, 5%, 7% and 10% (V/V) incorporated with sand which met to the USGA(United State of Golf Association) particle standard. To analyze the effects of amendment on chemical soil properties, pH, EC(electrical conductivity) and CEC(cation exchangeable capacity) were measured. The porosity, bulk density and hydraulic conductivity also measured to analyze the changes of physical properties. In the chemical properties, pH was significantly related to the mixture ratios of amendments, A and C(P<0.05), CEC and EC also related to the ratios of C(P<0.01). When the results were applied to the USGA standard of the soil physical properties, the optimum mixture ratios of each amendment were 3% in A and B, and 7~10% in C. To analyze the corelation of mixture ratio versus to physical character, volume of porosity was significantly related to the ratio of B (P<0.05), and showed similar corelation in porosity and hydraulic conductivity with ratio of C(P<0.05). These results indicate that types and mixture ratio of inorganic soil amendments should affect on soil physio-chemical properties of root zone on USGA sand green.

Geochemical Behavior of Metals in the Contaminated Paddy Soils around Siheung and Deokeum Mines through Laboratory Microcosm Experiments (실내 microcosm실험에 의한 시흥광산 및 덕음광산 주변 오염 논토양내 중금속의 지구화학적 거동 연구)

  • 김정현;문희수;안주성;김재곤;송윤구
    • Economic and Environmental Geology
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    • v.35 no.6
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    • pp.553-565
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    • 2002
  • Seasonal variations in vertical distributions of metals were investigated in the contaminated paddy soils around Siheung Cu-Pb-Zn and Deokeum Au-Ag mines. Geochemical behavior of metals was also evaluated with respect to redox changes during the cultivation of rice. Two microcosms simulating the rice-growing paddy field were set up in the laboratory. The raw paddy soils from two sites showed differences in mineralogy, metal concentrations and gecochemical parameters, and it is suggested that high proportions of exchangeable fractions in metals may give high dissolution rates at Deokeum. In both microcosms of Siheung and Deokeum, redox differences between surface and subsurface of paddy soils were maintained during the flooded period of 18 weeks. Siheung soil had neutral to alkaline pH conditions, while strongly acidic conditions and high Eh values were found at the surface soil of Deokeum. The concentrations of dissolved Fe and Mn were higher in the subsurface pore waters than in interface and upper waters from both microcosms, indicating reductive dissolution under reducing conditions. On the contrary, dissolved Pb and Zn had high concentrations at the surface under oxidizing conditions. From the Siheung microcosm, release of dissolved metals into upper waters was decreased. presumably by the trap effect of Fe- and Mn-rich layers at the interface. However, in the Deokeum microcosm, significant amounts of Pb and Zn were released into upper water despite the relatively lower contents in raw paddy soil, and seasonal variations in the chemical fractionation of metals were observed between flooded and drained conditions. Under acidic conditions, rice may uptake high amounts of metals from the surface of paddy soils during the flooded periods, and increases of exchangeable phases may also increase the bioavailability of heavy metals in the drained conditions.

Numerical Approach for Evaluation of Forest Soil Fertility (수치적(數値的) 접근방법(接近方法)에 의(依)한 산림토양(山林土壤)의 비옥도(肥沃度) 평가(評價))

  • Ma, Sang Kyu
    • Journal of Korean Society of Forest Science
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    • v.35 no.1
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    • pp.1-8
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    • 1977
  • Forest soil fertility was evaluated through the approach of numerical method. In this study, the soil chemical properties analyzed for 35 different soil series as table 2 were cited in numerical analysis. Minimum contents of essential nutrients in the surface soil for a satisfactory growth of tree in the plantation were evaluated by comparing with Wild's standard as table 1. Demanding level of fertilization were evaluated by using the formula 1 as table 5. Similar relation of soil chemical properties between soil series were calculated through formula 2, and then classified into 5 groups in soil chemical properties. 1. General chemical properties of surface soil in case of 35 soil series. About 40 percent of 35 different soil series are less than 2 percent in organic matter, 10 ppm in available phosphorus, 1.25m.e/l00g in exchangeable calcium and 0.5m.e/l00g in exchangeable magnesium. Generally, shortage of exchangeable potash are not found. CEC less than 10m.e/l00g are in two thirds and strong acid soil less than PH 5.5 are in about four fifths. 2. Soil series requested or not the fertilization are indirectly evaluated from the formula 1 using the relative figure of chemical components of CEC, OM and MgO. Through this analysis, 8 different soil series have very poor quality in soil chemical capacity so that demands highly the fertilization. On the other hand, other 13 different soil series group have not been thought to need the fertilization according to chemical guality. 3. By the results comparing the similarity of chemical properties of forest soil, it is thought to be suitable that the forest soil fertility are divided into 5 groups as follows: 1. Low CEC soil 1-1 Low organic matter soil less than 2 percent 1-2 Medium organic matter soil less than 4 percent 2. High CEC and organic matter soil 2-1 Low magnesium soil 2-2 High magnesium soil 3. High magnesium and calcium soil as lime stone.

