• Title/Summary/Keyword: 탄소이동

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Penetration behavior by carbon potential in laser-carburized TiZrN coatings (TiZrN 코팅의 레이저 침탄에서 탄소 포텐셜에 따른 침입 거동)

  • Lee, Byunghyun;Kim, Taewoo;Hong, Eunpyo;Kim, Seonghoon;Lee, Heesoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.6
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    • pp.282-286
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    • 2021
  • Penetration depth and compressive residual stress of laser-carburized TiZrN coating by thickness of carbon paste were investigated in terms of carbon potential. The carbon paste was covered with a thickness of 1.1 mm using screen printing, and applied to a thickness of 0.4 mm using spin coating, and laser carburization was performed under the same conditions. As the thickness of carbon paste increased, the diffraction pattern of the laser-carburized TiZrN coating shifted to a lower angle, indicating solid solution strengthening and lattice distortion. For microstructure analysis using TEM, the defects and carbon concentration of the laser-carburized TiZrN coating increased as the carbon paste was thicker. It indicated that the variation of the carbon potential corresponds to the change in the paste thickness. In XPS depth profile analysis, high concentration of carbon and formation of carbide were observed in laser-carburized TiZrN coating with thick carbon paste. It revealed that the carbon concentration on the surface and carbon potential were changed by the thickness control of carbon paste. The compressive residual stress increased from 3.67 GPa to 4.58 GPa by the variation of carbon concentration.

A Service Model for Mobility Support of the Transportation Vulnerable based on MyData (마이데이터 기반 교통약자 이동지원 서비스 모델)

  • Choi, Hee-Seok;Lee, Seok-Hyung;Park, Moon-Soo
    • Proceedings of the Korea Information Processing Society Conference
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    • 2021.11a
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    • pp.487-490
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    • 2021
  • 교통약자의 이동권 보장을 위한 다양한 제도와 교통서비스가 국내외에서 시행되고 있다. 그러나 교통약자를 위한 정책이 이동편의시설 확충이나 특별교통수단·저상버스 확보 등에 치우쳐 있다. 이로 말미암아 교통수단간 연계와 이용자 관점의 서비스 편의성과 자율성 확보에는 여전히 한계가 있다. 본 연구에서는 교통약자 이동편의를 국내외 정책과 서비스 사례를 살펴보고, 마이데이터를 활용한 교통약자 이동지원 서비스 모델을 제시한다.

Sufface Structures and Electrode Characteristics of Carbon Electrodes (탄소전극의 표면조직과 전극특성)

  • O, Han-Jun;Kim, In-Gi;Ji, Chung-Su
    • Korean Journal of Materials Research
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    • v.7 no.11
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    • pp.991-998
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    • 1997
  • 중성과 산성의 전해질내에서 여러 탄소전극의 전기화학적 특성과 전극재료의 중요함수인 이중층 축전용량에 대하여 조사 하였다. 이를 위해 임피던스 스펙트로스코피를 이용하였으며, 0.5M $K_{2}$SO$_{4}$용액과 0.1M H$_{2}$SO$_{4}$용액내에서 electrographite와 박판상 흑연의 경우 이중층 축전용량은 다른 두 전극재료에 비하여 높게 나타났으며, 0.1M H$_{2}$SO$_{4}$용액에서 탄소재료의 전하이동저항 R$_{1}$은 유리상 탄소와 PVDF graphite의 경우 140 ㏀과 31.9㏀로 나타났으며 electropraphite와 박판상 흑연의 경우 2.0㏀과 5.7㏀의 적은 값을 나타냈다. 이는 재료의 표면이나 내부의 기공에 의해 생기는 커다란 비 표면적 때문이며, 이것에 의해 재료의 상경계에서 측정된 임피던스량은 저주파영역에서 낮게 나타났다. 특히 electrographite는 전극계면에서 흡착의 영향이 현저하게 나타났으며, 4종류 전극재료의 전기화학적 특성과 이중층 축전용량은 전극표면 조직에 의해 차이가 나타났다.

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Two-dimensional Thermal Analysis for Carbonacious Thermal Liner of Rocket Nozzle with Ablation and In-depth Pyrolysis (삭마 및 내부 열분해를 고려한 로켓노즐 탄소계 내열재의 2차원 열해석)

  • 황기영;강윤구
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.2
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    • pp.37-47
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    • 1999
  • This paper describes the thermal analysis which can calculate the ablation depth and temperature distribution of the rocket nozzle liner allowing geometry change caused by the ablation of nozzle liner. In this analysis, Zvyagin's model is used for surface ablation and Yaroslavtseva's model for in-depth pyrolysis. A deforming finite-element grid is used to account for external-boundary movement due to the erosion of thermal liner. The accuracy of the present numerical method is evaluated with a rocket nozzle liner and the numerical solutions are favorably agreed with experimental data. The temporal variations of temperature and ablation depth at the thermal liner of another rocket nozzle are numerically simulated and the results are discussed. Special emphasis is given to the effects of kinetic constants for carbon-carbon and carbon-phenolic composites on the ablation depth of thermal liner.

