• Title/Summary/Keyword: 토양화학

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Geochemical Characteristics of Soil Solution from the Soil Near Mine Tailing Dumps and the Contamination Assessment in Duckum Mine (토양수의 자구화학특성에 따른 금속폐광산 광미야적장주변 토양오염평가: 덕음광산)

  • 이상훈;정주연
    • Economic and Environmental Geology
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    • v.37 no.1
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    • pp.61-72
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    • 2004
  • The soil samples were collected from the paddy field near the mine tailing dumps in the abandoned Duckum mine in Korea. In the laboratory, the soil solution was extracted from the soil using centrifuge, and analysed for the chemical composition. Physical and chemical soil properties were also analysed. Kaolinite is the main clay minerals in the paddy soil and the CEC value is therefore relatively low. Nearly all soil samples show enrichment in their trace elemental concentrations(Cd, Cu, Pb and Zn) compared with natural background level. Some soil samples exceed the soil remediation intervention values for Cd, Pb and Zn and target value for Cu, when compared with Dutch standard, whereas As, Ni and Cr are in normal range. Lead concentrations in some samples near the mine tailing dumps also exceed the standard for remediation act for agricultural area set by Korean soil conservation law. The trace elemental concentrations are higher in the paddy soil nearer the mine tailing dumps and lower for the samples from distance. Similar trend with distance is found for the soil solution chemistry but the decrease with distance from the mine tailing dumps are sharper than the changes in soil chemistry. Cadmium, Cu and Pb concentrations in the soil solution are very low, ranging from a tenth and hundredths to a maximum of several mg/l, whereas their concentrations in soils are highly enriched for natural background. Most of the trace elements are thought to be either removed by reduced iron sulphides or iron oxides, depending on the redox changes. Geochemical equilibrium modelling indicate the presence of solubility controlling solid phases for Cd and Pb, whereas Zn and Cu might have been controlled by adsorption/desorption processes. Although pollutants migration through solution phase are thought to be limited by adsorption onto various Fe, Mn solid phases, the pollutants exist as easily releasable fractions such as exchangeable site. In this case, the paddy soil would act as pollutant pool, which will supply to plants in situ. whenever the geochemical conditions favour.

토양 유기물과 산화철의 흡착 반응 및 특성

  • 고일원;김주용;김광구;김경웅
    • Proceedings of the KSEEG Conference
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    • 2003.04a
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    • pp.69-71
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    • 2003
  • 토양 및 수질 유기물질과 금속 산화물사이의 상호 반응관계는 환경지구화학적으로 중요하게 다루어진다 (Sposito, 1984). 토양내 광물들의 표면은 토양 유기물질의 주요한 부분을 차지하는 휴믹물질, 즉 휴믹산과 펄빅산에 의해서 이온강도와 산도에 따라 피복하는 현상을 일으킨다. 특히, 휴믹산과 펄빅산은 토양 및 수질내 주요한 구성 유기물로 존재하며 다양한 유기화합물과 분자량을 갖으며, 중금속들의 유출에 의한 오염 환경에서 그 화학종과 이동도에 영향을 주게된다 (Thurman, 1985). (중략)

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Effect of Mixtures with Lignite and Amino Acid Solution on the Growth of Rice Plant, Chinese Cabbage and Red Pepper, and the Chemical Properties of Soil (갈탄과 아미노산액 혼합제 시용이 벼, 배추와 고추의 생육 및 토양의 화학적 특성에 미치는 영향)

