• Title/Summary/Keyword: 탄소비율

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Synthesis of Cyclododecatriene from 1,3-Butadiene by Trimerization over Amine-Titanium Complex Catalyst (아민-티타늄착체 촉매상에서 1,3-부타디엔의 삼량화반응에 의한 싸이클로도데카트리엔의 합성)

  • Park, Da Min;Kim, Gye-Ryeong;Lee, Ju Hyun;Cho, Deuk Hee;Kim, Geon-Joong
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.394-402
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    • 2013
  • The new complex catalysts were synthesized by the reaction of titanium compounds (titanium chloride or titanium butoxide) and diamines in this work, and they showed very high catalytic activities for the cyclododecatriene (CDT) synthesis from 1,3-butadiene through trimerization. CDT synthetic reaction was performed in an autoclave reactor, and the effects of reaction temperature, type of catalyst, catalyst amount added into the system, the mole ratio of Al/Ti and immobilization method were investigated on the yield of product CDT. The titanium complex catalyst combined to diamine with 1:1 ratio showed high selectivity to CDT more than 90%. The ratio of TTT-CDT/TTC-CDT isomers in the product revealed as different values, depending on the type of diamine combined to titanium and Ti/diamine ratios. Those homogeneous complexes could be used as a heterogenized catalyst after anchoring on the supports, and the immobilized titanium catalyst retained the catalytic activities for several times in the recycled reactions without leaching. The carbon support containing titanium has exhibited superior activity to the silica support. Especially, when the titanium complex was anchored on the support which was fabricated by the hydrolysis of tripropylaminosilane itself, the resulting titanium catalyst showed the highest BD conversion and CDT selectivity.

The Agriculture Decision-making System(ADS) based on Deep Learning for improving crop productivity (농산물 생산성 향상을 위한 딥러닝 기반 농업 의사결정시스템)

  • Park, Jinuk;Ahn, Heuihak;Lee, ByungKwan
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.11 no.5
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    • pp.521-530
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    • 2018
  • This paper proposes "The Agriculture Decision-making System(ADS) based on Deep Learning for improving crop productivity" that collects weather information based on location supporting precision agriculture, predicts current crop condition by using the collected information and real time crop data, and notifies a farmer of the result. The system works as follows. The ICM(Information Collection Module) collects weather information based on location supporting precision agriculture. The DRCM(Deep learning based Risk Calculation Module) predicts whether the C, H, N and moisture content of soil are appropriate to grow specific crops according to current weather. The RNM(Risk Notification Module) notifies a farmer of the prediction result based on the DRCM. The proposed system improves the stability because it reduces the accuracy reduction rate as the amount of data increases and is apply the unsupervised learning to the analysis stage compared to the existing system. As a result, the simulation result shows that the ADS improved the success rate of data analysis by about 6%. And the ADS predicts the current crop growth condition accurately, prevents in advance the crop diseases in various environments, and provides the optimized condition for growing crops.

Estimation of Biomass for 27 Years Old Korean Pine (Pinus koraiensis) Plantation in Gangneung, Gangwon-Province (강릉지방 27년생 잣나무조림지의 바이오매스에 관한 연구)

  • Lee, Young-Jin;Seo, Yeon-Ok;Park, Sang-Moon;Pyo, Jung-Kee;Kim, Rae-Hyun;Son, Yeong-Mo;Lee, Kyeong-Hak;Kim, Hyung-Ho
    • Journal of agriculture & life science
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    • v.43 no.1
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    • pp.1-8
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    • 2009
  • This study was conducted to examine the biomass, allometric equations, net primary production, above and total biomass expansion factors and stem density values for 27 years old Korean pine(Pinus koraiensis Siebold et Zuccarini) plantation at the Gangneung National Forest. After considering of the diameter distributions in the $20m{\times}20m$ plot measurement, a total of 5 representative sample trees were destructively sampled to measure green weights and dry weights of the four(root, stem, branch and foliage) protions of Korean pine trees. According to the results of this study, total dry weights were 117.6 kg/tree and 59.9 ton/ha. Aboveground biomass and total (above and belowground) biomass for this species were 59.9 and 82.4 ton/ha, respectively. Ratios of root to aboveground biomass were 0.38. Net primary production of aboveground biomass and belowground biomass were 9.4 and 11.3 ton/ha, respectively. Stem density was $0.49g/cm^{3}$. Above and total biomass expansion factors were 1.78 and 2.19, repectively. This information could be very useful to calculate carbon sequestrations by applying stem desity values and biomass expansion factors for Korean pine species.