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A Measurement of Proton Beam Energy using Carbon Target for Medical Cyclotron (탄소 표적물을 사용한 의료용 싸이클로트론의 양성자 에너지 측정)

  • Chai, Jong-Seo;Ha, Jang-Ho;Kim, Yu-Seok;Lee, Dong-Hun;Lee, Min-Yong;Hong, Seong-Seok
    • The Korean Journal of Nuclear Medicine
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    • v.29 no.3
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    • pp.350-354
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    • 1995
  • 한국 원자력 연구소 부설 원자력병원에 설치된 AVF 싸이클로트론을 이용하여 요즈음 핵의학에 널리 사용되는 PET 용 싸이클로트론의 에너지를 검정 할 수 있고 양성자 과잉 핵종인 싸이클로트론 동위원소의 생산 수율에 중요한 변수인 양성자에너지를 탄소에 입사시켜 입사빔의 Range와 에너지를 측정하는 방법을 제시하였다. 본 실험에서 사용된 양성자 빔의 양성자 에너지는 35 MeV와 50 MeV 사이였으며, 탄소 막은 두께 6.3mm, 밀도 $1.712 g/cm^3$를 사용하였다. 탄소 표적물을 $0.9^{\circ}$씩 스텝 모터를 사용하여 회전시킴으로 두께를 변화 시켜 공칭 에너지에 대한 Range를 측정함으로써 입사된 양성자의 에너지를 구하였고 이를 인출반경과 RF주파수를 바탕으로 상대론 적으로 계산된 에너지와 비교하였다.

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A Study on the Growth Morphology of VGCF Nano-Materials by Acetylene Pyrolysis over Stainless Steel Catalyst - Effect of Reduction Pretreatment and Hydrogen Supply (스테인리스 스틸 촉매 상에서 아세틸렌 분해에 의한 VGCF 나노물질의 성장 형태 연구 - 환원 전처리 및 수소공급 효과)

  • Park, Seok Joo;Lee, Dong Geun
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.563-571
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    • 2006
  • Vapor grown carbon fiber (VGCF) nano-materials such as carbon nanotubes and carbon nanofibers were directly grown on the surface of the stainless steel mesh pre-treated by reduction. The reduction of the stainless steel mesh by hydrogen formed small catalytic particles and large particles with bi-modal distribution on the metal surface. When the VGCFs were synthesized on the reduced mesh, carbon nanotubes (CNTs) were dominantly grown from the small catalytic particles without supplying hydrogen gas. However, carbon nanofibers (CNFs) were dominantly grown from the large catalytic particles with hydrogen.

Effect of heat treatment on mechanical properties of overlay welds (육성 용접부의 기계적 성질에 미치는 열처리조건의 영향)

  • 이기호;김기철;윤의박
    • Journal of Welding and Joining
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    • v.7 no.4
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    • pp.30-37
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    • 1989
  • Effect of heat treatment on mechanical properties of an overlay weldment was investigated. Over welding was carried out on the structural C-Mn mild steel substrate to take required test specimens. Shielded metal arc welding process with 13Cr-0.2Ni stick electrode was applied. The heat treatment temperatures and holding times were $450{\circ}C., 550{\circ}C., 650{\circ}C., 750{\circ}C., 850{\circ}C.$ and 0.5hr, 2hr, 10hr, respectively. Mechanical tests and microscopic inspection were also carried out to investigate welds soundness. Test results indicated that carbon migration was dominant near bonded zone. At temperature of around 650.deg. C, carburized layer and decarburized layer were formed remarkably along overlay welds region and C-Mn mild steel region, respectively. The wideth of these layers became wider with increasing heat treatment temperature and/or holding time at the elevated temperature, and this relationship agreed with Larson-Miller parameter. Side bending test results demonstrated that the crack free region of overlay welds could be deduced from the relationship between temperature and holding time.

