• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.04a
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• pp.283-286
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• 2002

유류로 오염된 부지에 토양세정기법을 적용하기 위한 전 단계로, 실험실 규모의 컬럼실험을 통하여 pilot 규모 현장 적용을 위한 설계인자 및 최적 운전조건을 규명하고자 적정 세척제 종류와 농도, 배합비 및 세정용액 주입유량을 고찰하였다. 회분식실험 결과 POE$_{14}$와 SDS(1:1)를 1%로 적용한 흔합계면활성제의 효율이 가장 우수하였으나, 예비실험 결과 음이온계 계면활성제인 SDS는 미생물에 독성을 끼치는 경향이 있는 것으로 나타나 같은 농도에서 효율이 거의 유사한 POE$_{5}$와 POE$_{14}$ 혼합계면활성제를 이용하여 실험하였다. 선정된 혼합계면활성제를 적용하여 디젤 오염토양 세척능력을 검토한 결과 세척제 농도 1%까지는 효율이 증가하다가 1% 이상의 농도에서는 다시 감소하는 경향을 나타내었으며, 계면활성제 배합비는 1:1로 혼합하였을 경우 세척효율이 가장 우수하였다. 따라서 POE$_{5}$와 POE$_{14}$ (1:1) 1% 혼합계면활성제를 세척제로 선정하였다. 컬럼실험 결과, 주입 flux가 클수록 세정 제거된 총 유류의 양이 증가하였으며, 같은 pore volume의 세정용액 통과 시에는 flux가 작을수록 제거효율이 좋았다.

• Resources Recycling
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• v.20 no.3
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• pp.28-39
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• 2011

This review investigated theoretical principals and practical application examples on recirculation system of soil washing-wastewater treatment-treated water recycling. As for technologies which have attempted to remediating metals-contaminated soil in and around country, there are reactive barriers, encapsulation, solidification/stabilization, soil washing, and phytoremediation. Among those, in particular, this review covers soil washing technology which physicochemically removes contaminants from soils. The major drawbacks of this technology are to generate a large amount of wastewater which contains contaminants complexed with ligands of washing solution and needs additional treatment process. To solve these problems, many chemical treatment methods have been developed as follows: precipitation/coprecipitation, membrane filtration, adsorption treatment, ion exchange, and electrokinetic treatment. In the last part of the review, recent research and field application cases on soil washing wastewater treatment and recycling were introduced. Based on these integrated technologies, it could be achieved to solve the problem of soil washing wastewater and to enhance cost effective process by reducing total water resources use in soil washing process.

• Journal of Soil and Groundwater Environment
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• v.13 no.1
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• pp.60-66
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• 2008

Laboratory soil washing experiments with HCl or EDTA were conducted to remediate lead-contaminated soil in a firing range. After lead bullets were removed by standard sieve #18 (1.0 mM), Pb concentrations were measured by EPA Method 3050B (9,443 mg/kg) and Korea Standard Test (4,803.5 mg/kg). The results of the batch test showed that the removal efficiency curve was logarithmic and approximately 90% of lead in soil was removed, when HCl was used. In case of EDTA, the removal efficiency increased proportionally to the concentration of EDTA, up to 98% lead removal with 0.1M EDTA. High mixing strength resulted in increase of removal efficiency and kinetics showed that the most lead was extracted in 10 min.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1997.05a
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• pp.74-78
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• 1997

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1997.05a
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• pp.57-60
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• 1997

• Journal of Korean Society of Environmental Engineers
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• v.27 no.10
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• pp.1072-1080
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• 2005

The extraction characteristics of heavy metals(HM) from a contaminated soil at existing lead smelters were investigated with ethylene diamine tetraacetic acid(EDTA), citrate and HCl as washing solutions. EDTA was more effective for Pb than for other heavy metals. As the mol ratio of EDTA/HM increased, the removal efficiency of heavy metals became higher. When the mol ratio of EDTA/HM approached to 6.5, it removed Pb most effectively. Citrate was effective especially in extracting Zn. The removal efficiency of HCl was comparatively high in almost all heavy metals, and at 0.3N concentration it was the highest. After soil washing process by the use of EDTA, the great part of exchangeable fractions and most of heavy metals of weakly adsorbed like carbonate fraction were extracted. For washing with citrate and HCl, four heavy metals showed the similar exchange of chemical partitioning and the exchangeable fractions of Pb which has weakly adsorbed to soil were more increased than before the process. As removal efficiency of citrate washing process depends upon the distribution of non-detrital fractions, so it can be contended that only the amount of non-detrital fractions could be removed from all the heavy metal content. EDTA and HCl could remove most of non-residual fractions in all heavy metals except Zn. As a result of EDTA washing, toxicity characteristic leaching procedure(TCLP) concentration of the processed soil met the USEPA Pb limit of 5.0 mg/L.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.4
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• pp.171-176
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• 1998

