• Title/Summary/Keyword: 타르

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Toughness Improvement of Unsaturated Polyester Mortars Blended with Polyurethane Liquid Rubber (폴리우레탄 액상고무를 혼합한 불포화 폴리에스테르 모르타르의 인성 증진효과)

  • 최영준;박준철;박정민;김화중
    • Journal of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.283-290
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    • 2002
  • Generally polymer mortar and concrete using unsaturated polyester resin has high strengths and good chemical resistance. However it also has high brittleness and because of this reason, it is not used for the purpose that demands high resistance to impact. The purpose of this study is to improve the brittleness of unsaturated polyester mortar(UPE mortar) which could be used for the flooring material with recycled aggregates and UPE. Polyurethane liquid rubber(PU) and recycled aggregates were used to complement the brittleness and to recycle the resources respectively. The characteristics of mortar were investigated according to the molecular weight and substitution rate of PU. As the molecular weight and PU substitution rate were increased, the viscosity was increased, working life became fast and curing shrinkage was reduced. Compressive and flexural strengths were also reduced but tile brittleness was improved. Therefore, it is seemed that the improved WE mortar could be obtained by using polyurethane liquid rubber with the polyol of molecular weight 2000, 3000.

Stabilization Characteristics of the Pyrolyzed Oil from Waste Lubricating Oil (폐윤활유 열분해유의 안정화 특성 연구)

  • Kim, Seung-Soo;Kim, Young-Seok;Chun, Byung-Hee;Park, Chan Jin;Yoon, Wang Lai;Kim, Sung Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1055-1061
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    • 2000
  • The kinetics of tar formation has been studied experimentally and modeled mathematically for waste lubricating oil after pyrolyzed at batch reactor. And stabilization of pyrolyzed oil has been studied. A combination of series and parallel reaction was assumed for the mechanism of tar formation. From the proposed kinetic model, pyrolyzed oil to tar was found to be rate limiting step for tar formation. It was found that the fly ash and coke had the ability to remove materials of tar formation and to protect oxidation of pyrolyzed oil.

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Correlation Between Flexural Toughness and Cracking Characteristics of Micro-fiber Reinforced Mortar According to Fiber Contents (마이크로 섬유보강 모르타르의 휨 인성과 균열 특성의 상관관계)

  • Shin, Kyung-Joon;Jang, Kyu-Hyou;Kim, Eui Sung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2A
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    • pp.249-257
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    • 2008
  • Various methods have been used to reinforce the cementitious material such as mortar and concrete that have weak tensile strength. Major reinforcing method is to mix matrix with fibers which have strong tensile strength. Recently, micro-fiber reinforced mortar has been studied which removes coarse aggregate and uses micro-fiber with small diameter in order to homogenize the matrix properties and maximize the performance of fiber. Performance of micro-fiber reinforced mortar showing multiple cracking behavior is hardly represented only by the flexural toughness. Therefore, This paper reports the cracking behavior as well as mechanical behavior for various mixtures which have different fiber type and mixture proportions to find the proper parameter representing the cracking characteristic. Correlations between flexural toughness and various cracking characteristics such as cracking area, width and number are explored. As a result, it is found that flexural toughness, volume of fiber and number of cracks are suitable for representing the characteristics of micro-fiber reinforced mortar.

Influence of SO42- Ions Concentration on Sulfate Resistance of Cement Mortars (시멘트 모르타르의 황산염침식 저항성에 대한 SO42- 이온 농도의 영향)

  • Lee, Seung Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5A
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    • pp.757-764
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    • 2008
  • This paper was conducted to evaluate the durability of cement mortars exposed to varying concentrations of sodium sulfate for up to 540 days. Three types of cement mortars, namely OPC, SRC and SGC, were exposed to four sodium sulfate solutions with concentrations of 4225, 8450, 16900 and 33800 ppm of ${SO_4}^{2-}$ ions at ambient temperature. The sulfate deterioration was evaluated by measuring compressive strength and linear expansion of mortar specimens. Experimental results indicated that the maximum deterioration was noted in OPC mortar specimens in highly concentrated sulfate solution. In particular, the $C_3A$ content in cements plays a critical role in resisting expansion due to sodium sulfate attack. Additionally, the beneficial effect of GGBS was clearly observed showing a superior resistance against sodium sulfate attack, because of its lower permeability. Another important observation was that the parameters for the evaluation of deterioration degree are greatly dependent on the products formed by sulfate attack.