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Hydro-Biogeochemical Approaches to Understanding of Water and Carbon Cycling in the Gwangneung Forest Catchment (수문생지화학적 접근을 통한 광릉 산림 유역의 물과 탄소 순환 이해)

  • Kim, Su-Jin;Lee, Dong-Ho;Kim, Joon;Kim, Sung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.2
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    • pp.109-120
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    • 2007
  • The information on flowpath, storage, residence time, and interactions of water and carbon transport in a catchment is the prerequisite to the understanding and predicting of water and carbon cycling in the mountainous landscapes of Korea. In this paper, along with some up-to-date results, we present the principal methods that are currently used in HydroKorea and CarboKorea research to obtain such information. Various catchment hydrological processes have been examined on the basis of the water table fluctuations, the end-member mixing model, the cross correlation analysis, and cosmogenic radioactive isotope activity. In the Gwangneung catchment, the contribution of surface discharge was relatively large, and the changes in the amount, intensity and patterns of precipitation affected both the flowpath and the mean residence time of water. Particularly during the summer monsoon, changes in precipitation patterns and hydrological processes in the catchment influenced the carbon cycle such that the persistent precipitation increased the discharge of dissolved organic carbon (DOC) concentrated in the surface soil layer. The improved understanding of the hydrological processes presented in this report will enable a more realistic assessment of the effects of climate changes on the water resource management and on the carbon cycling in forest catchments.

Carbon nanofiber and metal oxide composites for photovoltaic cells

  • O, Dong-Hyeon;Gu, Bon-Yul;Bae, Ju-Won;An, Hyo-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.412-412
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    • 2016
  • 염료감응 태양전지(dye-sensitized solar cells, DSSCs)는 식물의 광합성원리와 매우 유사한 작동원리를 갖고 있는 전지이며, 간단한 구조, 저렴한 제조단가, 친환경성 등의 등의 장점으로 인하여 많은 관심을 모으고 있다. 이러한 염료감응 태양전지는 빛을 받아들인 염료분자가 전자-홀 쌍을 생성하며 전자는 반도체 산화물을 통해 이동되고 전해질의 산화환원 과정을 통해 염료 분자가 다시 환원되는 순환메커니즘을 따르고 있다. 일반적으로 염료감응 태양전지는 밴드 갭 에너지가 큰 반도체 산화물을 포함하는 작업전극, 산화환원 반응을 통해 전자를 염료로 보내는 전해질, 환원 촉매역할을 하는 상대전극으로 구성되어 있다. 특히, 상대전극으로는 우수한 촉매특성과 높은 전도성을 갖는 백금이 가장 많이 이용되고 있지만 가격이 비싸고 요오드에 취약하기 때문에 상용화에 큰 장애물이다. 따라서, 백금을 대체하기 위해 저가의 탄소나 고분자에 대한 연구가 활발히 진행되고 있고, 그 중 탄소나노섬유(carbon nanofiber, CNFs)는 높은 표면적과 뛰어난 화학적 안정성으로 촉매효율을 증대시킬 수 있어 촉매물질로서 관심이 높아지고 있다. 본 연구에서는 상대전극에 탄소나노섬유기반 복합체를 합성하였고, 성공적으로 저가격 및 고성능의 염료감응 태양전지를 제작하였다. 이때, 지지체인 탄소나노섬유는 전기방사법을 통해 합성하였으며, 수열합성법을 이용하여 금속산화물을 담지하였다. 이렇게 제작된 탄소나노섬유-Fe2O3 복합체는 scanning electron microscopy, transmission electron microscopy, X-ray diffraction, 그리고 X-ray photoelectron spectroscopy 통해 구조적, 화학적 특성을 평가하였으며 전기화학적 특성 및 광전변환 효율을 분석하기 위해 cyclic voltammetry, electrochemical impedance spectroscopy, 그리고 solar simulator를 사용하였다. 본 학회에서 위와 관련된 더 자세한 사항에 대해 논의할 것이다.

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Stable Isotope Studies for Constraining Water and Carbon Cycles in Terrestrial Ecosystems: A Review (안정 동위원소를 이용한 육상 생태계의 물과 탄소의 순환 연구: 재검토)

  • Lee Dongho
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.1
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    • pp.15-27
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    • 2005
  • The water and carbon cycles in terrestrial ecosystems are the essential database for better understanding of the causes and the current processes of climate change and for the prediction of its future change. CarboKorea and HydroKorea are dedicated research efforts to develop technologies to quantitatively interpret and forecast carbon/water cycles in typical landscapes of Korea. For this, stable isotope studies have been launched to genetically partition various components of carbon/water cycles in terrestrial ecosystems. From stable isotope studies, practical deliverables such as evaporation, transpiration and gross primary productivity (GPP) can be provided at scales from tower (footprint) to large watersheds. Such reliable field-based information will form an important database to be used for validation of the results from various eco-hydrological models and satellite image analysis which constitute main components of Carbo/HydroKorea project. Stable isotope studies, together with other relevant researches, will contribute to derive quantitative interpretation of carbon/water cycles in terrestrial ecosystems and support Carbo/HydroKorea to become a leading research infrastructure to answer pending scientific and socio-economic questions in relation to global changes.