• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.844-847
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• 2009

진공압출성형 공정을 이용하여 한쪽 끝단이 막힌 다공질 탄화규소 캔들 필터를 단일공정으로 제조하는 기술을 확립하였다. 캔들 필터 지지층의 특성 최적화를 위해 탄화규소 출발입자와 무기바인더의 첨가량 변화를 통해 기계적 특성과 기공크기 등의 분석을 수행하여 상용 캔들 필터의 수준에 대응할 수 있는 조합을 도출하였다. Mullite와 clay를 소결조제로 사용하고, $30{\mu}m$ 입도의 탄화규소 입자로 지지층을 제조한 경우, 30% 이상의 기공율을 보유하면서 50 MPa 이상의 상온 3점 굽힘강도를 나타낼 수 있는 조건이 확립됨에 따라 $125{\mu}m$ 입도의 탄화규소와 bi-modal로 사용할 경우, 상용제품의 특성을 상회하는 탄화규소 캔들 필터가 제조될 수 있음을 확인하였다.

• Korean Chemical Engineering Research
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• v.43 no.6
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• pp.683-690
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• 2005

The microwave carbonization of rice chaff was performed, and their kinetics were compared to those of conventional thermal carbonization. Thermal carbonization was carried out at $300-600^{\circ}C$ for 30 minutes. The weight loss and C/H mole ratio remarkably increased as increase of temperature, while there was no carbonization by microwave dielectric heating in spite of increasing incident power and irradiation time. However, microwave carbonization was successfully performed by addition of 6 wt％ of thermal carbonized rice chaff, it's C/H mole ratio is larger than 3.0, as a catalytic initiator to uncarbonized rice chaff, and the kinetics was depended on the incident power and irradiation time, resulting in the coincide with thermal carbonization to the Arrhenius equation. The activation energy of microwave carbonization was quite low as compared to that of thermal carbonization, while the kinetic constant was large. This is due to the internal volumetric heating characteristics of carbonized rice chaff by microwave. The effect of ash, and C/H mole ratio and amount of carbonized rice chaff were investigated on microwave carbonization.

• Journal of the Korean Wood Science and Technology
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• v.30 no.4
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• pp.33-40
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• 2002

This research was to investigate the adsorption characteristics of charcoals of major Korean wood species (thinned trees) and wood-based materials. As carbonization time and temperature increased, methylene-blue adsorption (MBA) of charcoals of thinned trees and wood-based materials increased. Pinus koraiensis charcoal showed the highest MBA. MBA of softwoods was higher than that of hardwoods. There was a negative correlation between air-dried specific gravity before carbonization and MBA of carbonized thinned trees. The MBA of wood-based materials showed similar value, but wood-based materials in MBA was lower than thinned woods. Surface area and total pore volume of thinned trees and wood-based materials increased as carbonization temperature increased. The species showing highest MBA appeared to have the highest surface area at the carbonization temperature of 600℃ as well. There was a positive correlation between surface area, total pore volume and MBA of charcoals. The charcoal of wood-based materials generally exhibited micro pores.

• Resources Recycling
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• v.23 no.5
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• pp.28-35
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• 2014

The basic properties of cow and chicken manure such as proximate analysis and element analysis were estimated and the comparison to energy characteristics of carbonization residue between cow and chicken manure was evaluated. The optimum carbonization condition of cow and chicken manure was decided by total heating value of carbonization residue which was expressed by multiplying low heating value by yield. The optimum carbonization conditions for carbonization time and temperature can be decided by 15 min, and $350^{\circ}C$ for chicken manure, and 20 min, and $300^{\circ}C$ for cow manure. At the optimum carbonization conditions, low heating values for the carbonization residue of cow and chicken manure are evaluated by 4,378kcal/kg, and 3,462kcal/kg, respectively. The residues of cow manure were satisfied with the standard of solid fuel product. However, the residue of chicken should be improved by materials changes to be used as a renewable energy source.

• 한국신재생에너지학회:학술대회논문집
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• 2005.11a
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• pp.446-461
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• 2005

본 연구에서는 반응소결 탄화규소 다공질 지지체 개발을 위하여 SiC/C로 이루어진 성형체를 사용한 Si melt infiltration 공정 및 SiC/C/Si으로 이루어진 성형체를 사용하는 Si embedding 공정 개발이 이루어졌다. 개발된 반응소결 탄화규소 다공질 지지체의 기공률은 38% 이상이었으며 평균기공은 130 ${\mu}m$ 크기이었다. Si melt infiltration 방법으로 제조된 반응소결 탄화규소 다공질 지지체의 파괴강도는 상용 반응소결 탄화규소 지지체의 파괴강도보다 최대 200% 이상 높게 나타났다. 본 연구에서는 용융 Si의 침윤공정을 이용하여 반응소결 탄화규소 여과층을 갖는 반응소결 탄화규소 필터 및 그 제조공정이 개발되었다. 개발된 반응소결 탄화규소 필터의 필터 특성은 상용 탄화규소 필터의 필터 특성과 대체적으로 대등한 것으로 조사되었다.