The Properties of Durability and Strength of Fiber-Reinforced Polymer-Modified Mortars Using Eco-Friendly UM Resin (친환경 UM수지를 사용한 섬유보강 폴리머 시멘트 모르타르의 내구성 및 강도 특성)

  • Kwon, Min-Ho;Seo, Hyun-Su;Lim, Jeong-Hee;Kim, Jin-Sup
    • Journal of the Korea Concrete Institute
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    • v.25 no.3
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    • pp.313-320
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    • 2013
  • In this study, performance of fiber-reinforced polymer-modified mortar was studied for the development of eco-friendly materials for high performance repair and reinforcement. The general cement mortar and eco-friendly UM resin was mixed with a certain percentage for increased durability. To increase the strength of the polymer-modified mortar, PVA fiber, steel fiber and hybrid fiber were added at a constant rate. Hybrid fiber is contains the same percentage of PVA fiber and steel fiber. In order to determine the strength properties of fiber-reinforced polymer-modified mortar, the compressive strength test, the splitting tensile strength test and the flexural strength test were performed. And, in order to determine the durability properties of fiber-reinforced polymer-modified mortar, water absorption test and chemical resistance test were performed. From the experimental results, polymer-modified mortar using UM resin was improved durability. And the tensile strength and flexural strength increased, which were the vulnerability of fiber reinforced polymer-modified mortar. From this study, fiber-reinforced polymer-modified mortar using eco-friendly UM resin can be used to repair and reinforcement for the external exposure of concrete structures to improve the durability.

The Setting and Strength Characteristics of Lightweight Mortar Using Wood Chips Treated with Water (수처리한 목편을 사용한 경량모르타르의 응결 및 강도특성)

  • Choi, Jae-Jin;Moon, Seung-Kwon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.77-84
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    • 2012
  • It is known that some components of wood obstruct the hydration of cement when wood is mixed with cement. In order to examine the effect of pretreatment of wood chips in hot water, this study conducted the experiments for the setting and compressive strength of mortar by sieving pine wood chips with a 2.4mm sieve, dipping them in waters of different temperatures, and then using them as a part of the fine aggregate. For the experiments, water-cement ratio of the mortar was 0.50 and the amount of the fine aggregate substituted by wood chips was set at 0%, 2%, 4%, 6%, 8%, and 10% of the mass of the fine aggregate. As a result of the test, it was found out that when wood chips were used to substitute fine aggregate for the production of mortar, more usage of wood chips postponed setting more, and the treatment of wood chips with water improved the problem of the delay in setting time. Especially, the final setting time of the mortar which used 2~6% of wood chips treated in $100^{\circ}C$ water for 30 minutes was almost the same as the final setting time of the mortar which used no wood chips. Also, the compressive strength of the mortar which used the wood chips treated with water was compared to that of the mortar which used the wood chips not treated with water. The result showed that the strength improved for age of 7 days and 28 days, while there was little change in strength for age of 3 days.

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An Experimental Study on the Quality of Mortar Mixed with Tapioca Starch (타피오카 전분을 혼합한 모르타르의 품질에 관한 실험적 연구)

