• Title/Summary/Keyword: 탄소동위원소분석

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Palaeodietary Reconstruction of 6th Century Naju Yeongdong-ri People Recorded in Stable Carbon and Nitrogen Isotope Analysis of Human Bone Collagen (뼈 콜라겐의 탄소와 질소 안정동위원소에 기록된 6세기대 나주 영동리 고분군 피장자 집단의 식생활 양상)

  • Choe, Hyeon Goo;Shin, Ji Young
    • Journal of Conservation Science
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    • v.33 no.6
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    • pp.533-539
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    • 2017
  • Stable carbon and nitrogen isotope results recorded in human bone reflects palaeodiet, nutrition, subsistence and palaeoenvironment. We analyzed the remains of the Naju Yeongdong-ri people, who live at around $6^{th}$ century, excavated from stone chambers and stone-lined tombs. The following results of the analysis of stable carbon and nitrogen isotopes were obtained: ${\delta}^{13}C=-19.5{\pm}0.7$‰, ${\delta}^{15}N=9.6{\pm}0.7$‰, (n=9). The value for stable carbon isotopes indicates that the Naju Yeongdong-ri people had a largely $C_3$-based diet such as rice, barley, and beans. On the other hand, the value for stable nitrogen isotopes reflect the consumption of terrestrial animal protein. This study presents new information on the dietary patterns of the Naju Yeongdong-ri people, whose tombs were similar to the Baekje tomb style and their burial type was much like the one followed by the indigenous people of the Yeongsan river basin.

Isotopic palaeodiet studies of human bone from Gyeongju Donggung Palace and Wolji pond site (pond No.3), Goryeo period (경주 동궁과 월지 3호 우물 출토 옛사람 뼈의 동위원소에 기록된 고려시대 식생활 양상)

  • Choe, Hyeon Goo;Shin, Ji Young
    • Analytical Science and Technology
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    • v.32 no.6
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    • pp.262-270
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    • 2019
  • The stable isotopic composition of bone collagen plays an important role in reconstructing palaeodiet, nutrition, palaeoenvironment and their lifestyle. This is the first case in extracting palaeodietary information and breastfeeding pattern of Goryeo people using stable isotope analysis due to the lack of human remains in this period. We analyzed human bone collagen excavated from Gyeongju Donggung palace and Wolji pond No.3. The average values of δ13C and δ15N are as follows: (δ13C(‰) = -19.5 ± 0.9‰, δ15N(‰) = 11.1 ± 1.1 ‰, (n = 4). Stable carbon isotope values shows a mainly C3 based diet such as rice and barley. Stable nitrogen isotope results implies the protein sources attributed to terrestrial animals. There are various age groups in this study, which are adult, child and infant. Two individuals within early childhood age ranges (< 3 years) shows more elevated δ15N values than that of adult and this result implies the continuation of breastfeeding in this group until the age of 3. The results provide new insight into the breastfeeding pattern of Goryeo people, where breastfeeding and weaning practices have important implication for fertility, population dynamics, migration pattern and disease.

Unveiling dietary lifestyle of a Joseon-era mummy by extracting isotopic information from hair and bone (조선시대 회곽묘 출토 미이라의 안정동위원소 분석으로 생애 주기에 따른 식생활 변화 추적)

  • Kang, Da Young;Shin, Ji Young
    • Analytical Science and Technology
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    • v.25 no.5
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    • pp.300-306
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    • 2012
  • This study reports the stable carbon and nitrogen isotope of mummy, the preserved human time capsule from Joseon Dynasty. The stable isotopic composition of biological tissue is expected to be a direct and constant function of diet because the stable isotope ratios do not decay or change in abundance through time. Over the past three decades, stable carbon and nitrogen isotope analysis has been extensively applied for archaeological topics. However, this is the first case in Korean mummy to extract palaeodietary information using stable isotope analysis. We extracted isotopic information from bone collagen and hair keratin, which reflects the lifetime average diet and short-term diet, respectively. The average values of ${\delta}^{13}C$ and ${\delta}^{15}N$ values are -19.0‰ and 11.4‰ (bone collagen), and -21.3‰ and 14.3‰ (hair keratin). Stable carbon isotope shows a mainly $C_3$-based diet from cradle to grave. On the other hand, there is significant difference in stable nitrogen isotope which implies a relatively enriched diet before death. We expect this study opens up a potential to understand the palaeodietary lifestyle in Joseon Dynasty.

