• 제목/요약/키워드: 탈색

검색결과 300건 처리시간 0.024초

불용성 전극을 이용한 Rhodamine B의 전기화학적 탈색 (Electrochemical Decolorization of a Rhodamine B using Dimensionally Stable Anode)

  • 김동석;박영식
    • 한국물환경학회지
    • /
    • 제23권3호
    • /
    • pp.377-384
    • /
    • 2007
  • This study has carried out a performance of dimensionally stable anode for the purpose of decolorization of Rhodamine B (RhB) in water. Seven kinds of 1, 2 and 3 component electrodes were prepared by plating and thermal deposition, which were coated by the oxides of Pt, Ru, Ir, Sn-Sb, Ir-Sn-Sb, Ru-Sn-Sb and Ru-Sn-Ti on Ti metal surface, respectively. Performance for RhB decolorization of the seven electrodes lay in: Ru-Sn-Ti/Ti ${\fallingdotseq}$ Ru-Sn-Sb/Ti > Ir-Sn-Sb/Ti > Sn-Sb/Ti > Ru/Ti > Ir/Ti > Pt/Ti. The effects of electrode area and distance, electrolyte type and concentration, current density and pH were investigated on the decolorization of RhB using Ru-Sn-Ti/Ti electrode. Decolorization of RhB was not influenced by electrode area and distance largely, however wattage was influenced by them. NaCl was superior to the decolorization of RhB than $Na_2SO_4$. Optimum NaCl dosage and current density were 0.5 g/L and $0.183A/cm^2$, respectively. The pH effect of decolorization of RhB was not significant within the range of 3-7.

백강잠(Bombyx Mori Linne) 물추출물의 미백 효능 (The Whitening Effect by Water Extracts of Bombyx Mori Linne)

  • 안영희;최정숙
    • 한국패션뷰티학회지
    • /
    • 제4권4호
    • /
    • pp.81-86
    • /
    • 2006
  • Numerous novel ingredients have been introduced for the hight functionality of whitening cosmetics. Tough the preliminary research, we have found water extracts Bombyx mori have high whitening efficacy. The results of the research for the whitening effect of Bombyx Mori L. are as follow 1. Bombyx Mori L. inhibited concentration dependently the generation of melanin increased by the stimulation of $\alpha$-MSH and protoporphyrin IX, and $IC_{50}$ value was 8.3, 9.2 ${\mu}M$ respectively. 2. Melanin increased by the stimulation of $\alpha$-MSH and protoporphyrin IX was five to seven times superior in the inhibiting effect, compared with kojic acid used as positive control group. 3. Bombyx Mori L. did not have a decolorizing effect on melanin already generated. 3. Bombyx Mori L. was observed to have toxicity of over 100 ${\mu}M$ for the mouse melanoma B16 cells. Therefore, These results suggest that water extracts of Bombyx mori have inhibitory activity against mushroom tyrosinase and inhibitory activity of melanin synthesis in B16 melanoma cells in vitro.

  • PDF

산성염료에 의한 모발염색에서 용매의 효과 (Effect of solvent in hair dyeing with acid dye)

