• Title/Summary/Keyword: 탄소동위원소분석

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A Study on Methods of Separating Soil Respiration by Source (발생원별 토양 호흡 측정 연구 방법에 대한 고찰)

  • Koo Jin-Woo;Son Yowhan;Kim Rea-Hyun;Kim Joon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.1
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    • pp.28-34
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    • 2005
  • We review three methods of separating soil respiration into root and soil microbial contribution: (1) component integration, (2) root exclusion, and (3) isotopic method. Among these methods, component integration and root exclusion are most commonly used. Root respiration contribution to soil respiration estimated by the root exclusion method is higher than those by other two methods. Trenching has little environmental disturbances in soil or on surface of site compared to other methods in root exclusion such as root removal and gap formation. Isotopic method has an advantage over other methods because of minimal soil and root disturbances, but this method is costly and requires techniques for the complex analysis. Trenching seems to be an appropriate in situ method for calculating component contributions to soil respiration with minimum disturbances in site. However, the method overestimates the contribution of microbial respiration because of root decay, and realistic results could be obtained by estimating root decay or avoiding large roots in trenched plots.

Late Holocene Paleoceanography from Core Sediments in the Admiralty Bay and Maxwell Bay, King George Island, Antarctica (남극 킹 죠지 섬 에드미럴티 만과 멕스웰 만 시추 퇴적물의 홀로세 후기 고해양환 경 연구)

  • 박병권;윤호일
    • 한국해양학회지
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    • v.30 no.4
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    • pp.302-319
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    • 1995
  • The geochemical properties, sedimentation rates, foraminiferal distributions, and oxygen and carbon isotope records of sediment from Cores S-2 and S-19 were studied to investigate late Holocene paleoceanographic and paleoclimatic changes of the admiralty and Maxwell Bay, King George Island, Antarctica. Total organic carbon contents increased from the lower part to the upper part of Cores S-2 and S-19, whereas calcium carbonate contents decreased from the lower part to the upper part of Cores S-2 and s-19,whereas calcium carbonate contents decreased from the lower part to the upper part of Cores S-2 and S-19. Twenty-seven foraminiferal species were identified, and Globocassidurina biora was mostly a bundant in sediment samples. The sedimentation rates ranged from 24 cm/kyr to 237 cm/kyr based on /SUP 14/C-age dating of G. biora. The sedimentation rates increased rapidly in the upper part of the Cores. б/SUP 18/O values ranged from 0.3% to 6.2% and б/SUP 13/C values ranged from -3.0% to 0.0% with several fluctuations of the values. The lowest part of Core S-2, at 128 cmbsf in depth, had a /SUP 14/C-age of 3,100${\pm}$60 yr B.P. and the lowest part of Core S-19, at 230 cmbsf in depth, of 7,400${\pm}$ yr B.P. The results of geochemical and sedimentological analyses of the core sediments suggested five stages of paleoceanographic and paleoclimatic changes as follows: war,-cold stage of 7,500∼6,500 yr B.P., cold stage of 6,500∼3,600 yr B.P., cold-warm stage of 3,600∼2,770 yr B.P., warm stage of 2,770∼2,380 yr B.P. and cold-warm stage of 2,380∼2,100 yr B.P.

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Determination of the Origin of Particulate Organic Matter at the Lake Paldang using Stable Isotope Ratios (${\delta}^{13}C$, ${\delta}^{15}N$) (입자성 유기물의 안정동위원소비를 이용한 팔당호 수계내의 유기물 기원 연구)

  • Kim, Min-Seob;Kim, Jong-Min;Hwang, Jong-Yeon;Kim, Bo-Kyong;Cho, Hang-Soo;Youn, Seok Jea;Hong, Suk-Young;Kwon, Oh-Sang;Lee, Won-Seok
    • Korean Journal of Ecology and Environment
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    • v.47 no.2
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    • pp.127-134
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    • 2014
  • Organic carbon and nitrogen stable isotope ratios of particulate organic matter (POM) were determined at 7 stations (6 stations in Han river and Paldang dam outflow station) from May to October 2013, in order to understand the origin of POM at the Han river. ${\delta}^{13}C$ values of POM in four stations showed significant seasonal changes season, but ${\delta}^{15}N$ values were enriched in around Kyeongan stream (K). POC, PN and Chl-a concentration showed a similar seasonal pattern in Kyeongan stream, with an apparent decrease from July to August. POC and PN concentration has a higher correlation with Chl-a concentration in Kyeongan stream (K). ${\delta}^{13}C$ and ${\delta}^{15}N$ values of POM has a lighter value during lower Chl-a concentration peroid, compared to other seasons. Our results revealed that Kyeongan stream (K) seemed to be influenced by substantial amount of organic manure or fertilizer input in 2013, compared to the previous year (2012). These results suggest that the analysis of stable isotope ratios is a simple but useful tool for the identification of organic matter origin in aquatic environments.