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Changes in Soil Properties and Rice Production as Influenced by the Consecutive Application of Liquid Swine Manure in Paddy Field (돈분 액비의 연용이 벼의 수량과 토양에 미치는 영향)

  • Ryoo, Jong-Won
    • Korean Journal of Organic Agriculture
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    • v.24 no.2
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    • pp.221-234
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    • 2016
  • The application of animal manure on farm fields is one of the most economical ways. However, the continuous application of manure in paddy fields might change soil properties influencing the growth of rice plant. Thus, this study was conducted to investigate the changes in selected chemical and biological properties of soils and rice production as affected by the applications of two different fertilizer sources, which were the consecutive applications of liquid swine manure (LSM) and chemical fertilizer (CF), during the three experimental years, from 2012 to 2014. Application amount of LSM was based on 100% of nitrogen fertilizer recommendation rate for rice cultivation estimated by soil testing. Plant height and tiller number in rice at the first year of liquid swine manure manure plot were lower than those of chemical fertilizer plot. Height and tillers of rice in liquid swine manure plot were higher than those of rice in chemical fertilizer plot after consecutive application for 3 years. Rice yield In the first year of application was decreased by 7% than that of chemical fertilizer, but the yield of rice in the third year of application in LM 100% plot was increased by 8% compared to the chemical fertilizer. Toyo-taste value of milled rice in LM 100% was decreased by increasing of protein contents and decreasing rate of perfect grain. The K and Zn contents in the soil were increased in the plots of consecutive LSM application. The results implied that the liquid manure may neither decrease the yield of rice and nor increase soil properties except K and Zn in the soil, and decrease rice quality.

Effect of Homemade Liquid Fertilizers on Chemical Property and Microbial Activity of Soil and Cucumber Growth (자가제조 액비처리가 토양 화학성과 미생물상 및 오이의 생장에 미치는 영향)

  • Jung, Ji-Sik;Jung, Seok-Kyu;Choi, Hyun-Sug
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.3
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    • pp.15-25
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    • 2019
  • The study was conducted to compare the chemical properties and microbial activity of soil and the crop productivity by applying homemade liquid fertilizers (LF) used in leading cucumber farms as well as to evaluate the eco-friendly LFs to substitute for a chemical fertilizer. Three homemade LFs, EM, starfish, and native microbes, and a chemical LF were regularly fertigated per three days during the growing season. Chemical LF contained the highest pH, EC (electrical conductivity), and concentrations of T-N, $P_2O_5$, K, Ca, and Mg, while the lowest EC level was observed for EM LF. Soil EC was the highest to the 3.0 dS/m for chemical LF-plots, with lowering soil pH, OM (organic matter), and Mg concentration. Soil chemical properties mostly increased in native microbes LF-plots. However, soil microbial properties were not significantly different among the LF treatment plots. OTU (operational taxonomic units), richness estimator, and diversity index of bacteria and fungi increased in the chemical LF and EM LF based on the pyrosequencing analysis. SPAD and PS II values on the treated-cucumber leaves were seasonally decreased from 32 to 60 days after transplanting, with the rapid decline observed at 45 days after transplanting. Number of leaves and crop height increased in the treatments with EM and native microbes LF. LF treated-cucumber crops were not significantly different for total fresh weight and fruit yield.

Effects of Organic Fertilizer Applications on Soil Properties and the Development of Chinese Cabbage (Braccica campestris) in the Alpine Regions of Korea (강원도 고랭지 채소 재배지에 시비한 유기물이 토양과 배추의 성장에 미치는 영향)

  • Kim, Su-Jung;Yang, Jae-E.;Shin, Young-Oh
    • Korean Journal of Organic Agriculture
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    • v.15 no.1
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    • pp.85-91
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    • 2007
  • 광범위하게 집중적으로 채소 재배에 이용되고 있는 강원도 태백산맥 지역의 고랭지를 대상으로 유기물 시용이 토양의 비옥도를 비롯한 화학적 성질에 미치는 영향을 조사했다. 또한 이런 조건에서 재배되는 배추의 생장과 수확량, 그리고 품질을 평가했다. 토양에 첨가한 많은 양의 돈분과 톱밥, 계분과 톱밥, 계분, 퇴비 등의 유기물질과 화학비료가 토양 유기물 함량에는 결과적으로 거의 영향을 미치지 못했다. 토양의 pH에도 마찬가지로 별 영향이 없었다. 그러나 K와 함께 Fe와 Mn의 함량은 감소한 반면 Ca와 Mg의 함량은 증가했으며 특히 유효 $P_2O_5$는 대단히 많은 양이 축적되는 것을 발견하였다. 배추의 양분함량을 내엽과 외엽으로 구분하여 분석한 결과 일반적으로 외엽의 영양소 함량이 내엽보다 많았으며 토양에 첨가한 유기물질의 종류간에는 별 차이가 없었다. 수확량에도 첨가한 유기물질의 종류가 뚜렷한 차이를 나타내게 하지 않았으며 병충해에 의한 피해는 관찰되지 않았다.

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Analysis of Soil Chemical Characteristics Changes According to Elapsed Time after the Forest Rehabilitation for Drawing Management of Abandoned Coal Mine Forest Rehabilitation Areas in Gangwon-do (강원도 폐탄광 산림복구지 관리방안 도출을 위한 산림복구후 시간경과에 따른 토양 화학적특성 분석)

  • Jung, Mun Ho;Ko, Ju In;Bak, Gwan In;Ji, Won Hyun
    • Economic and Environmental Geology
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    • v.54 no.4
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    • pp.457-464
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    • 2021
  • The objectives of this study were to analyze of soil chemical characteristics of abandoned coal mine forest rehabilitation areas in Gangwon-do. The study sites were 8 areas and the investigations were performed 11 times according to elapsed time. Soil characteristics were soil pH, TOC, Total-N, C/N ratio, and Av. P2O5. Soil pH and Av. P2O5 were decreased according to elapsed time after forest rehabilitation, while TOC, Total-N, and C/N ratio increased. TOC and Total-N arrived at quality requirements of covering soil for forest rehabilitation in abandoned coal mine area passed 10 years after forest rehabilitation, while soil pH became lower than that. Therefore, it needs long-term monitoring of soil chemical characteristics after the forest rehabilitation and to establish post management.