  • 최창남;이진;허진영
    • 한국염색가공학회:학술대회논문집
    • /
    • 한국염색가공학회 2011년도 제44차 학술발표회
    • /
    • pp.64-64
    • /
    • 2011
  • 모발(human hair)은 양모섬유와 마찬가지로 시스틴을 많이 함유하고 있는 섬유상 케라틴 단백질로써, 두부(頭部)를 보호할 뿐만아니라 신체에 필요하지 않는 중금속을 체외로 방출하는 기능을 지닌 신체의 일부분이다. 또한 모발은 미(美)와 관련하여 가장 관심을 가지는 부분이며, 다양한 방법으로 모발에 변화를 주어 신분을 표시하거나 자신의 미적 표현을 하고 있다. 퍼머넌트 웨이브는 모발에 형태학적 변화를 주는 유효한 수단이며, 염색과 탈색 등은 색상 변화를 주는 중요한 수단이다. 본 연구 에서는 모발을 산성염료로 염색할 때 염색성을 향상시키기 위하여 염색보조제로써 벤질알콜 등을 첨가하여 염색할 때 염색된 모발의 염착량, 보습성, 단백질 유출성, 주사전자 현미경 관찰을 측정하여 다음과 같은 결과를 얻었다. 1) 염색시간이 길어지고, 염색온도가 높아질수록 모발에의 염착량은 증가하며, 특히 벤질 알콜을 첨가하여 염색하는 경우에는 빠른 시간내에 염착평형에 도달하고 비교적 낮은 염색온도에서도 높은 염착량을 나타내었다. 2) 이와같은 용매 첨가의 효과는 염액에 계면활성제와 함께 첨가하여 염색하면 나타나지 않았다. 3) 염색시간이 길어질수록 모발의 보습성은 열악해지지만, 벤질 알콜을 첨가하여 염색하는 경우에는 오히려 보습성이 증가하였다. 또한 염색시간이 길어지면 모발의 단백질 유출성은 증가하지만, 벤질 알콜을 첨가하여 염색하는 경우에는 오히려 단백질 유출성이 감소하였다. 이와같은 결과는 벤질 알콜을 첨가하여 염색하는 경우에 모발의 손상이 적다는 것을 의미한다. 4) 모발의 손상정도에 대한 주사전자현미경의 측정결과는 벤질 알콜의 첨가여부에 따라 큰 차이를 보이지 않았다.

  • PDF

Aspergillus sojae B-10에 의한 반응성 염료의 탈색조건 (Continuous Biodegradation of Reactive Dyes by Aspergillus sojae B-10)

  • 류병호;김동석;안성만;원용돈;정종순
    • 한국환경보건학회지
    • /
    • 제21권4호
    • /
    • pp.10-16
    • /
    • 1995
  • Dyes are released into the environment from industrial wasterwater. They are considered to be a pollution problem because of the wide spread into environment with a variety of colors. In order to biological treatment of industrial dyes waste water, biodegradation of reactive dyes such as Rifacion Red H-3EB, Rifazol Blue BT, Rifacion Yellow P-4G and Rifacion Brown RT were carried out decolorized by Aspergillus sojae B-10. Aspergillus sojae B-10 showed the almost completely biodegradation ability when it was cultivated in a 2.0% glucose, 0.06% sodium nitrite, 0.1% $KH_2PO_4$, 0.5% $MgSO_4\cdot 7H_2O$ containing each reactive dyes (500 ppm) under the optimal conditions of 32$\circ$C and pH 5. The mycelium of Aspergillus sojae B-10 was produced extracellular enzyme which has concerned responsible for dyes biodegradation. Under optimal conditions, reactive dyes started being decolorized within 24 hr and its was almost decolorized c ompletely after 5 days incubation. Rifazol blue RT was not completely decolorized until 5 days of cultivation. Rafacion Red BT, Rifasol blue BT and Rifacion yellow P-4G were completely decolorized after 5 days cultivation.

  • PDF

회전원판 반응조에 고정화시킨 Aspergillus sojae B-10에 의한 반응성 염료의 탈색 (Biodergradation of Reactive Dyes Using Multistage Rotating Disc Contactor Immobilized by Aspergillus sojae B-10)

