• Journal of the Korean Institute of Gas
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• v.27 no.1
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• pp.1-12
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• 2023

Coal gasification is a process of incomplete coal combustion to produce a syngas composed of hydrogen and carbon monoxide. It is one of methods to utilize coal cleanly because the process does not emits nitrogen oxides or sulfur oxides and particulate matters. In addition, chemicals can be produced using syngas. Coal gasification is classified as IGCC (Integrated Gasification Combined Cycle), Plasma coal gasification and UCG (Underground Coal Gasification). Recently, WGS (Water Gas Shift) reactor and carbon capture system have been combined to gasifier to produce hydrogen from coal. In this study, the coal gasification and method of hydrogen production from syngas was summarized, and the hydrogen production from coal gasification project was investigated.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.32-32
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• 2021

넥서스는 물, 에너지, 식량, 토지, 기후 및 환경 등의 부문 간 연관성과 상호의존성을 나타내며, 이러한 넥서스 개념은 최근에 학계와 정책결정자들에게 많은 관심을 받고 있다. 더 나아가 넥서스 관점의 도입으로 단일 부문별로 자원을 관리하는 기존의 정책 결정 체계의 한계를 극복하고, 관련 있는 부문 간의 시너지와 트레이드오프를 고려한 지속가능한 발전을 위한 의사 결정이 가능하게 되었다. 일반적으로 취수-도수-정수처리-송수-분배·급수-물이용-하수집수-하수처리-물재이용으로 구성되는 도시 물순환 시스템에서 공급과정에서 발생되는 물손실 관리를 위한 전략 및 프로그램은 물부문 만에서 평가를 통해 수립되고 있다. 본 연구에서는 시스템 다이나믹스(System Dynamics)를 적용하여 물, 에너지 및 환경 부문을 동시에 고려한 도시 물순환 시스템 모델을 개발하여, 넥서스 관점에서의 합리적인 도시 물손실 관리 방안을 도출하고자 하였다. 그리고 모델 내 부문 간 자원의 사용량 및 이동량의 정량화를 위해 물, 에너지, 환경 지표로 각각 물발자국(Water Footprint), 총 에너지 사용량(Total Energy Use) 및 탄소발자국(Carbon Footprint)이 적용되었다. 개발된 모델을 3개의 도시 에너지 인텐시티 현황(낮음, 보통, 높음)과 4개의 물손실 현황(낮은 물손실, 높은 물손실&낮은 명목손실비, 높은 물손실&보통 명목손실비, 높은 물손실&높은 명목손실비)을 고려한 12개의 시나리오에 적용하여 분석하였다. 그 결과 기존의 경제적인 측면 중심의 의사결정 과정에서는 명목손실이 물손실 관리 전략 수립 및 적용의 우선순위였으나, 넥서스 관점에서는 실손실 부분의 개선이 중요함을 알 수 있었다. 또한, 도시의 단위 물공급 에너지 인텐시티가 자원 사용 및 이동에 큰 영향을 미치는 것으로 분석되어서, 넥서스 관점의 의사결정시 사전적으로 분석해야 하는 중요 항목인 것으로 도출되었다. 이와 같은 범용적이고 포괄적인 도시 물순환 물-에너지-환경 넥서스 모델을 통해, 지속가능하고, 체계적이며, 구체적이고, 실현가능한 넥서스관점의 물손실 관리가 가능할 것으로 판단된다.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.421-421
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• 2021