Study on the hepatoprotective effects of lemon balm and dandelion leaf extract combination in carbon tetrachloride-mediated liver injured mice (사염화탄소 유도성 급성 간 손상 모델에서 레몬밤과 민들레 잎 추출물의 혼합 비율에 따른 간 보호 효능 연구)

  • Choi, Beom-Rak;Cho, Il Je;Jung, Su-Jin;Kim, Jae Kwang;Lee, Dae Geon;Ku, Sae Kwang;Park, Ki-Moon
    • Herbal Formula Science
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    • v.27 no.3
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    • pp.199-211
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    • 2019
  • Objectives : Present study investigated the hepatoprotective effects of various combinations of lemon balm and dandelion (LD) leaf extract on carbon tetrachloride ($CCl_4$)-induced acute liver injury. Methods : Mice were orally treated with 200 mg/kg of LD extracts [1:1, 1:2, 1:4, 1:6, 1:8, 2:1, 4:1, 6:1, or 8:1 (weight : weight)] for 7 days, and then intraperitoneally injected with $CCl_4$ (0.5 mL/kg). Silymarin (100 mg/kg) was used as reference drug. Body weight gain, relative liver weight, serum biochemistry, histopathologic analyses, and hepatic antioxidant system were examined to elucidate the fittest combination ratio of LD extract. Results : All varying combinations of LD extract significantly increased body weight gain and decreased relative liver weight by $CCl_4$. In addition, LD extract reduced serum aspartate aminotransferase and alanine aminotransferase. Histopathological analyses indicated that LD extract significantly decreased histological activity index score, degenerated hepatocytes, and infiltrated inflammatory cells induced by $CCl_4$. Moreover, LD extract reduced lipid peroxidation, and attenuated the reduction of hepatic glutathione, superoxide dismutase, and catalase by $CCl_4$. Although there were no statistical differences in body weight gain between silymarin- and LD extract-treated groups, administration of 1:1, 2:1, and 4:1 combination of LD extract exhibited more favorable hepatoprotective effects than silymarin. Especially, 2:1 combination of LD extract showed the most potent hepatoprotective effects. Conclusion : Of various combinations of LD extract tested, present results suggest that 2:1 combination of LD extract would be a promising herbal formulation to protect liver from oxidative stress.

Properties Evaluation and flowability of Controlled Low Strength Materials Utilizing Industrial By-Products (산업부산물을 활용한 저강도 고유동 채움재의 유동성 및 물성평가)

  • Cho, Yong-Kwang;Kim, Chun-Sik;Nam, Seong-Young;Cho, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.27 no.4
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    • pp.64-69
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    • 2018
  • The purpose of this study is to expand the use of coal ash and coal slag in thermal power plants. In addition, controlled low strength materials was developed to prevent mine settlement. Bottom ash and KR slag are mixed at ratio of 7:3 to expand the use of industrial by-products through carbonate reaction and inhibit the exudation of heavy metals. In order to efficiently fill the abandon mine, workability and physical properties were evaluated according to flow. As a result of elution of harmful substance experiment, it was confirmed that the carbonation reaction inhibited the elution of heavy metals. It was confirmed that the difference in water ratio was the difference in specific surface area of the controlled low strength materials. It was confirmed that the working efficiency is excellent when the flowability is 300mm compared to 260mm. compressive strength measurement result was relatively high at 260mm compared to 300mm because the number of pores due to decrease of water ratio was small.

