• 보존과학연구
• /
• s.35
• /
• pp.87-98
• /
• 2014

Fourier transform infrared spectroscopy(FTIR-ATR) was applied to chemical analysis for conservation status of 10 human bone remains from Joseon Dynasty. The result of crystallinity index (CI) is $4.25{\pm}0.78$, carbonate to carbonate ratio (C/C) is $0.91{\pm}0.04$ and cabonate content (C/P) is $0.19{\pm}0.06$. The higher histological index (HI) confirmed CI and C/P value was increased and C/C value was reduced. While C/C or C/P values analysis is possible. While DNA analysis can be extracted from the bone, C/C values are lower or C/P values are higher was found to the analysis is possible. Chemical assessment of FTIR and histological index consequence is expected to be applicable as a basis for comprehensive understanding of the conservation status excavated bones.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.30 no.2C
• /
• pp.133-140
• /
• 2010

A series of triaxial test was performed in order to determine critical state parameters of calcareous Jeju sand, which comprises angular shape particles with many pores in the surface. It is observed that Jeju sand mainly shows the contractive behavior during triaxial shear due to high extreme void ratios and large compressibility. The peak friction angle of Jeju sand decreases slightly with increasing mean effective stress due to the particle crushing of carbonate materials. However, the peak friction angle of Jeju sand is higher than that of other silica sands because of the more angular particle shape. The critical state friction angle of Jeju sand gradually decreases when the mean effective stress at a critical state increases. Whereas, there is not a clear influence of void ratio on the critical state friction angle. Critical state parameters of Jeju sand are similar to those of calcareous sands, but significantly larger than those of common sands.

• Proceedings of the Korean Quaternary Association Conference
• /
• 2004.11a
• /
• pp.4-13
• /
• 2004

제주도 북제주군 한림읍 협재리에는 대부분 탄산염퇴적물로 이루어진 해안사구가 분포하고 있다. 사구를 이루는 탄산염퇴적물은 연체동물과 홍조류의 조각이 약 80% 이상을 차지하며 그 외에 저서성 유공충, 성게류와 태선동물의 조각, 그리고 화산암편으로 이루어져 있어, 제주도에 분포하는 여러 탄산염 해빈퇴적물의 입자조성과 매우 유사한 경향을 나타낸다. 이러한 탄산염 입자들은 천해에 서식하던 해양생물들에 의해 생성되며, 그 각질이 해빈으로 운반되고 바람에 의해 재동되어 사구를 형성하였다. 특히 이 연구지역의 사구가 분포하는 지점에서 북쪽으로 약 1km 떨어져 있는 협재 해수욕장에는 현재에도 천해에서 생성된 많은 양의 탄산염 해빈퇴적물이 퇴적되어 있으며, 제주도의 타 지역에 비해 매우 빠른 북동${\sim}$북서방향의 바람이 불고 있어, 퇴적물을 해빈에서부터 사구형성지점으로 운반시키는 데 효과적인 역할을 했을 것으로 판단된다. 사구를 절개하여 그 단면을 관찰한 결과, 전반적으로 희미한 수평층리와 사층리가 발달하고 있으며, 그 외의 다른 뚜렷한 퇴적구조는 관찰되지 않는다. 퇴적물의 입자들은 주로 직경이 $0.27{\sim}0.40mm$로 중립질 모래에 해당한다. 이 크기의 입자들은 가장 침식이 잘 될 수 있는 입자크기에 해당하는 것으로 알려져 있으며, 따라서 해빈으로부터 퇴적물이 운반될 때에 특히 이 크기의 입자들이 차별적으로 더 많이 운반되었을 것이라고 생각된다. 또한 퇴적물 입자의 크기와 구성성분의 함량은 각 사구의 전 층준에서 크게 변화하지 않는 것으로 나타나며, 이는 사구가 형성되는 기간 동안 탄산염퇴적물을 운반한 바람의 세기가 어느 정도 일정하였음을 지시한다. 해안사구의 형성시기를 알아보기 위하여 사구의 기반을 이루는 고토양층과 사구 최하부와 최상부의 탄산염퇴적물에 대해 방사성탄소연대측정을 실시하였다. 그 결과, 사구의 형성시기를 지시하는 고토양의 연령은 $680{\sim}720\;BP\;(1,200{\sim}1,300\;AD)$로 측정되었으며, 사구를 이루는 탄산염퇴적물의 연령은 전 층준에서 모두 약 3,500 BP로 측정되었다. 따라서 약 3,500 BP에 천해에서 생성된 탄산염퇴적물이 해빈에 분포하다가 $1,200{\sim}1,300\;AD$에 바람에 의해 재동되고 현재의 위치에 쌓여 사구를 형성한 것이라고 해석할 수 있다. 사구가 형성되기 시작하던 시기는 전세계적으로 춥고 바람이 세었던 Little Ice Age ($1,300{\sim}1,820\;AD$)에 해당하며, 따라서 해빈에 분포하던 많은 양의 탄산염퇴적물이 이 시기에 집중적으로 운반된 것으로 사료된다.