도시화, 산업화로 인해 하수처리장 유입하수 내 질소 농도가 증가하면서 그에 따른 부영양화 발생, 수생태계에 독성을 미치는 등의 악영향 또한 증가하게 되었다. 하수 내 고농도 질소를 처리하기 위해 1990년 초 연구가 시작되어 현재 보편적으로 사용되고 있는 생물학적 질소 제거 공정은 산소공급과 외부탄소원 보충 과정에서 상당한 비용이 소요된다. 이와 같은 문제점이 대두됨에 따라 고도의 질소 제거 공정이 요구되면서, 경제적으로 개선이 이루어져 기존의 질산화·탈질 공정보다 효율적인 혐기성 암모늄 산화 공정(ANaerobic AMMonium OXidation, ANAMMOX)이 제안되었다. ANAMMOX 공정은 혐기성 조건 아래 전자공여체와 전자수용체로써 암모니아성 질소와 아질산성 질소를 이용해 질소가스 형태로 질소를 제거하는 공정이다. 질산화·탈질 공정과 비교했을 때, 폭기과정에서의 산소요구량 감소, 외부탄소원 불필요, 질소 제거 과정 단축 등의 장점을 가진다. 본 연구는 수처리공정에서의 ANAMMOX 공정의 적용 가능성을 확인하고, 암모니아성 질소대비 아질산성 질소 비율에 따른 Mainstream ANAMMOX 공정의 효율 비교를 통해 공정의 안정성과 높은 제거효율을 확보할 수 있는 NH₄⁺ 대비 NO₂^- 비율을 도출하는데 목적이 있다. 실험실 규모의 Mainstream ANAMMOX 반응조에 적용한 비율은 선행연구를 비롯한 화학양론식에서 제시된 비율을 바탕으로 산정하였다. 1.00부터 1.30의 전체적인 비율을 Initial과 Advanced 2개의 구간으로 나누어 운전한 결과, 각 구간의 NH₄⁺ 제거효율은 각각 58~86%, 94~99%였다. NH₄⁺ 대비 NO₂^- 비율이 증가함에 따라 공정의 안정성이 확보되고, NH₄⁺ 및 총질소(TN) 제거효율이 증가하는 경향이 나타났다. 본 연구의 결과는 수처리공정에서의 안정적인 ANAMMOX 공정 적용을 유도하고, ANAMMOX 공정의 성능개선을 도모하는 연구의 기초로 활용될 수 있다.

• Journal of the Korea Concrete Institute
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• v.16 no.5 s.83
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• pp.667-675
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• 2004

This paper presents the failure mode and strengthening design of reinforced concrete slab strengthened with Carbon Fiber Reinforced Polymer(CFRP) grid. Parameters involved in this experimental study are FRP grid reinforcement quantity, repair mortar thickness, the presence of anchor, and strengthening in compression. In this study, there are different failure types with increasing the CFRP grid strengthening reinforcement. On the low strengthening level, CFRP grid in repair mortar cover ruptures. On the moderate strengthening level, there is a debonding shear failure in the interface of carbon FRP grid because of the excessive shear deformation. On the high strengthening level, diagonal shear failure occurs. With the increasing of FRP grid reinforcement, the strengthening effect increased, but the ductility decreased. By limiting the strengthening level, it can be achieved to prevent shear failure which result in sudden loss in the resisting load capacity. CFRP rupture failure is desirable, because CFRP ruptured concrete slab keeps the same load capacity and ductility haying before strengthening even after failure. Finally, design guideline and procedure are given for strengthening of concrete slab with CFRP grid.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.4002-4006
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• 2014

The automotive exhaust gases generated by the vehicles containing carbon monoxide, hydrocarbons and lead, is a large concern because of their harm to human health or the living environment. To reduce exhaust gas, it is important to develop a variety of techniques that are currently being used by elemental analysis to determine the optimal conditions. In this study, the anti-freeze coolant contained in the exhaust gas was examined, which can affect the emissions. The effects of the commercially available coolant from five domestic companies on the HC, NOx and $CO_2$ emissions were analyzed to determine the optimal amount of antifreeze. In addition, antifreeze products from the five companies were analyzed with respect to driving time of the cooling fan and the correlation of the NOx emission analysis. The temperature of the engine oil was matched using a manual gear of small passenger inspection standard speed $40{\pm}2Km/h$ so the vehicle could meet the specifications for inspection $90{\sim}93^{\circ}C$. The Company D fan operation time resulted in the shortest antifreeze, $CO_2$ and NOx emissions.

• Journal of Korea Water Resources Association
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• v.41 no.10
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• pp.1035-1044
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• 2008

It is critical to study on data charateristics analysis and prediction for the flood disaster prevention and water quality monitoring because discharge and TOC data in a river channel are strongly nonlinear. Therefore, in the present study, prediction models for discharge, TOC, and TOC load data were developed using approximation component in the last level and detail components segregated by wavelet transform. The results show that the developed model overcame the persistence phenomenon which could be seen from previous models and improved the prediciton accuracy comparing with the previous models. It might be expected that the results from the present study can mitigate flood disaster damage and construct active alternatives to various water quality problems in the future.

• Journal of the Korean Electrochemical Society
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• v.27 no.2
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• pp.73-79
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• 2024

As the use of fossil fuels has gradually increased, so has the emission of greenhouse gases such as carbon dioxide, leading to environmental problems. As a result, lithium-ion batteries (LiB) have emerged as the solution to this issue. To manufacture medium to large-sized lithium-ion batteries (LiB), it requires electrodes with high capacity and fast charging capabilities. Silicon (Si) is considered a next-generation anode with high-capacity properties, so, reduced graphene oxide (rGO) was compounded with Si@resorcinol-formaldehyde resin (RF) composite to prevent the volume expansion of Si. It was confirmed that the composite anode prepared exhibited improved capacity and enhanced stability.

