• Korean Chemical Engineering Research
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• v.44 no.4
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• pp.329-339
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• 2006

The production of lower olefins from methanol becomes an attractive process because of the rapid increase in crude oil price. This paper reivews the conversion mechanisms of methanol to hydrocarbons over zeolite and SAPO molecular sieve catalysts to understand the formation steps of lower olefins from methanol. The feasibility of the conversion mechanisms such as the direct mechanism based on well-defined intermediates and the hydrocarbon pool mechanism involving hydrocarbon moieties as an active centers is discussed with reepect to the induction period, the selectivity for products and the deactivation phenomena of the methanol conversion. The literature appeered since 1999 for the structure of the hydrocarbon pool and its catalytic role in the methanol conversion are summariged, and the prospect for the methanol-to-olefins process is described.

• Korean Journal of Plant Resources
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• v.10 no.4
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• pp.324-333
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• 1997

This research was conducted to determine contents of lipids and hydrocarbons for plants distributed in the sourthern region of Korea. The lipid extracts from each plants were purified by solvent fractionation, column chromatography. TLC and analyzed by gas chromatography. As a result, contents netural lipids and phospholipids were the highest in Aleurites fordii and Camellia japonica among the all plants examined. Most of the fatty acids in lipids was palmitic acid, oleic acid and linoleic acid. Content of hydrocarbon was the highest in Fatsia japonica among the all plants examined. Hydrocarbons contained in the plant was mainly more than 16 number of carbons.

• Clean Technology
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• v.28 no.4
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• pp.331-338
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• 2022

The objective of this study is to prepare bead-type and pellet-type Pt (1 wt%)/Kieselguhr catalysts as hydrogenation catalysts for the polycyclic aromatic hydrocarbons (PAHs) included in pyrolysis fuel oil (PFO). The optimal reaction temperature to maximize the yield of saturated cyclic hydrocarbons during the PFO-cut hydrogenation reaction in a trickle bed reactor was determined to be 250 ℃. A hydrogen/PFO-cut flow rate ratio of 1800 was found to maximize 1-ring saturated cyclic compounds. The yield of saturated cyclic compound increased as the space velocity (LHSV) of PFO-cut decreased. The difference in hydrogenation reaction performance between the pellet catalyst and the bead catalyst was negligible. However, the catalyst impregnated by Pt after molding the Kieselguhr support (AI catalyst) showed higher hydrogenation activity than the catalyst molded after Pt impregnation on the Kieselguhr powder (BI catalyst), which was a common phenomenon in both the pellet catalysts and bead catalysts. This may be due to a higher number of active sites over the AI catalyst compared to the BI catalyst. It was confirmed that the pellet catalyst prepared by the AI method had the best reaction activity of the prepared catalysts in this study. The majority of the PFO-cut hydrogenation products were cyclic hydrocarbons ranging from C₈ to C₁₅, and C₁₁ cyclic hydrocarbons had the highest distribution. It was confirmed that both a cracking reaction and hydrogenation occurred, which shifted the carbon number distribution towards light hydrocarbons.

• 한국생물공학회:학술대회논문집
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• 2000.11a
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• pp.229-232
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• 2000

The carbon dioxide, nitrogen, and phosphate removals from wastewater using microalgae have extensively been studied. Especially, the green colonial algae Botryococcus braunii is characterized by unusual high hydrocarbon contents, ranging from 15 to 75% of dry weight, as long-chain unsaturated hydrocarbons. These hydrocarbons suggest that the possibility of renewable biofuels to be converted into useful fuels such as gasoline by simple catalytic cracking. The poor recovery (18 - 32%) of hydrocarbon from B. braunii culture in two-phase bubble column seems to be caused by insufficient mixing between two phases, which was operated using only aeration on the narrow interface between hydrophobic solvent and cell suspension. In addition, hydrocarbon was entrapped tightly in cell-matrix (formed by exopolysaccharide) of algal colony, which make difficult to extract using two-phase system. In order to overcome low recovery efficiency, two-stage extraction culture system including culture vessel and two-phase separator is now under development, resulted improving contact between solvent phase and cell suspension. Hydrocarbon recovery using this process was more than two times as that using two-phase extraction culture.

• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.129-135
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• 1996

The entrapping capacity of the single hydrocarbons and the entrapping equilibrium data for binary mixtures of the $C_6$ to $C_9$ hydrocarbons on the activated thiourea have been investigated. The entrapping capacity of single component varied irregularly with molecular size and was independent of temperature. In the liquid phase entrapping from binary system, the lower molecular weight hydrocarbon was entrappe preferentially. In the liquid phase entrapping from trimethylbenzene isomer and ethyltoluene isomer, selectivity was found to be related to the relative position of methyl groups in the molecules and hence the electronic configuration. Pseudocumene of a purity of 99.5wt% may be obtained from $C_9$ aromatic raffinate found in naphtha cracking center. Activated thiourea was more efficient than distillation, extractive crystallization and adductive crystallization in terms of separation factor.