• Journal of the Korean Geosynthetics Society
• /
• v.13 no.4
• /
• pp.57-68
• /
• 2014

This study categorizes the distributed sand around coastal area of Jeju volcanic Island into three groups according to their components, and arranges their characteristics. In the case of basic physical properties, the silicate sand has slightly greater specific gravity than general sand, and the carbonate sand with widespread distribution has a lower specific gravity. In the gross, the carbonate sand has poor particle classifying and low uniformity coefficient because carbonate minerals of relatively large grain size are mixed. The relation between compressive strength and components shows conflicting tendency that silicate and carbonate components have positive correlation and negative correlation with compressive strength, respectively. Based on the components ratio of one to one, the sand having low carbonate component ratio is expected to be able to utilize in construction fine aggregate. To compare between square root (ACI 308) and cube root (KCI 2012) of compressive strength at computation of elastic modulus, it is considered to non-dimensional elastic modulus.

• Economic and Environmental Geology
• /
• v.45 no.3
• /
• pp.317-333
• /
• 2012

The Yeongweol Group is a Lower Paleozoic mixed carbonate-siliciclastic sequence in the Taebaeksan Basin of Korea, and consists of five lithologic formations: Sambangsan, Machari, Wagok, Mungok, and Yeongheung in ascending order. Sequence stratigraphic interpretation of the group indicates that initial flooding in the Yeongweol area of the Taebaeksan Basin resulted in basal siliciclastic-dominated sequences of the Sambangsan Formation during the Middle Cambrian. The accelerated sea-level rise in the late Middle to early Late Cambrian generated a mixed carbonate-siliciclastic slope or deep ramp sequence of shale, grainstone and breccia intercalations, representing the lower part of the Machari Formation. The continued rise of sea level in the Late Cambrian made substantial accommodation space and activated subtidal carbonate factory, forming carbonate-dominated subtidal platform sequence in the middle and upper parts of the Machari Formation. The overlying Wagok Formation might originally be a ramp carbonate sequence of subtidal ribbon carbonates and marls with conglomerates, deposited during the normal rise of relative sea level in the late Late Cambrian. The formation was affected by unstable dolomitization shortly after the deposition during the relative sea-level fall in the latest Cambrian or earliest Ordovician. Subsequently, it was extensively dolomitized under the deep burial diagenetic condition. During the Early Ordovician (Tremadocian), global transgression (viz. Sauk) was continued, and subtidal ramp deposition was sustained in the Yeongweol platform, forming the Mungok Formation. The formation is overlain by the peritidal carbonates of the Yeongheung Formation, and is stacked by cyclic sedimentation during the Early to Middle Ordovician (Arenigian to Caradocian). The lithologic change from subtidal ramp to peritidal facies is preserved at the uppermost part of the Mungok Formation. The transition between Sauk and Tippecanoe sequences is recognized within the middle part of the Yeongheung Formation as a minimum accommodation zone. The global eustatic fall in the earliest Middle Ordovician and the ensuing rise of relative sea level during the Darrwillian to Caradocian produced broadly-prograding peritidal carbonates of shallowing-upward cyclic successions within the Yeongheung Formation. The reconstructed relative sea-level curve of the Yeongweol platform is very similar to that of the Taebaek platform. This reveals that the Yeongweol platform experienced same tectonic movements with the Taebaek platform, and consequently that both platform sequences might be located in a body or somewhere separately in the margin of the North China platform. The significant differences in lithologic and stratigraphic successions imply that the Yeongweol platform was much far from the Taebaek platform and not associated with the Taebaek platform as a single depositional system. The Yeongweol platform was probably located in relatively open shallow marine environments, whereas the Taebaek platform was a part of the restricted embayments. During the late Paleozoic to early Mesozoic amalgamations of the Korean massifs, the Yeongweol platform was probably pushed against the Taebaek platform by the complex movement, forming fragmented platform sequences of the Taebaeksan Basin.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.20 no.6
• /
• pp.283-288
• /
• 2010