  • 류병호;김동석;진승록;정종순;원용돈
    • 한국환경보건학회지
    • /
    • 제21권4호
    • /
    • pp.49-55
    • /
    • 1995
  • Dyes are released into the environment as industrial wasterwater. Dyes are considered to be a pollution problem because of the wide spread into environment with a variety of colors. Continuous biodegradation of reactive dyes such as Rifacion Red H-3EB, Rifazol Blue BT, Rifacion Yellow P4G and Rifacion Brown RT were demonstrated using multistage rotating disc contactor immobilized by Aspergillus sojae B-10. Aspergillus sojae B-10 was cultivated the optimal medium containing 2.0% glucose, 0.08% $NaNO_3$, 0.1% $KH_2PO_4$ and 0.5% $MgSO_4\cdot 7H_2O$, pH 5 at 32$\circ$C. Mycelium of Aspergillus sojae B-10 were guck to the rotating disc for 10 days until steady state. For continuous biodegradation of reactive dyes by using rotating disc contactor, it was most effective biodegradation in the medium containing 1,000 ppm each dyes at the medium feeding rate of 20 ml per hour. Under the conditions biodegradation of each dyes on 2, 4 and 6 days were 20~50%, 75% and 96%, respectively. Therefore, practical application of reactive dyes were carried out at the feeding rate of 20 ml/h as synthetic wasterwater containing 500 ppm of mixture reactive dyes. It was found the highest levels of 94% biodegradation during 20 days.

  • PDF

스펀지에 고정한 광촉매를 이용한 안료의 탈색 (Decolorization of Dye Using Immobilized Photocatalyst onto Sponge)

  • 김동석;박영식
    • 한국환경보건학회지
    • /
    • 제31권5호
    • /
    • pp.415-422
    • /
    • 2005
  • The photocatalytic decolorization of Reactive Red 2B(RR2B) was studied using immobilized photocatalyst/UV System. Two pairs of 20 W UV-B and UV-C lamps were employed as the light source. Immobilization of $TiO_2$ was carried out using sponge (as the photocatalyst body) and silicone sealant(as the binder). The effects of parameters such as the thickness, pore size of sponge photocatalyst and attached material on the reactor bottom were investigated. The results showed that the optimum thickness of sponge photocatalyst was 1 cm. Decolorization of reactor which had the bottom coated $TiO_2$ was higher than that of reactor attached aluminum plate. Decolorization of photocatalyst with large pore size(mean pore size, 3.8 mm) was higher than that of the small(mean pore size, 1.75 mm). Initial decolorization of RR2B could be descrived using the Langmuir-Hinshelwood(L-H) model and gave constant values of $0.55mg/l{\cdot}min(k)\;and\;2.65{\times}10^{-2}l/mg(K)$, respectively.

비금속 자원 재활용을 위한 전해부상 장치를 이용한 고농도 유기질 폐수의 재활용에 관한 연구 (A Study on Recycle of Concreted Organic Waste water by Electroflotation Apparatus for Resource Recycle of Non-Metal)

  • 김기준;남상성
    • 한국응용과학기술학회지
    • /
    • 제29권4호
    • /
    • pp.653-658
    • /
    • 2012
  • 고농도 유기질 폐수처리를 위해 전기화학적 방법의 사용에 있어 관심이 고조되고 있다. 전기화학적 방법의 기술은 음식물폐수 및 공업적 폐수 문제를 해결하는데 이상적 처리 방법이다. 다른 화학적 처리 방법과는 다르게 전기화학적 처리장치는 2차 폐수의 부피를 증가시키지 않고 용수와 유기질 비료로 재활용한다. 전기화학적 방법은 전해부상장치를 무기화학적 약품과 병행하여 더욱 효과적으로 음식물 폐수를 처리한다. 이 연구는 2차 처리로 초음파와 오존처리로 탈색, COD와 BOD가 격감함으로 용수 및 유기질 비료로 활용하도록 실험하였다.