• Korean Journal of Environmental Agriculture
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• v.31 no.2
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• pp.104-112
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• 2012

BACKGROUND: Agricultural inputs (fertilizer and organic inputs) and water conditions can influence $CH_4$ and $CO_2$ emission from agricultural soils. This study was conducted to investigate the effects of agricultural inputs (fertilizer and organic inputs) under changing water regime on $CH_4$ and $CO_2$ emission from a soil in a laboratory incubation experiment. METHODS AND RESULTS: Four treatments were laid out: control without input and three type of agricultural inputs ($(NH_4)_2SO_4$, AS; pig manure compost, PMC; hairy vetch, HV). Fertilizer and organic inputs were mixed with 25 g of soil at 2.75 mg N/25 g soil (equivalent to 110 kg N/ha) in a bottle with septum, and incubated for 60 days. During the first 30-days incubation, the soil was waterlogged (1 cm of water depth) by adding distilled water weekly, and on 30 days of incubation, excess water was discarded then incubated up to 60 days without addition of water. Based on the redox potential, water regime could be classified into wetting (1 to 30 days), transition (31 to 40 days), and drying periods (41 to 60 days). Across the entire period, $CH_4$ and $CO_2$ flux ranged from 0 to 13.8 mg $CH_4$/m/day and from 0.4~1.9 g $CO_2$/m/day, and both were relatively higher in the early wetting period and the boundary between transition and drying periods. During the entire period, % loss of C relative to the initial was highest in HV (16.4%) followed by AS (8.1%), PMC (7.5%), and control (5.4%), indicating readily decomposability of HV. Accordingly, both $CH_4$ and $CO_2$ fluxes were greatest in HV treatment. Meanwhile, the lower $CH_4$ flux in AS and PMC treatments than the control was ascribed to reduction in $CH_4$ generation due to the presence of oxidized compounds such as ${SO_4}^{2-}$, $Fe^{3+}$, $Mn^{4+}$, and ${NO_3}^-$ that compete with precursors of $CH_4$ for electrons. CONCLUSION: Green manure such as HV can replace synthetic fertilizer in terms of N input, however, it may increase $CH_4$ emission from soils. Therefore, co-application of green manure and livestock manure compost needs to be considered in order to achieve satisfactory N supply and to mitigate $CH_4$ and $CO_2$ emission.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.662-668
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• 2018

Most electric rooms are located in the underground spaces of buildings. When a fire occurs in electrical equipment, the fire expands to cable insulation material, resulting in toxic smoke and combustion products. If the smoke and combustion products quickly move vertically and horizontally, the evacuation of occupants and firefighting activities will be hindered. Therefore, it is necessary to design optimal equipment for smoke control in cases of fires in electric rooms. This study analyzes the characteristics of smoke and combustion products in fires in a cubicle-type switchboard in an electric room using PyroSim, which is based on the program Fire Dynamics Simulator (FDS). The fire modeling consists of four scenarios according to the operation mode of the mechanical ventilation equipment, the amount of air supply and exhaust, and the location of the air supply slot. The analysis shows that the mechanical ventilation equipment improves the smoke density, visibility, carbon monoxide concentration, and temperature characteristics. The visibility and temperature characteristics were improved when the air flow rate and the location of the air supply slot from fire defense regulations were applied.

• Fire Science and Engineering
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• v.33 no.1
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• pp.69-75
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• 2019

In this study, the combustibility of five types of plastic plates, fiber reinforced plastic (FRP), polystyrene (PS), polycarbonate (PC), polypropylene (PP), and polyvinyl chloride (PVC), were tested using a cone calorimeter (ISO 5660). The PVC plate showed a $44.65kW/m^2$ lower peak heat release rate (HRR) and a $30.97kW/m^2$ lower maximum average rate of heat emission than the other four types of plastics, whereas the PS plate showed a $773.44kW/m^2$ higher peak HRR and $399.14kW/m^2$ higher maximum average rate of heat emission. The PC plate and PS plate showed the highest HRR by a maximum of 3.88 times in $CO_{mean}$ yields, while the PS pate and PP plate showed the highest HRR by a maximum 4.88 times in $CO_{2mean}$ yields. In addition, the smoke performance index (SPI) of the PS plate decreased by 74.81%~95.99%; the smoke growth index (SGI) increased to 76%~300%; the smoke intensity (SI) also increased to 917.73% ~ 9607.57%, and the danger of smoke increased. The PS plate was found to have the highest risk of life damage due to smoke on the thermal and smoke sides.