• Journal of the Korea Institute of Building Construction
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• v.23 no.1
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• pp.23-33
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• 2023

It is widely known that the level of fire resistance of wooden structure is determined by a charring rate or charring depth, and these are adopted for fire design. In this study, specimens of domestic larch column with a lamination wooden type were prepared and the fire resistance properties such as the charring depth, load ratio and the specific charring rate suggested by EN Code investigated. Test results showed that as expected, the weakest part was the corner of the column, so that the charring depth of the corner was deeper than the other parts of the column. For the load ratio less than 0.9, it had little effect on the charring depth.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.23 no.2
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• pp.161-167
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• 2009

Organic insulating materials which are utilized as insulating materials for the low voltage show unique carbonization characteristics when they are carbonized by a leakage current. Therefore the use of the carbonization characteristics makes it possible to examine the electrical fire which is caused by a leakage current flowing on the surface of the organic insulating material. In order to understand such carbonization characteristics, in this paper, experiments have been done to carbonize typical organic insulating materials such as phenol resin, PVC, and acrylic resin, and the carbonization patterns and the IR absorption spectrum of specimens have been analyzed. According to the analysis of the carbonization patterns, the phenol resin shows the so-called 'spider-leg' carbonization pattern due to a thermosetting property. In contrast to the phenol resin, the thermoplastic property makes it difficult to observe a clear carbonization pattern to verify carbonizing causes on the surfaces of PVC and acrylic resins. In this case, the IR absorption spectrum can be analyzed to examine the specimen carbonized by a leakage current. The analysis result shows that absorption peaks appear at the wave numbers of $3,400[cm^{-1}]$ and $1,618[cm^{-1}]$, which can be an important factor to verify the carbonizing causes.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.161.1-161.1
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• 2015

복합소재는 두가지 이상의 서로 다른 물질을 조합하여, 단일 물질이 가질 수 없는 뛰어난 특성을 가진 소재로 그 중 전기 전도성 복합소재는 일반적으로 폴리머와 전도성 필러의 혼합을 통해 만들어 전자파 차폐, 대전 방지 등의 목적으로 사용되고 있다. 종류에 따라 기존 금속 소재에 비해 가볍거나 탄성율이 높은 등의 장점이 있으나 필러나 레진에 따라 재활용에 어려움이 있으며 전도성 필러로 주로 쓰이는 카본블랙 등이 석유/천연가스 등의 한정적 자원으로부터 만들어짐에 따라 환경적인 이슈가 최근 부각되고 있다. 목재는 가장 널리 쓰이는 소재 중 하나로 재생 가능하며 친환경적인 특성으로 인해 더욱 다양한 분야로의 활용이 모색되고 있다. 본 연구에서는 목재 소재의 탄화를 통해 만들어진 탄화목분의 전도성 필러로의 적용가능성을 시험하고자 CBT 레진과 탄화목분 필러의 복합소재를 제작하였다. 탄화 목분 복합소재의 전도성은 20 wt% 필러 함량 기준 카본블랙 복합소재 전도도에 20%에 이르렀으며, 전도도의 향상을 위해 필러의 플라즈마 처리 시 복합소재의 전도도가 급격히 향상되어, 카본 블랙 복합소재 전도도의 3배에 이르렀다. 플라즈마 처리가 탄화목분 복합소재의 전도도향상에 미치는 영향을 분석하기 위해 micro-CT, TGA 분석을 수행하였으며, 플라즈마 처리 시 탄화 목분 필러가 일부 미분화 되어 복합소재의 전도도를 향상하는 것으로 나타났다. 이와 같이 탄화 목분의 전도성 복합소재 적용과, 탄화목분의 플라즈마 처리를 통해 친환경적일 뿐만아니라 전도도도 우수한 복합소재를 구현하였으며, 실험적으로 전도도 향상 메커니즘을 확인하였다.

• Journal of the Korean Wood Science and Technology
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• v.44 no.3
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• pp.424-429
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• 2016

In this study, the carbonized boards were manufactured from different types of wood-based panel and then their moisture absorption/desorption properties were investigated and compared. The carbonization temperature was maximum $600^{\circ}C$ with 2 h maintains. Test results showed higher absorption/desorption capacity on carbonized plywood than carbonized MDF, PB, and OSB, respectively. However, carbonized MDF, OSB, and plywood had similar absorption/desorption rate per hour. It means carbonized OSB and plywood can transfer moisture into deeper side and then possibly hold more amount of water. Based on SEM images, carbonized OSB and plywood showed more like wood structure, while carbonized MDF and PB had only wood fiber or/and chunk of wood fragments. Therefore, original wood structure may affect moisture absorption/desorption capacity. In order to manufacture high moisture absorbing/desorbing carbonized board, wood structure should be considered and then carbonized.

• Journal of the Korean Wood Science and Technology
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• v.35 no.3
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• pp.53-60
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• 2007

Carbon content, properties of micro-pore, and chemical properties of the charcoal prepared from wood powder, wood fiber, and bark of Abies sibirica Ledeb at different temperatures were investigated. The yield of charcoal decreased with increasing the carbonization temperature. The yield of bark charcoal was higher than those of wood and wood fiber charcoal. The content ratio of carbon atom in the charcoal increased with increasing the carbonization temperature, whereas those of hydrogen and oxygen atom were decreased. Ash content of bark charcoal was also higher than those of wood and wood fiber charcoal. The specific surface area of wood and wood fiber charcoal was greater than that of bark charcoal. In all charcoal, the specific surface area and the volume of micro-pore were highest when the carbonization temperature was $600^{\circ}C$, however they tended to decrease when the temperature was reached to $800^{\circ}C$. For the functionality test of chemical groups on the charcoal surface, adsorption test have performed against acidic (HCl) and basic chemicals (NaOH, $Na_2CO_3$, and $NaHCO_3$). As carbonization temperature increased, adsorption amount of HCl increased, while adsorption amounts of NaOH, $Na_2CO_3$, and $NaHCO_3$ were decreased. The charcoal prepared at higher temperature showed basic properties, while the charcoals manufactured at lower temperature presented acidic properties. Therefore, it was considered that the carbonization temperature affected the pH of charcoal.