  • Han, Seong-Soo;Yoo, Ki-Yong;Park, Min-Su;Lee, Young-Il;Baek, Seung-Hwa
    • Korean Journal of Environmental Agriculture
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    • v.29 no.2
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    • pp.93-101
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    • 2010
  • For the study of possibility of practical use as an organic farm materials of the mixtures with lignite and amino acid solution, this experiment was carried out to investigate the effects of the mixtures on the growth and the yield of rice plant, chinese cabbage, and red pepper, and the effects of the mixtures on chemical properties of soil. Also, when the mixtures of the lignite plus amino acid solution and the chemical fertilizer were applied to these three crop cultivation area, authors want to know how can the loss in quantity of chemical fertilizer affects the growth and the yield of these crops. As the results, growth of rice plant applied with the mixtures of lignite and amino acid solution was better than that applied with the recommended rate of chemical fertilizer. Especially, the growth of rice plant appeared to be good at the treatment of 150 kg/ha of the mixed lignite with amino acid solution and at that of its mixtures and standard fertilization. Growth of chinese cabbage and red pepper was good at the application of 600 kg/ha of the mixed lignite with amino acid solution and at that of its mixtures and standard fertilization. Yield of rice and chinese cabbage was good at the treatment of 150 kg/ha of the mixed lignite with amino acid solution and at that of its mixtures and standard fertilization, and yield of red pepper was good at the application of 600 kg/ha of the mixed lignite with amino acid solution and at that of its mixtures and standard fertilization. The organic matter content increased and while the exchangeable cation decreased when the lignite mixed with amino acid solution and the loss in quantity of chemical fertilizer applied at paddy field. Incase of these treatments, pH and available phosphorus increase at upland field, but did not change at paddy field.

The Use of Green Manure Crops as a Nitrogen Source for Lettuce and Chinese Cabbage Production in Greenhouse (녹비작물의 토양환원이 상추 및 얼갈이 배추의 수량에 미치는 영향)

  • Lim, Tae-Jun;Kim, Ki-In;Park, Jin-Myeon;Lee, Seong-Eun;Hong, Soon-Dal
    • Korean Journal of Environmental Agriculture
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    • v.31 no.3
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    • pp.212-216
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    • 2012
  • BACKGROUND: Green manure and graminaceousmanure crops have several benefits, such as improving soil physical and chemical properties and utilizing excessive greenhouse nutrients that they have a potential to be a water pollutant source. METHODS AND RESULTS: The objective of this study was to investigate nitrogen (N) supplying capabilities of green manure and graminaceous manure crops for lettuce (Lactuca sativa L.) and Chinese cabbage (Brassica campestris L.) grown under greenhouse conditions. For this two leguminous manures (Crotalaria juncea (Cr.) and Sesbaniaexaltata (Se.)) and two graminaceous manures (Sorghum bicolor; Haussolgo(Ha.) and Sudangrass (Sg.)) in the greenhouse were grown, cut, and incorporated into the greenhouse soil before planting. Chemical nitrogen (N) fertilizer rate was estimated based on N recommendation for lettuce and Chinese cabbage. 100% of the N recommended rates (1N) were 70 kg N $ha^{-1}$ for lettuce and 60 kg N $ha^{-1}$ for Chinese cabbage and 50% of the N recommendation rates (0.5N) were 35 kg N $ha^{-1}$ for lettuce and 30 kg N $ha^{-1}$ for Chinese cabbage. Nitrogen treatments were control (0N), Cr., Se., Cr + 0.5 N, Se + 0.5 N, Ha + 0.5 N, Sg + 0.5 N, and N recommendation rate (1N). Incorporated N from green manure and graminaceous manure crops were 130, 116, 93, and 87 kg N $ha^{-1}$ for Cr., Se., Ha., and Sg., respectively. Lettuce and Chinese cabbage were grown after incorporated green manure crops into the greenhouse soil. There was no significant difference in lettuce and Chinese cabbage yields under N treatments except control (0 kg/ha). Nitrogen use efficiency (NUE)was from 44% to 73% and the highest NUE was under Se. treatment. Although yields were not statistically different under N treatments except control, actual yield increase ranged from 170 to 1,100 kg/ha for lettuce and ranged from 2,770 to 5,210 kg/ha for Chinese cabbage compared to yield under N recommendation rate. Estimated economic benefit from this would be higher approximately between \2,770,000 and \5,210,000/ha under N treatments except control than the N recommendation rate. CONCLUSION: These results suggest that incorporating green manure crops, such as Cr. and SeSe. into soil or adding 0.5 N after incorporation of them can be beneficial in many ways in that it increases economic return because of yield increase, reduces the use of chemical N, and decreases the negative environmental impact on water quality because excessive N in the greenhouse soil can be used by green manure crops during the fallow.