Nanosized NiO powder was prepared by mixing an acid nickel salt and a base nickel salt and their reduction behavior was studied. Ni formate was employed as an acid salt and nickel hydroxide and basic nickel carbonate as base salts. One equivalent acid salt was mixed with 9 equivalent base salt. The mixture of the formate and the carbonate produced ~100 run spherical NiO powder by heat treatment at $750^{\circ}C$/2 h, but the mixture of the formate and the hydroxide gave rise to ~100 nm pseudo spherical NiO powder by heat treatment at $600^{\circ}C$/2 h and grew fast to give pseudo cubic crystals of 100~600 run by heat treatment at $750^{\circ}C$/2 h. Reduction by hydrogen gas proceeded much faster for the one with the hydroxide than that with the carbonate to give porous body with well grown necks. Their behavior was studied by analysis of TG/DSC, XRD, and SEM.

• Analytical Science and Technology
• /
• v.12 no.4
• /
• pp.279-283
• /
• 1999

The purpose of this study was to optimize carbonate suspension counting method for the measurements of high level activity of $^{14}C$ in a reactor stack effluent gases. Although it is less sensitive method, the carbonate suspension counting method has been found to be a suitable technique for the $^{14}C$ monitoring of samples with small amount but with high specific activity and to be relatively simple and fast.

• Resources Recycling
• /
• v.15 no.3 s.71
• /
• pp.74-80
• /
• 2006

In this article, we would like to investigate a durability characterization of cement mortar with inert filler, which is ground calcium carbonate(GCC). The kinds of techniques to evaluate cement mortar are chloride ion ingress, carbonation and sulfate attack. For the experimental result of the resistance of chloride ion ingress, carbonation and sulfate attack, as the addition of GCC makes decreasing the permeability by micro-filler effect, the specimens of $5{\sim}15%$ ratio of replacement are superior to the GCC0 mortar specimen with respect to durability of cement matrix in this scope.

• Journal of Energy Engineering
• /
• v.8 no.1
• /
• pp.7-13
• /
• 1999

원형 용융탄산염 단위 연료전지의 성능 및 온도분포가 수치모사를 통해 얻어졌다. 원형 단위전지내에서는 사각형 단위전지에 비해 비교적 균일한 온도분포가 얻어졌다. 전지의 바깥쪽으로 갈수록 가스전환율이 커졌고 전류밀도도 크게 증가하였다. 운전전압이 감소할수록 각 가스들의 전환율은 커지고 전류밀도도 커졌다. 원형 전지에서의 평균전류밀도나 출력은 전압이 높을 때는 사각형 전지보다 작았고, 전압이 낮을 때는 더 컸다. 음극 및 양극 가스의 전환율도 마찬가지였다. 전압이 낮을 때 가스의 전환율이 커서 원형 전지의 효용성이 크게 나타났다.

• 한국해양학회지
• /
• v.21 no.2
• /
• pp.92-100
• /
• 1986

Laboratory investigations of physical (density and porosity), acoustic (velocity and velocity anisotropy), and electrical (resistivity and resistivity anisotropy) properties in deep-sea carbonate sequences at DSDPsites 288 and 289 in the western equatorial Pacific were made and correlated as a function of diagenesis. Profile of resistivity shows almost a mirror image of velocity indicating that electrical resistivity can be a useful variable to determine the diagenetic stage. Some fluctuations in acoustic and electrical properties near the zones of cherty and siliceous limestones for both sites imply significant changes in pore geometry due to interbedded silica. The significantly reduced pore throat size by the presence of silica which provides excess calcium carbonate to adjacent pore spaces is partly responsible for several jumps in acoustic and electrical properties of the zones. These observed geophysical data are interpreted as the result of silica diagenesis influencing carbonate diagenesis.