Analysis of Power System Stability by Deployment of Renewable Energy Resources (재생에너지원 보급에 따른 전력계통 안정도 분석)

  • Kwak, Eun-Sup;Moon, Chae-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.16 no.4
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    • pp.633-642
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    • 2021
  • Growing demand for electricity, when combined with the need to limit carbon emissions, drives a huge increase in renewable energy industry. In the electric power system, electricity supply always needs to be balanced with electricity demand and network losses to maintain safe, dependable, and stable system operation. There are three broad challenges when it comes to a power system with a high penetration of renewable energy: transient stability, small signal stability, and frequency stability. Transient stability analyze the system response to disturbances such as the loss of generation, line-switching operations, faults, and sudden load changes in the first several seconds following the disturbance. Small signal stability refers to the system's ability to maintain synchronization between generators and steady voltages when it is subjected to small perturbations such as incremental changes in system load. Frequency stability refers to the ability of a power system to maintain steady frequency following a severe system upset resulting in significant imbalance between generation and load. In this paper, we discusses these stability using system simulation by renewable energy deployment plan, and also analyses the influence of the renewable energy sources to the grid stability.

A Study on the Application of GOCI to Analyzing Phytoplankton Community Distribution in the East Sea (동해에서 식물플랑크톤 군집 분포 분석을 위한 GOCI 활용 연구)

  • Choi, Jong-kuk;Noh, Jae Hoon;Brewin, Robert J.W.;Sun, Xuerong;Lee, Charity M.
    • Korean Journal of Remote Sensing
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    • v.36 no.6_1
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    • pp.1339-1348
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    • 2020
  • Phytoplankton controls marine ecosystems in terms of nutrients, photosynthetic rate, carbon cycle, etc. and the degree of its influence on the marine environment depends on their physical size. Many studies have been attempted to identify marine phytoplankton size classes using the remote sensing techniques. One of successful approach was the three-component model which estimates the chlorophyll concentrations of three phytoplankton size classes (micro-phytoplankton; >20 ㎛, nano-; 2-20 ㎛ and pico-; <2 ㎛) as a function of total chlorophyll. Here, we examined the applicability of Geostationary Ocean Colour Imager (GOCI) to the mapping of the phytoplankton size class distribution in the East Sea. A fit of the three-component model to a biomarker pigment dataset collected in the study area for some years including a large harmful algal bloom period has been carried out to derive size-fractioned chlorophyll concentration (CHL). The tuned three-component model was applied to the hourly GOCI images to identify the fractions of each phytoplankton size class for the entire CHL. Then, we investigated the distribution of phytoplankton community in terms of the size structure in the East Sea during the harmful Cochlodinium polykrikoides blooms in the summer of 2013.

Growth characteristics of oyster mushroom following the addition of wheat straw pellet as a substitute for beet pulp (비트펄프 대체 밀짚펠렛 첨가에 따른 느타리 생육 특성)

  • Jun-Yeong, Choi;Jeong-Han, Kim;Yeon-Jin, Kim;Chae-Young, Lee;Il-Seon, Baek;Tai-Moon, Ha;Chan-Jung, Lee;Gab-June, Lim
    • Journal of Mushroom
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    • v.20 no.4
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    • pp.270-273
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    • 2022
  • The present study investigated the optimum additive ratio of wheat straw pellet as a substitute for beet pulp during oyster mushroom cultivation. The chemical properties across treatments were pH of 4.8-5.5, total carbon content of 45.9-46.5%, total nitrogen content of 1.5-1.7%, and carbon-to-nitrogen ratio of 27.8-31.0. Mycelial growth was the fastest in a medium containing 20% wheat straw pellet (at 88.2 mm in 'Heuktari' and 70.3-79.6 mm in 'Suhan-1Ho'); however, there were no significant differences in mycelial density among the treatments. The characteristics of fruiting bodies by variety were as follows. In 'Heuktari', the valid stipe number per bottle (1,100 cc) was 22.5 and yield was 177.1 g/1,100 cc in the mixed medium containing 10% wheat straw pellet, with the values being comparable to those of controls. In 'Suhan-1Ho', the valid stipe number per bottle (1,100 cc) was 14.0 and yield was 151.2 g/1,100 cc in the mixed medium containing 10% wheat straw pellet, with the values being comparable to those of controls.