Effect of Mixed Cultivation of Green Manure Crops on Mineral Nutrients, Microbial Activities, Weed Occurrences and Yields of Red-pepper (토양 무기양분, 미생물활성, 잡초발생 및 고추수량에 대한 녹비작물 혼파효과)

  • Sung, Jwa-Kyung;Lee, Sang-Min;Lee, Yong-Hwan;Lee, Youn;Lee, Ju-Young;Jang, Byong-Choon
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.301-301
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    • 2009
  • 겨울철 농경지 이용율 제고 및 자연경관 조성을 위하여 녹비작물을 재배하는 면적이 지속적으로 증가하고 있는 추세이다. 그 동안 녹비작물에 대한 연구는 주로 파종적기, 작물에 대한 양분공급효과 및 타감 효과 등에 집중되어왔다. 본 연구에서는 토양 중 양분공급 및 미생물활성의 경시적 변화, 잡초억제 및 작물생육에 대한 녹비작물의 투입효과를 알아보기 위하여 수행하였다. 국립농업과학원 구내포장에서 2007년 9월 하순에 헤어리베치(8kg/10a)와 호밀(10kg/10a) 종자를 파종한 후, 이듬해 4월 하순에 수확하여 토양에 환원하였다. 질소공급량은 화학비료(15.2kgN/10a) 대비 헤어리베치(32.2kg/10a, 212%), 호밀(9.2kg/10a, 60%) 및 헤어리베치+호밀(15.5kg/10a, 102%)로 헤어리베치의 질소공급효과가 매우 높았다. 토양 무기태질소 함량은 녹비 처리 후 30일경에 최대에 도달하였으나, 호밀 처리구는 조사기간 동안 큰 변화가 없었다. 토양 유기물 함량의 변화는 시험 전(10DBI)과 비교하여 큰 차이를 보이지 않았으나, 녹비환원 후 10일경에 일시적으로 감소하는 경향을 보였는데 이는 녹비환원 후 토양경운에 의한 영향으로 판단되며, 무기태질소와는 달리 호밀처리구의 유기물함량이 지속적으로 증가하는 경향을 보였다. 토양 탄수화물(수용성 당)은 시험 전에 가장 높았으며, 시간의 경과와 함께 서서히 감소되는 양상을 보였으며 토양 미생물탄소 및 미생물질소의 양은 녹비처리구가 화학비료 처리구에 비해 높았으며 녹비환원 후 50일 까지는 증가하다가 그 이후에 감소하는 경향을 보였는데 이는 토양의 무기태질소 및 탄수화물과 밀접한 관계가 있는 것으로 판단되었다. 녹비처리 후 85일경에 잡초발생량을 조사한 결과, 화학비료 처리구에 비하여 헤어리베치 처리구는 40%, 호밀 처리구는 68%, 헤어리베치+호밀 처리구는 40%의 잡초억제효과가 있었다. 고추과의 수량은 화학비료 처리구(702kg/10a)>헤어리베치(694kg>10a)>헤어리베치+호밀(361kg/10a)>호밀(179kg/10a)의 순으로 나타났다.

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Compositional Characterization Analysis of Wall Soils Excavated in Poongnatoseong Earthen Castle, Seoul (풍납토성 성벽 토양의 성분 특성 연구)

  • Seo, Min Seok;Lee, Han Hyeong;Hu, Jun Soo;Kim, Soo Keung;Yoo, Young Mi;Lee, Seong Jun
    • Korean Journal of Heritage: History & Science
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    • v.45 no.4
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    • pp.114-125
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    • 2012
  • The purpose of this study is to analysis chromaticity, granulometry, main chemical composition and mineral crystal structure of wall soils excavated from Poongnatoseong Earthen Castle using color reader, XRD, particla size analyzer. The analysed soils of Poongnatoseong Earthen Castle were yellowish brown and isabella. All samples were sands or sands including silty soil(SW~SC) and showed similar granulometry, chemical composition and mineral crystal structure, which were characteristics of construction materials suitable for modern road or airstrip. As resulting in comparison with 4 factors from chromaticity, granulometry, main chemical composition and mineral crystal structure, we decided that the control soils(PNS) near by Poongnatoseong Earthen Castle were not to be used for the castle wall construction We presumed that there was a huge soil distribution area for the wall construction around Poongnatoseong Earthen Castle. For further study, we will make a comparison analysis all kinds of soil characteristics. And then we can understand correctly about wall soils producing area, construction method, repair method and time of Poongnatoseong Earthen Castle.