Quality Properties of Honey in Korean Commercial Markets (국내 유통되는 벌꿀의 품질특성)

  • Kim, Jae-Young;Song, Ha-Yeon;Moon, Jin-Ah;Shin, Min-Hong;Baek, Seung-Hwa
    • Korean Journal of Food Science and Technology
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    • v.46 no.4
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    • pp.432-437
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    • 2014
  • This study was carried out to examine the quality properties of honey in Korean commercial markets. The moisture content, stable carbon isotope ratio, invert sugar, cane sugar, and hydroxy-methylfurfural (HMF) contents of honey were measured according to the Korea Food Code and AOAC's (Association of Official Analytical Chemists) official methods. The stable carbon isotope ratio ranged from -25.18‰ to -12.60‰, which clearly differed between honey of $C_3$ origin (flower) and $C_4$ origin (artificial). Results of quality measurements revealed a moisture content of 18.12 to 19.70%, fructose content of 36.10 to 43.94%, glucose content of 22.61 to 31.91%, sucrose content of 1.56 to 4.75%, invert sugar content of 64.89 to 72.79%, and HMF content of 4.10 to 78.66 mg/kg. These values demonstrate that the quality of the tested honey meets the standard criteria of the Korean Food Code and Codex. However, it is necessary to reconsider the appropriate criteria for imported honey because it is circulated in the market through a long distribution process.

Determination of the Origin in both Dissolved Inorganic Nitrogen and Phytoplankton at the Lake Paldang using Stable Isotope Ratios (δ13C, δ15N, δ15N-NO3 and δ15N-NH4) (질산염 및 식물플랑크톤의 안정동위원소비를 이용한 팔당호 수계내의 질소원 기원 연구)

  • Kim, Min-Seob;Lee, Eun-Jeong;Yoon, Suk-Hee;Lim, Bo-La;Park, Jaeseon;Park, Hyunwoo;Chung, Hyen-Mi;Choi, Jong-Woo
    • Korean Journal of Ecology and Environment
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    • v.50 no.4
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    • pp.452-458
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    • 2017
  • The nitrogen isotope value in both ammonium and nitrate ion were determined at 9 stations during both June and August 2016, in order to understand the origin of DIN at the Han river. ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ values in 8 stations (CP, SB, MHC, P4, SJ, SBC, P2, SC) were no significant variation. However ${\delta}^{15}N-NO_3$ and ${\delta}^{15}N-NH_4$ values in KK (Kyeongan stream) showed significant different in comparison with 8 stations, with an apparent increase of nitrogen isotope values. These results indicate that antropogenic nitrogen source influence on KK station. Also the ${\delta}^{13}C$ and ${\delta}^{15}N$ isotope ratio of phytoplankton (Diatom and Cyanobacteria) in KK (Kyeongan stream) showed heavier values, compared to other study stations. These results indicate that nitrogen isotope value in phytoplankton effects by different nitrogen source in study sites. These results suggest that the analysis of stable isotope ratios is a simple but useful tool for the identification of dissolved inorganic nitrogen origin in aquatic environments.

An Experimental Study on Depositional Environments and Consolidation Properties of Shihwa Deposits (시화지역 퇴적층의 퇴적환경과 압밀특성에 관한 연구)