Characteristics of Nitrogen and Carbon Isotopes on Organic Matter and River Sediments of Toil Stream in Yeongju Dam Basin (영주댐 유역 토일천 유입 유기물 및 하천 퇴적물에 대한 질소와 탄소 동위원소 특성 연구)

  • Kang, Han;Song, Hye Won;Kim, Young Hun;Kim, Jeong Jin
    • Economic and Environmental Geology
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    • v.55 no.5
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    • pp.439-445
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    • 2022
  • Organic pollutants that contained in stream sediments have origins of mountain soil in natural and cattle manure in human activity. Nitrogen and carbon isotope analysis for mountain soil, cattle manure and stream sediment were performed for contribution evaluation of organic pollutants in Toil stream of Yeongju dam basin. Average carbon isotope ratio(δ13C) is -25.17‰, -22.34‰, and -26.39‰ for river sediments, cattle manure and mountain soil, respectively. Result of carbon isotope analysis suggests that river sediments are more affected by acid soils. Average value of the nitrogen isotope ratio (δ15N) is 9.46% for river sediment, 1.99% for mountain soil, and 19.53% for cattle manure. Result of nitrogen isotopic analysis show that contribution of cattle mature is slightly higher than that of mountain soil in Toil stream sediments.

First GC-IRMS in Korea and Its Application Fields (국내 최초로 도입된 GC-IRMS와 응용분야 소개)

  • Shin, Woo-Jin;Lee, Kwang-Sik;Ko, Kyung-Seok
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.699-703
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    • 2007
  • Compound-specific isotope analysis (CSIA) by isotope ratio mass spectrometer (IRMS) interfaced with gas chromatography (GC) is a state of the art analytical technique for stable isotopes in earth sciences, environmental sciences and forensics. Since early 1990s, GC-IRMS has been widely used to investigate the authenticity of food in forensic science and to trace the sources of organic contaminants in environmental science. In Korea, a GC-IRMS was firstly installed at the Korea Basic Science Institute (KBSI) in early 2005. In this study, we introduce the GC-IRMS of the KBSI shortly to stimulate various isotope-related researches of Korea, and report preliminary CSIA results for BTEX of different manufacturers.

Accelerator Mass Spectrometry in Atmospheric Environment (가속기 질량 분광분석법을 이용한 대기 환경 연구)

  • 문창범;채수조;정준오;정진도
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.103-107
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    • 1999
  • 가속기 질량분광분석법(Accelerator Mass Spectrometry; AMS)은 동위원소 분석에 있어 초정밀 질량 분석 기술에 속한다. 시료(Samples)의 원자를 이온화 시켜 가속시키고, 에너지, 운동량 그리고 전하 상태를 분석하여 최종 얻고자 하는 원자핵의 동위원소, 예를 들어 탄소-14$^{14)C$),의 수를 정확하게 측정하는 분광분석 기술이다. 본 논문을 통하여 AMS를 소개하고 대기 환경 연구에 AMS가 어떻게 응용될 수 있는지 살펴 보기로 한다.(중략)

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Isotopic dietary history of Neolithic people from Janghang site at Gadeok Island, Busan (부산 가덕도 장항 유적 출토 인골의 안정동위원소 분석을 통해 본 신석기시대의 식생활 양상)

  • Shin, Ji Young;Kang, Da Young;Kim, Sang Hyun;Jung, Eui Do
    • Analytical Science and Technology
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    • v.26 no.6
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    • pp.387-394
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    • 2013
  • We aim to unveil dietary history recorded in Neolithic human bone from Janghang site at Gadeok Island, Busan. Excavation of Janghang site at Gadeok Island from 2010 to 2011 is an outstanding discovery in Korean Neolithic archaeology. A large number of human bones (48 individuals) were found at Janghang site, which is the largest-scale Neolithic cemetery in Korea. We extracted human bone collagen from 10 individuals and stable carbon and nitrogen isotope analysis were carried out using carbon and nitrogen analyzer connected to a continuous-flow isotope-ratio-monitoring mass-spectrometer. Although bone histological analysis shows poor preservation state, stable isotope results correspond well with bone collagen quality indicator, which implies that bone collagen reflects lifetime signature. Stable carbon and nitrogen isotope result indicates highly marinebased diet(${\delta}^{13}$C=$-14.5{\pm}1.3$‰, ${\delta}^{15}$N=$-17.4{\pm}1.7$‰, n=10), however the possible input of terrestrial animal and wild plant cannot be excluded. Our isotopic findings provide an invaluable information on Neolithic subsistence economy in this coastal area. In addition, Janghang site shows specific features in burial methods and burial goods. Two different burial methods of arranging bodies are found with extended burial type and particularly high ratio of flexed burial type. There are also burial goods such as pottery. However, there are no significant isotopic differences according to burial methods and burial goods. Although this is a preliminary study on this site, our research will provide important clues in understanding isotopic dietary history of Korean Neolithic people.