• 한국생물공학회:학술대회논문집
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• 2002.04a
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• pp.112-115
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• 2002

The green colonial algae Botryococcus braunii is characterized by unusual high hydrocarbon contents, ranging from 15 to 75% of dry weight, as long-chain unsaturated hydrocarbons. In two-phase bubble column using various organic solvents, poor recovery 08 - 32%) of hydrocarbon seems to be caused by insufficient mixing between two phases, which was operated using only aeration on the narrow interface between hydrophobic solvent and cell suspension. In addition, hydrocarbon was entrapped tightly in cell-matrix (formed by exopolysaccharide) of algal colony, which make difficult to extract using two-phase system. To improve recovery efficiency, mixed-solvent of extractive solvent (octane) and biocompatible solvent (octane) was tested in two-phase column for in situ extraction. In two-phase extraction culture using mixed-solvent, the algal growth was intensely inhibited even at low concentration of polar octanol solvent. the hydrocarbon recovery in two-stage cell-recycle extraction showed a 2.9 fold increase (57%) over that in two-phase extraction. Up to 60 % of hydrocarbon could be recovered without serious cell-damage in the case of downstream separation for 6 h at the high recycle flow rate using this process after batch culture.

• Elastomers and Composites
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• v.39 no.4
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• pp.318-323
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• 2004

Cloud-point and bubble-point curves for poly(ethylene-co-13.8 mol% octene) ($PEO_{13.8}$) and Poly(ethylene-co-15.3 mol% octene) ($PEO_{15.3}$) were determined up to $150^{\circ}C$ and 450 bar in hydrocarbons which have different molecular size and structure. Whereas ($PEO_{15.3}$+ n-pentane) system has cloud-point and bubble-point type transitions, ($PEO_{15.3}$+ n-propane) and ($PEO_{15.3}$+ n-butane) systems do only cloud-point type transition. In cyclo-pentane, -hexane, -heptane, and -octane, $PEO_{15.3}$ has a bubble-point transition. ($PEO_{13.8}$+ n-butane) mixture has a critical mixture concentration at 5 wt% PEO. (PEO + hydrocarbon) mixtures exhibit LCST type behavior. Solubility of PEO increases with hydrocarbon size due to increasing dispersion interaction which is favorable to dissolve PEO.

• Journal of the Korean earth science society
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• v.43 no.5
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• pp.639-646
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• 2022

Occurrence of black opaque hydrocarbon (pyrobitumen) in some Cretaceous Jinju sandstones of the Sindong Group, Gyeongsang Basin in Korea is first reported in this study. The pyrobitumen is developed on chlorite pore-lining cement, or impregnated into the outer zone of chlorite cement. Therefore, it seems to have been formed after the precipitation of chlorite cement, indicating the former presence of crude oil. The liquid hydrocarbons migrated into sandstones during moderate burial and these sandstones seem to have acted as a liquid hydrocarbon reservoir. The presence of pyrobitumen in the Jinju Formation indicates that this formation underwent deep burial after liquid hydrocarbon migration. As reservoir temperatures increased further, hydrocarbons were cracked and a solid pyrobitumen residue remained in the reservoir.

• Transactions of the Korean hydrogen and new energy society
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• v.19 no.4
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• pp.331-339
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• 2008

본 논문은 내경 7.73 mm와 5.80mm의 수평관내 프레온계 냉매 R-22와 탄화수소계 냉매 R-290과 600a의 응축 열전달 계수의 실험적 결과를 나타내었다. 실험장치는 압축기, 응축기, 팽창밸브, 증발기 등으로 구성된다. 응축 실험은 질량유속 $35.5{\sim}210.4\;kg/m^2s$이고, 응축온도 40$^{\circ}C$인 조건에서 수행하였다. 주요 결과를 요약하면 다음과 같다. 탄화수소계 냉매 R-290과 R-600a의 평균 열전달 계수는 프레온계 냉매 R-22보다 높게 나타났으며, R-600a의 평균 열전달 계수가 모든 관경에 대해 가장 높게 나타났다. 실험결과와 종래의 상관식을 비교한 결과, 모든 관경과 냉매에 대해 Haraguchi 등의 상관식이 가장 좋은 일치를 보였다. 그 중에서 Cavallini-Zecchin의 상관식은 7.73 mm 관경의 실험데이터와, Dobson 등의 상관식은 내경 5.80 mm 관경의 데이터와 좋은 일치를 보였다.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2004.11a
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• pp.447-448
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• 2004