지하수 관측망과 다중패커시스템을 이용한 심부지하수 모니터링

  • 유시원;고용권;김건영;박경우;배대석;정찬호
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.354-357
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    • 2004
  • 방사성폐기물 처분 연구의 일환으로 대전 유성북부 화강암 지역내 200~500m 심도를 갖는 9개의 심부 시추공이 착정되었으며, 이중 3개 시추공에 대하여 다중패커시스템이 설치되어 장기적으로 심도별지하수의 수리특성, 화학특성 및 동위원소 특성이 모니터링 되고 있다. 다중패커시스템이 설치되기 전의시추공 지하수의 수리 및 지화학 특성은 심도에 따라 별다른 특성이 보이지 않지만, 다중패커시스템 설치 후, 심도에 따라 특징적인 수리 및 지화학특성을 보여주고 있다. 또한, 다중패커시스템이 설치된 시추공의 경우, 최상부 구간을 제외하고 모든 구간 지하수의 수리화학특성은 일정기간이 경과한 후에는 각 구간별로 거의 일정한 값으로 유지되고 있음을 보여준다. 그러나, 지하수의 함양특성이 크게 변하는 우기 동안에는 지하수 수두압이 심도 약350m의 구간까지 변화되는 특성을 보여주고 있다. 동위원소특성 역시 심도구간에 따라 특징적인 값을 보여주며, 장기적으로 일정한 구간별 특정 값을 보여주고 있다.

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pH Dependence on EC in Soils Amended with Fertilizer and Organic Materials and in Soil of Plastic Film House (비료와 퇴구비를 처리한 토양과 시설재배지 토양에서 토양의 EC에 따른 pH변화)

  • Kim, Yoo-Hak;Kim, Myeong-Sook;Kwak, Han-Kang
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.5
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    • pp.247-252
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    • 2005
  • Soil pH is an intensity factor of releasing hydrogen ion which is buffered by aluminum. It depends on pH buffer capacity of Al whether soil pH is governed directly by cations or not. A study was conducted to elucidate the pattern of pH changes by soil EC. Fertilizer and three kinds of organic manures composed of cow and pig and fowl dropping and one kind of rice straw compost were added independently into upland sandy loam soil. This treated soils and four upland soils under plastic film house having different levels in electrical conductivity (EC) were incubated with field capacity at $30^{\circ}C$ for 5, 10, 20 and 40 days. Soil pH varied directly as the cations contained in organic materials according to degree of saturating pH buffer capacity (pBC) of sandy loam soil. pH of the soils under plastic film house was lowered by soil EC due to governing by overplus of cation beyond pBC.

Effect of Organic Fertilizer Application on the Chemical Properties of the Orchard Soils and Apple Yield (사과원에서 유기질비료시용이 토양화학성 및 사과 수량에 미치는 영향)

  • Choi, Jyung;Lee, Dong-Hoon;Choi, Choong-Lyeal
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.393-397
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    • 2000
  • This study was conducted to find out the effect of long-term compost application on the chemical properties of the orchard soils and apple quality. The contents of P and cations in soils were increased by the application of compost, while there are no difference in that of organic matter. The increase in application rates of compost resulted to the increase in apple yields, however, firmness and Brix of apple were as not differentiated by the compost application. The application of lower chemical fertilizer and higher compost resulted to the increase in the contents of organic matter and Ca in soils. The compost application resulted to the increase in inorganic material contents in soil but was not effective on the quality of apple fruits.

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