Characteristics of fruiting body growth according to alternative substrates of king oyster mushroom (Pleurotus eryngii) (큰느타리 대체배지 종류에 따른 자실체 생육 특성)

  • Hye-Sung, Park;Gyong-Jin, Min;Eun-Ji, Lee;Tai Moon, Ha
    • Journal of Mushroom
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    • v.20 no.4
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    • pp.274-278
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    • 2022
  • The present study aimed at selecting a cost-effective substrate for king oyster mushroom based on the growth characteristics of fruiting body for use as a basic resource to ensure stable production on farms. Compositional analysis of substrates manufactured with different materials in each process revealed that the total carbon content was 42.24-48.22% higher and the total nitrogen content was 1.7-2.29% higher in the processed lot than in the control (i.e., substrate used by the farmhouse; 40.86% and 1.39%, respectively). Meanwhile, the carbon-to-nitrogen ratio was the highest in the control (27.9% vs. 19.12-27.88% in the processed lot). When cultured for 28 days, the mycelium growth was 11.5 and 11.3 mm in substrates 1 and 6, respectively, indicating the fastest growth; meanwhile, the values were 10.1-10.3 mm in the control and substrate 11, showing a similar tendency. Mycelial density did not differ significantly among the processed lots. Yield per bottle was higher in substrates 8 (205.95 g/bottle), 7 (178.51 g/bottle), and 11 (170.63 g/bottle) than in the control (152.2 g/bottle). Fruiting body quality was comparable to controls in all processed lots. Overall, economic effects, such as substrate material prices, should be analyzed, and stability evaluations, such as residual pesticide and harmful microorganisms, should be undertaken along with further detailed examination to ensure safe and stable production on farms.

Hepatoprotective effect of fermented Schizandrae Fructus Pomace extract and Hoveniae Semen Cum Fructus extract combination mixtures against carbon tetrachloride-induced acute liver injured mice (사염화탄소 유발 급성 간 손상에 대한 발효 오미자박 및 헛개과병 추출물의 혼합 비율에 따른 간 보호효능)

  • Hye-Rim, Park;Kyung Hwan, Jegal;Beom-Rak, Choi;Jae Kwang, Kim;Sae Kwang, Ku
    • Herbal Formula Science
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    • v.31 no.1
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    • pp.53-65
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    • 2023
  • Objectives : Present study investigated the hepatoprotective effects and the optimal mixing ratio of fermented Schizandrae Fructus Pomace (fSFP) and Hoveniae Semen Cum Fructus (HSCF) extract combination in carbon tetrachloride (CCl4)-induced acute liver injury mice. Methods : ICR mice were orally administered with 200 mg/kg of fSFP, HSCF and mixtures of fSFP and HSCF [MSH (w:w); 1:1, 1:2, 1:4, 1:6, 2:1, 4:1, 6:1, and 8:1] for 7 consecutive days. Silymarin (100 mg/kg) was administered as a reference drug. 0.5 mL/kg of CCl4 was injected intraperitoneally to induce acute liver injury. Body weight gain, relative liver weight, serum chemistry, histopathological analysis, and hepatic endogenous antioxidants capacities were observed. Results : All diverse combinations of MSH significantly reduced relative liver weight increase by CCl4. In addition, MSH administrations significantly decreased the elevation of serum alanine aminotransferase and aspartate aminotransferase activities by CCl4. Histopathological observation indicated that all MSH treatments significantly reduced the increase of degenerated hepatocytes, inflammatory cell infiltration, and histological activity index score by CCl4. Moreover, all MSH administrations reduced the elevation of malondialdehyde contents, and ameliorated the reduction of hepatic glutathione contents, superoxide dismutase activity, and catalase activity. Among the various mixing ratio of MSH combinations, MSH 1:1 and 2:1 showed the most potent anti-oxidative stress, and hepatoprotective effect. Conclusion : Present results suggest that 1:1 and 2:1 combinations of MSH is promising herbal formulation with the hepatoprotective effect against oxidative stress.