Discrimination of vegetable oils by stable carbon isotope ratio and fatty acid composition (탄소 안정동위원소 비율 및 지방산 조성을 활용한 식용유지류의 판별)

  • Kim, Jae-Young;Lee, Sang-Mok;Chang, Moon-Ik;Cho, Yoon-Jae;Chae, Young-Sik
    • Analytical Science and Technology
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    • v.27 no.1
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    • pp.66-77
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    • 2014
  • This study was carried out to examine the authenticity discrimination of circulated vegetable oils by using carbon isotope ratio (${\delta}^{13}C$) and fatty acid composition. This analysis was applied to vegetable oils which we can buy in Korean markets, and the analytical instrument was measured by using EA-IR/MS for ${\delta}^{13}C$ and GC/FID for fatty acid composition. ${\delta}^{13}C$ was separated into 3 groups as $C_3$ plant including sesame oil, $C_4$ plant including maize oil, and rice bran oil. Fatty acid composition was significantly different among vegetable oils. In addition, the interval of low and high price vegetable oils was classified through the scatter plot analysis showing the correlation of the ${\delta}^{13}C$ and fatty acid composition. Therefore, through a simultaneous determination of the ${\delta}^{13}C$ and fatty acid composition, we are able to determine the majority of vegetable oils. It help to ensure food safety in Korean market by exclusion of economically modified adulteration in food.

Seasonality of shellfish gathering using oxygen isotope analysis of Crassostrea gigas from the Gagok-ri shell midden site, Dangjin (산소동위원소 분석을 이용한 당진 가곡리 패총 굴 (Crassostrea gigas) 의 채집 계절 연구)

  • An, Deogim;Lee, Insung
    • The Korean Journal of Malacology
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    • v.30 no.1
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    • pp.1-8
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    • 2014
  • Oxygen isotope analysis was carried out on a oyster (Crassostrea gigas) from the neolithic age Gagok-ri shell midden site, Dangjin, Korea to determine the seasonality of shellfish gathering and site occupation. Isotope samples were taken from the hinge section of the left valve of the oyster. The isotope values of the shell range from -2.02‰ to -6.05‰ vs PDB. The isotope profile shows a seasonal temperature cycle, providing information related to seasonality of shellfish gathering. The isotope values towards the edge of the hinge are gradually increasing, suggesting progressively cooling and a fall period of shell gathering and site occupation. The result shows that the oxygen isotope analysis using oyster shell hinges can be used for archaeological seasonality studies.

Holocene Environments of the Buyeo Area Choongnam Province: Reconstructed from Carbon Isotopic and Magnetic Evidences from Alluvial Sequences (충남 부여지역의 홀로세 기후변화 -탄소동위원소분석과 대자율분석을 이용하여-)

  • Park, Kyeong;Park, Ji-Hoon
    • Journal of the Korean Geographical Society
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    • v.46 no.4
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    • pp.396-412
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    • 2011
  • Multi-proxy analysis was used to produce a high-resolution paleoclimatic record from a thick section of the Holocene alluvial fan deposit in Gatap-ri, Buyeo. According to ${\delta}^{13}C$ analyses, five minor climate fluctuations can be determined. From the stage I to stage VI, climate changes are as follows: cool-dry, warm-humid, cool-dry, warm humid, drier than stage IV, and finally more humid environment than stage V. According to magnetic susceptibility records, four different stages can be identified, among which stage ii shows the highest susceptibility. Stage-i deposit is derived from sediments of back marsh-type wetland. Stage-ii and stage-iii deposits, however, show higher magnetic susceptibility because magnetite-enriched soil from weathered upland was transported to the area to form an alluvial fan deposits. Stage-iv deposit is comparable to the modern plow horizon.