  • 원정윤;장병욱;김동범;손영환
    • Journal of the Korean Geotechnical Society
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    • v.20 no.5
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    • pp.49-58
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    • 2004
  • Consolidation properties of Shihwa deposits were analysed by means of depositional environments. Depositional environments including particle size distributions, sediment structures, geochemical properties, porewater chemistries and carbon age dating were analysed using undisturbed samples retrieved successively from a boring hole in the study area. Laboratory oedometer tests and anisotropic consolidated triaxial tests (CKoUC) for undisturbed samples were performed to examine the overconsolidation phenomena. Based on the results of analysis of depositional environments, it was found that the upper silt/clay mixed layer was deposited under marine condition while underlying sand and clay layers were deposited under fluvial condition. Planar laminated structures of silts and clays were dominant in marine deposits. Although there was no clear evidences that geological erosion had occurred in marine deposits, overconsolidation ratios of the upper marine samples were greater than unity Stress Paths of the upper marine samples behaved similarly to those of normally consolidated clays. Data plotted in stress state charts showed that the marine deposits were normally consolidated in geological meaning. These apparent overconsolidation of the marine deposits can be explained by the structures i.e. chemical bonding due to the difference of the rate of deposition, not by geological erosions and ground water fluctuations.

Usefulness of Biochemical Analysis for Human Skeletal Remains Assigned to the Joseon Dynasty in Oknam-ri Site in Seocheon, Korea (조선시대 인골에 대한 생화학적 분석의 유용성: 서천군 옥남리 회곽묘 출토 인골을 중심으로)

  • Kang, So-Yeong;Kwon, Eun-Sil;Moon, Eun-Jung;Cho, Eun-Min;Seo, Min-Seok;Kim, Yun-Ji;Jee, Sang-Hyun
    • Journal of Conservation Science
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    • v.26 no.1
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    • pp.95-107
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    • 2010
  • Biochemical research was carried out on 4 human skeletal remains from historical lime-layered tombs assigned to the Joseon Dynasty in Oknam-ri, Seocheon. The preservation of femur was evaluated by stereoscopic microscopy and scanning electron microscopy. Most of specimens showed good histological preservation. The histological results proved to be a good potentiality for biochemical analysis using bio-molecules. The amelogenin gene and mitochondrial DNA (mtDNA) analyses revealed that three specimens perhaps have maternal consanguinity due to sharing with mtDNA haplogroup D4b1, and two specimens buried in the same tomb were a couple in Gatjaegol site. Carbon and nitrogen stable isotope analysis indicated that four deads diet were built around C3 plant as rice, barley, wheat and bean. In this study we characterized genetic and diet features from the social stratum who could make lime-layered tombs during period of the Joseon Dynasty. The results suggest that biochemical research using the human skeletal remains from the Joseon Dynasty has the great potential and reasonable value for archaeology, anthropology, and population genetics.