여대생들의 모발상태와 모발관리습관 (A Study on Hair Condition and Hair Control among College Female Students)

  • 노영희
    • 한국식품영양학회지
    • /
    • 제12권6호
    • /
    • pp.588-591
    • /
    • 1999
  • 현대여성들은 모발상태에 관심이 많으나 정확한 모발분석을 해주는 곳도 드물고 자신의 모발상태에 관한 상담이나 지식을 전달받을 곳도 많지않은 실정이다. 따라서 본 연구는 1999년 10월 2일부터 -10월 6일까지 청주시내 거주하는 여학생을 대상으로 모발의 자가진단과 모발관리방법 모발에 대한 무제점 등을 파악하고 올바른 모발관리 습관을 갖는데 도움이 되고자 실시되었다. 본 연구 결과는 다음과 같다. 1. 연구대상자의 일반적 특성은 연령별 분포는 18세 -20세가 65,9% 21-30세가 30.9% 31세이상이 3,4%였다 2. 대상자들ㅇ의 모발상태는 손상모가 51.9%였으며 건강모가 21.6%로 손상모의 비율이 높았다. 3. 모발손상의 원인은 염색·탈색·퍼머의 시술이 47.1%로 가장높았고 드라이의 비율이 22.3%였다. 4. 모발이 자라는 정도는 잘 자란다가56,7%였다. 5., 현재 모발에 대한 가장 큰 관심거리는 머리결로 나타났고 헤어스타일도 높은 비중을 차지하였다. 6. 모발의 손질 횟수는 1주일에 한번이 32,3%로 가장 일반적이었고 대상자들의 33%는 모발손질을 전혀하지 않았다. 7. 모발의 손상도가 높을수록 모발관리벙법이나 횟수와 유의한 관련성이 있었다(P<0.05) 모발의 손상도가 심할수록 모발관리에 관심을 가졌고 모발관리 횟소도 많았다

탈색시술 조건에 따른 모발의 물성변화 (Physical Properties of Human Hair by the Bleach)

  • 윤종현;김호정;이영주;박차철
    • 한국의류산업학회지
    • /
    • 제7권1호
    • /
    • pp.96-100
    • /
    • 2005
  • The bleaching is one of the worst factors which leads to the damage of the human hair. The cuticle of the human hair is injured by the alkali that is one of the chief ingredients of a bleaching agent. The alkali component of the bleaching solution chemically reacts with human hair, reducing the tenacity and dissolving the cuticle layer. The purpose of this study is to examine the effects of bleaching time and temperature on the physical properties and morphology. The results were as follows. 1. The stress-strain curves for human hair indicated the three distinct regions, such as Hookean region, Yield region and post-Yield region. The tenacity of hair is reduced gradually with an increase of bleaching time. Under these same conditions, elongation of the hair increased. 2. The greatest drop in tenacity for hair occured between $40^{\circ}C$ and $60^{\circ}C$ of bleaching temperature. 3. Compared with the virgin hair, bleached hair showed a slower rate of weight reduction in the TGA thermogram. The rate decreased gradually as the bleaching time and temperature increased. 4. As the bleaching conditions reached time and temperature extremes, the human hair cuticle became more damaged. The cuticle layers seemed to have dissolved, as seen in the SEM photographs.

모발의 퍼머넌트 웨이브 형성 및 탈색에 미치는 열 함유 로드의 영향 (A Study of Effects of Heated Rods on Formation of Perm Waves and Hair Bleach)

  • 전현진;정찬이;임순녀
    • 한국염색가공학회지
    • /
    • 제26권1호
    • /
    • pp.63-70
    • /
    • 2014
  • This study has attempted to figure out the effects of the surface heat of perm rods on hair. For this, after forming perm waves, hair damage and its causes have been investigated with a different hair bleach method. If hair was bleached immediately without shampooing after a perm using the heat of rods, great perm waves were formed. However, severe damage was found on the hair because of the heated rods. In addition, when hair was shampooed and dried after the perm, hair bleach was more effective. It has been confirmed that hair was damaged because of high temperature of the surface of the rods. In fact, the heated rods had a direct effect on hair damage. According to these results, it has been confirmed that heat-based perms can accelerate hair damage. Therefore, it is necessary to perform a study on the minimization of the heating of permanent tools.