• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1998.05a
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• pp.243-251
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• 1998

내부개질형 용융탄산염 연료전지는 일반적인 연료전지가 갖는 고효율, 저공해, 모듈화 가능성 등의 장점 이외에도, 스택의 반응열을 열교환 없이 직접 개질반응에 이용하는 내부개질 특성 때문에 발전 설비의 단순화에 따른 추가 열효율의 상승이라는 장점을 갖는다. 또한 외부개질 용융탄산염 연료전지가 중앙집중식 대형 발전에 적합한 것과는 달리 내부개질형은 수십 MW 이하의 분산배치형 혹은 현장설치형에 더욱 적합하다는 특징이 있다. (중략)

• Resources Recycling
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• v.17 no.5
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• pp.11-18
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• 2008

The purpose of this study was to evaluate the effects of blast-furnace slag on chemical attack and carbonation of latex-modified concrete (LMC) and ordinary portland cement concrete as slag contents. Main experimental variables were performed latex contents (0%, 15%) and slag contents (0%, 30%, 50%). The compressive strengths, chemical attacks resistance and carbonation depth were measured to analyze the characteristic of the developed LMC and BS-LMC(latex-modified concrete added blast-furnace slag) on hardened concrete. The test results showed that compressive strength of BS-LMC with blast-furnace slag content 30% was quite similar to it of OPC without slag content. The structural quality deterioration was concerned when blast slag content was up to 50%. However, carbonation restraint of BS-LMC with blast-furnace slag 30% was bigger then that of opc. Also, the effects of added latex on OPC and BS-LMC were increased on the carbonation restraint and chemical attacks resistance.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.329-340
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• 2016

Increase in demotion and repair works on buildings in the construction market generates a large amount of construction waste. Recycling of construction waste is important for saving of resources, preservation of environment and constant advance of the construction industry. Accordingly, the environmental and economic value of recycled aggregate, which is produced after waste concrete is crushed, is increasingly highlighted. It is generally known that compared to concrete made of ordinary aggregate, concrete made of recycled aggregate has low quality, and the low quality is dependent on the amount of the bonding heterogeneous (cement paste and mortar) as well as the amount of the pores within the bonding heterogeneous. Reports on carbonation mechanism shows that the pores of cement-based materials are filled up by the progress of carbonation. Therefore, this study aims at an estimation of the period for optimum carbonation reforming appropriate for the thickness of the bonding heterogeneous of recycled aggregate, based on carbonation mechanism, with a view to improving the product quality by means of filling up the pores of the bonding heterogeneous of recycled aggregate. This study drew the carbonation depth according to the passage of age by calculating the bonding ratio and bonding thickness of the bonding heterogeneous as against the particle size distribution of recycled aggregate as well as by chemical quantitative analysis according to the age of accelerated carbonation of mock-up samples imitating bonding heterogeneous. Based on the correlation between the age of accelerated carbonation and carbonation depth, this study also proposed the estimated period of carbonation reforming of recycled aggregate appropriate for the thickness of the bonding heterogeneous.

• Journal of the Korea Concrete Institute
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• v.28 no.4
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• pp.445-454
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• 2016

With the increase of decrepit facilities, construction waste increased to a certain level and now the increase is more or less stabilized. Yet construction waste still constitutes the largest portion of the overall wastes. Also, it is inevitable to spend a huge amount of the national budget due to the aggravating shortage of aggregate caused by prohibition on collection of natural aggregates as well as due to the damage to the land and environment caused by development of the sources of aggregates. As a countermeasure to the situation, the Ministry of Land, Infrastructure and Transport promulgated the quality standard for recycled aggregate to manage the usage of recycled aggregate according to its quality. But use of recycled aggregate for the purpose of high added value still remains nominal. Therefore, this research aims to study the applicability of recycled aggregate concrete as structural concrete by evaluating the quality improvement effects and the performance of the recycled aggregate concrete including recycled fine aggregate and recycled coarse aggregate that have undergone carbonation for 4 days and 14 days respectively in the condition of 60% RH, 20% $CO_2$ and $20^{\circ}C$ temperature, suggested for carbonation modifying from the advance research. The result shows carbonation modify contributed to quality improvement with 0.91% decrease in absorption rate for recycled fine aggregate and 0.7% decrease in absorption rate for recycled coarse aggregate. The physical properties and durability of the recycled aggregate made of aggregate modified by carbonation showed results similar to general concrete, which confirmed the possibility of applying the recycled aggregate made of recycled aggregate modified by carbonation to structural concrete.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.341-348
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• 2016