마지막 최대빙하기 이후 북극해 스발바드군도 Van Mijenfjorden의 고환경 변화

  • 남승일;김예동;윤호일;강천윤
    • Proceedings of the Korean Quaternary Association Conference
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    • 2004.06a
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    • pp.46-46
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    • 2004
  • Van Mijenfjorden은 스발바드 군도의 Spitsbergen 서부에 위치하는 두 번째로 큰 피오르드로 온난하고 염분도가 높은 북대서양의 표층수가 북극해로 유입되는 Gateway에 위치하기 때문에 전지구적이며 지역적인 기후변화의 영향을 받는 지역이다. 1999년 IMAGES 프로그램의 일환으로 프랑스 탐사선인 'R/V Marion Dufresne'을 이용하여 북극해의 스발바드 군도에 위치하는 Van Mijenfjorden (77$^{\circ}$ 46.87'N and 15$^{\circ}$ 17.81'E)에서 약 18m의 빙ㆍ해양 퇴적물 코아(MD99-2305)를 시추하여 마지막 최대 빙하기 이후의 고환경변화를 연구하였다. AMS 14C 연대 측정에 의하면 diamicton 층인 하부 2m를 제외한 16m의 퇴적층은 지난 12cal. ka BP경에 피오르드에 존재하던 조수빙하(tidewater glacier)가 해빙되기 시작한 이후에 퇴적되었다. 특히 유기지화학 자료와 부유성과 저서성 유공충의 산출양상 그리고 저서성 유공충인 C. reniforme의 산소ㆍ탄소 안정동위원소 비에 의하면 코아 MD99-2305에는 Van Mijenfjorden에서 홀로세 동안에 일어난 퇴적환경변화를 잘 기록하고 있다. 특히 홀로세 동안에 피오르드내의 퇴적환경 변화는 조수빙하의 확장과 후퇴와 밀접한 관계가 있으며, 유기물의 탄소동위원소(13Corg) 비는 -24에서 -22$\textperthousand$ 값의 변화를 보인다. 이는 Van Mijenfjorden 퇴적물에 공급된 유기물은 육상과 해양기원이 혼합되어 퇴적되었음을 지시한다. 지난 12 cal. ka BP 이후 13Corg 값이 뚜렷하게 변하는 것은 Van Mijenfiorden에서 조수빙하의 변동과 표층수에서의 생산력의 변화를 강하게 반영한다. 강하게 반영한다.53%가 이공계 출신, 100대 기업 CEO의 38.4%가 이공계 출신, 대입수능시험에서 자연계 지원비율이 감소 -40.1%('99)\$\longrightarrow$34.7%('00)\$\longrightarrow$29.4%('01)\$\longrightarrow$26.9%('02)\$\longrightarrow$30.3%('03)\$\longrightarrow$31.5%\$\longrightarrow$'04)필요성, 효과적인 운전자 교육 정책 등이 그것이다. 자동차 긴급 피난 차선은 유용한 시설로 여러곳에서 그 기능이 발휘되고 있으므로 많은 고속도로 관계자들은 설계, 시공 및 유지 관리 측면에서 유의해야 할 것이다.미세조직을 광학현미경으로 압출방향에 평행한 방향과 수직방향으로 관찰하였고, 열간 압출재 이방성을 검토하기 위하여 X선 회절분석을 실실하여 결정방위를 확인하였다. 전기 비저항 및 Seebeck 계수 측정을 위하여 각각 2$\times$2$\times$10$mm^3$ 그리고 5$\times$5$\times$10TEX>$mm^3$ 크기의 시편을 준비하였다.준비하였다.전류를 구성하는 주요 입자의 에너지 영역(75~l13keV)에서 가장 높은(0.80) 상관계수를 기록했다. 넷째, 회복기 중에 일어나는 입자들의 유입은 자기폭풍의 지속시간을 연장시키는 경향을 보이며 큰 자기폭풍일수록 현저했다. 주상에서 관측된 이러한 특성은 서브스톰 확장기 활동이 자기폭풍의 발달과 밀접한 관계가 있음을 시사한다.se that were all low in two aspects, named "the Nonsignificant group". And the issues were

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Geochemistry of the hydrocarbon gases in the Pohang Area (포항 지역 지하수에 분포하는 탄화수소 가스의 지화학)

  • Lee Youngjoo;Cheong Taejin;Kim Jinseok;Kim Hagju;Yun Hyesu;Kwak Younghoon
    • The Korean Journal of Petroleum Geology
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    • v.6 no.1_2 s.7
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    • pp.37-43
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    • 1998
  • Chemical components of water, chemical and isotopic compositions of extractable gases were analyzed to characterize the properties of the natural gases which are dissolved in ground water in the Pohang area. Amount of total extracted gases ranges from 27 ml/l to 50.1 ml/l. Hydrocarbon gases are composed of methane ($27{\~}376,420 ppm$) and ethane ($19{\~}127 ppm$). Amount of total hydrocarbon gases is related to the lithology and geological factors around the reservoir. Quantity of hydrocarbon gases tends to increase in the Tertiary reservoirs and in the reservoirs where the Tertiary formations are thick enough. According to the relationship between hydrocarbon gases and total solids in the ground water, it is believed that the hydrocarbon gases were dissolved in the Tertiary formation water. Based on the methane content ($>99.9\%$) and isotopic composition (${\delta}C^{13};-73.1\%_{\circ}{\~}-43.22\%_{\circ}$), we interpret the gases to be of predominantly biogenic origin which were generated by the methanogenic bacterial processes under the low temperature and anoxic conditions.

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An Analysis on the Cryogenic Distillation Process for $^{13}CH_4$ Separation from LNG by Short-Cut Method (Short-Cut 방법에 의한 LNG 성분에서 $^{13}CH_4$초저온 증류 공정 분석)

  • Lee Youngchul;Song Taekyoong;Cho ByungHak;Baek Youngsoon;Song KyuMin
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.22-27
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    • 2005
  • In this study, we analyze computational simulation of cryogenic distillation process to separate $^{13}CH_4$ and $^{12}CH_4$ from LNG by using the cryogenic energy. Used computational simulation program is made Smoker's equation and FUG(Fenske-Underwood-Gilliland)'s method by short-cut method. Generally speaking, the technology of carbon isotope separation is studied by many methods, especially the separation by cryogenic distillation process is commercialized because of many merits.

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