The effect of non-ionic surfactants added by hydroxides was studied to wash HOCs-contaminated soil. The kinds and concentrations of additives-mixed surfactants suitable for the soil washing were found. The effects of temperature on the soil washing were analyzed and the relations of HLB and cloud point were estabilished. As the base strength was increased, the washing efficiency was increased : NaOH＞KOH＞ Mg(OH)$_2$>Al(OH)$_3$. Washing efficiency was not enhanced by Al(OH)$_3$for coagulation effect. When NaOH was added to POE$\_$5/ washing efficiencies by 0.01 M and 0.1 M solutions were increased to 62.5% and 67.3%, respectively. At 1 M of NaOH washing efficiency was decreased to 4.2%. The Optimum concentration ratio of mixed surfactant ［POE$\_$5//POE$\_$14/] was 1.8%/1.2% without additives. But optimum concentration ratio of surfactants was changed to 1.2%/1.8% with 0.01 M of NaOH addition. The surface tensions and CMCs of mixed surfactant added by NaOH solutions were investigated. The addition of NaOH reduces the surface tension of more hydrophobic surfactants. The nonionic surfactant of higher HLB showed highed cloud point.

• Journal of Soil and Groundwater Environment
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• v.14 no.2
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• pp.17-25
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• 2009

The applicability of soil washing/flushing to treat a contaminated soil with cadmium (Cd) and copper (Cu) using a mixture of organic/inorganic extractant was evaluated in laboratory-scale batch and column tests. Citric acid was the effective extractant to remove Cd and Cu from the soil among various organic acids except EDTA. Carbonic acid was chosen as inorganic extractant which was not only low toxicity to environment, but also increasing soil permeability. Moreover, the optimum ratio of organic and inorganic extractant to remove Cd and Cu was 10 : 1, and this ratio of organic and inorganic extractant achieved removal efficiencies of Cd (46%) and Cu (39%), respectively. The increasing flow rate of extractant could explain the phenomena of soil packing when carbonic acid was used with organic extractant (i.e. EDTA and citric acid). Therefore, a mixture of organic extractant with inorganic extractant, especially carbonic acid, could resolve a problem of soil packing when this extractant was applied to a field application to remove Cd and Cu using in-situ soil flushing process.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.04a
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• pp.44-48
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• 2002

Washing technique using solubilization and surfactant as a extractant was studied by removing contaminants from the cohesive soil contaminated with heavy metal. For this purpose, the laboratory desorption batch tests were peformed in the kaolinite contaminated with lead by using acetic acid as a solubilization and SDS as a anionic surfactant. In desorption batch tests, the effects of extractant concentration and mixing ratio were investigated and also the coupling effects of acetic acid added with surfactant were considered. Test results show that the removal efficiency of acetic acid as a extractant in the kaolinite contaminated with lead increased with increasing the concentration of acetic acid and the acetic acid was found to be more effective when adding CMC 2 or 3 of surfactant. Additionally, regardless of the initial concentration, the efficiency of lead removal from the contaminated soil increased with increasing shaking ratio.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.1
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• pp.30-36
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• 1998

For successful soil flushing process selection of appropriate flushing reagents is essential. Futhermore, obtaining operating parameters for site remediation application through various bench-scale tests is also important. In this research a series of organic acids (acetic, citric, oxalic, and succinic acids) were tested for flushing capability. Copper-contaminated natural soil was used as a test medium, and flushing experiments were performed with batch system. All the organic acids used did not provide effective flushing conditions at concentration of 1 mM. At the acid concentration of 50 and 100 mM copper was removed efficiently although 50 and 100 mM did not show any significant differences in removal efficiencies. Citric acid and oxalic acid removed copper more efficiently than the others, and especially, citric acid showed over 87% of removal efficiency of copper at near neutral pH of 5 to 7. Speciation of extracted copper using GEOCHEM simulation showed majority of extracted copper existed as complexed with organic acids and only small portion of organic acids were complexed with copper indicating promising application of soil flushing with organic acid to heavy metal-contaminated site remediation.