At present, about 40 million tons of concrete is dismantled each year, which accounts for the largest portion of the total amount of construction waste with 60.8%. It is known about 97.5% of it is recycled. However, most of the usage of waste concrete is limited to lower value-added business areas, and considering the increasing amount of waste concrete generated due to the deterioration of structures, the need for converting waste concrete to structural concrete is urgent. Therefore, this study aims at estimating the period for the optimum carbonation reforming to improve the quality of recycled aggregate, by making use of the method of accelerated carbonation reforming of the bonding heterogeneous (cement paste and mortar) for the purpose of converting recycled aggregate to structural concrete. Based on the period appropriate for the heterogeneous thickness and each bonding thickness of recycled aggregate which was drawn from previous studies, the changes in the characteristics and physical properties of pore structure according to progress of accelerated carbonation were analyzed. The result shows that with the progress of carbonation, the pore volume and the percentage of water absorption of the bonding heterogeneous decreased and the density increased, which indicates improvement of the product quality. But after certain age, the tendency was reversed and the product quality deteriorated. Synthesizing the results of previous studies and those of the present study, this study proposed 4 days and 14 days respectively for the period for the optimum carbonation reforming of recycled fine aggregate and recycled coarse aggregate.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.908-912
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• 2012

Lauan sawdust was gasified by steam reforming for hydrogen production from biomass waste. The fixed bed gasification reactor with 1m height and 10.2 cm diameter was utilized for the analysis of temperature and catalysts effect. Steam was injected to the gasification reactor for the steam reforming effect. Lauan sawdust was mixed with potassium carbonate, sodium carbonate, calcium carbonate, sodium carbonate + potassium carbonate and magnesium carbonate + calcium carbonate catalysts of constant mass fraction of 8:2 which was injected to the fixed gasification equipment. The compositions of production gas of gasification reaction were analyzed at the temperature range from $400^{\circ}C$ to $700^{\circ}C$. Fractions of hydrogen, methane and carbon monoxide gas in the production gas increased when catalysts were used. Fractions of hydrogen, methane and carbon monoxide gas were increased with increasing temperature. The highest hydrogen yield was obtained with sodium carbonate catalyst.

• 한국전기화학회:학술대회논문집
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• 2001.06a
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• pp.243-248
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• 2001

• 한국전기화학회:학술대회논문집
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• 2001.06a
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• pp.94-101
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• 2001

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.264-267
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• 2005

수소의 소규모 분산 생산 기술은 본격적 인 수소 인프라가 도입되기 전에 연료전지 자동차의 수소 충 전용이나 분산 발전형 연료전지의 수소 공급을 위해 필요하다. 생산 용량은 수소 기준으로 $10\~100 Nm^3/hr$ 정도로 현재로선 천연가스의 수증기 개질법이 가장 경제적인 공정으로 알려져 있다. 소규모 생산에 따른 열효율 저하를 줄이 기 위해 단위 공정들이 통합된 컴팩트 개질 시스템의 개발이 필요하다. 핵심 기술인 컴팩트 리포머의 국산화 기술 확보를 위하여 $20 Nm^3/hr$용량의 동심관형 리포머를 설계, 제작하였다. 내부구조는 제작의 단순화를 고려하여 중첩된 동심관이 배열되었고 압력 손실과 열웅력 발생을 억제하도록 유로를 배치하였다. 수증기개질 반응에 필요한 반응열은 리포머 본체에 부착된 버너를 이용하여 공급하였다. 성능 측정을 위한 부속 기기로 상온 흡착식 탈황기, 폐열 회수형 수증기 발생기, 반응물 예열을 위한 열교환기, 생성 가스 응축기를 설계 제작하여 전체 리포밍 시스템을 구성하였다. 반응 온도 $680\~720^{\circ}C$, 탄소 대 수중기 비(S/C ratio) $2.7\~3.2$ 조건에서 수증기 개질 반응을 수행하였다. 해당 반응 조건에서 메탄 전환율 $89\%$ 이상, 저위 발열량 기준 개질 열효율 $70\%$ 이상을 달성하였고 개질 생성가스 내 수소의 최대 유량은 $23.4Nm^3/h$였다. 개발된 리포밍 시스템은 고순도 수소 생산이 필요한 경우, 수소 수율 향상을 위한 고온 수성 가스 전화 반응기를 통합 가능하도록 열교환기 구성을 조정할 수 있으며 용융 탄산염 연료전지와 같이 고온형 연료전지의 경우 $550^{\circ}C$ 이상으로 개질 생성 가스를 공급하도록 구성할 수도 있다. 향후 리포머 본체의 개질 효율 향상 및 장치 소형화, 부속 기기의 최적화를 통한 전체 리포밍 시스템 개선, 스케일 업 설계를 위한 엔지니어링 설계 패키지 구성을 계획하고 있다.

• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.726-730
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• 2019

The removal of calcium ions using zeolite to solve problems of the CaCO₃ manufacturing process using cement kiln dust was investigated. To do so, a modified zeolite was employed and experiments were conducted to select the optimal zeolite type considered the binding cation and structure, evaluate the removal performance of calcium ions, the influence of the type and concentration of the modifying solution, and the removal selectivity when K coexists. Among five zeolites, 13X zeolite was found to have the best calcium ion removal performance, and it was confirmed that the removal performance was enhanced when KCl was used as a modifying solution instead of NaCl. This study is expected to be the basis for the solution of carbonation process and high concentration of KCl recovery technology.