  • Yong Jic Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.3
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    • pp.244-250
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    • 2023
  • In this paper, mortar mixed with tapioca starch was manufactured to evaluate the effect of tapioca starch on mortar, through evaluating the quality characteristics of mortar, the impact of tapioca starch on improving the performance and basic quality of mortar was examined. Tapioca starch tended to decrease flow by increasing the viscosity of the dough consistency of fresh mortar, which tended to reduce flow, and decreased by about 10 % as the tapioca starch mixing ratio increased by 0.025 %. In addition, the effect of tapioca starch on the compressive strength of mortar was at the same level regardless of the tapioca starch mixture at 28 days of age. However, at an early age of 3 days, the speed of compressive strength development was accelerated by mix ing tapioca starch. In addition, the effect of tapioca starch on the compressive strength of mortar was at the same level regardless of the tapioca starch mixture at 28 days of age. However, at an early age of 3 days, the speed of compressive strength development was accelerated by mixing tapioca starch. The speed of strength development improved by about 20 % when mixing 0.050 % tapioca starch. The adhesion strength improved by about 60 % when mixing 0.050 % tapioca starch, and the final shrinkage in length change decreased by 5 %.

Effects of Nanoparticles on the Fracture Toughness of Cement Mortar (나노 입자가 시멘트 모르타르의 파괴인성치에 미치는 영향)

  • Seung Won Choi;Cho Won Baek;Seon Yeol Lee;Van Thong Nguyen;Dong Joo Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.332-340
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    • 2023
  • This study investigated the effects of nanoparticles on the fracture toughness of cement mortar. Three-point bending tests, compressive tests, and slump tests were conducted on cement mortars reinforced with carbon nanotubes(CNTs), nanosilica(NS), and nano calcium carbonate(NC), respectively. Cement mortar with a water-to-cement ratio and a sand-to-cement ratio of 0.45 and 1.5, respectively, and reinforced with 0 and 2 vol.% of 19.5 mm steel fibers, respectively, was used. Reinforcement with nanoparticles partially improved the fracture toughness and compressive strength of the cement mortar. However, in the case of cement mortar reinforced with steel fibers, the reinforcement with nanoparticles was found to reduce the flowability of the mortar, adversely affecting the dispersion of steel fibers, and ultimately leading to a decrease in fracture toughness, contrary to the intended enhancement. Additional research is needed to improve the decrease in mortar fluidity caused by the reinforcement with nanoparticles.

Toxicity Evaluation of Tar Colors by Water Fleas and Luminescent Bacteria (물벼룩과 형광성 박테리아를 이용한 타르색소의 독성평가)

  • Choo, Yeon Jong;Kim, Gun Heung;Kim, Hung Soo
    • Journal of Wetlands Research
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    • v.9 no.1
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    • pp.21-29
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    • 2007
  • In Korea, we assign the chemical substances of 535 types as toxic substance. Only 10% of the 535 toxic substances are being managed by the Ministry of Environment related with water quality standard. Tar color is also one of chemical substances, but we have the lacks for the information of tar colors about the environmental effects of aquatic ecosystem. This study performed the test of bioassay using Water Fleas and Luminescent Bacteria. The tar has 7 types of colors allowed as the edible color and we evaluate the toxicities of 5 tar colors out of 7 colors and we would like to provide the informations for further study as we perform the toxicity test for the samples of 5 tar colors. We did the toxicity test of using Water Fleas From the results, we obtained the magnitudes of toxicity in order of Red No.2, Yellow No.5, Red No.3, Yellow No.4, Blue No.1. As the result based on Microtox Acute Toxicity Test using Luminescent Bacteria with the standard of 15min-EC50, we obtained in order of Yellow No.5, Food Red No.3, Red No.2, Yellow No.4, Blue No.1. We could expect the tar colors may have different effects on the aquatic ecosystem, respectively and it may influence to the aquatic ecosystem and the human, because of bioconcentration by food chain when toxicity of the tar colors overflow in the aquatic ecosystem.

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Physical Properties of Polymer Modified Mortar Containing FRP Wastes Fine Powder (폐FRP 미분말을 사용한 폴리머 시멘트 모르타르의 물성)

  • 황의환;한천구;최재진;이병기
    • Journal of the Korea Concrete Institute
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    • v.14 no.2
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    • pp.190-198
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    • 2002
  • In this research the physical properties of polymer modified mortar containing pulverized FRP(Fiber-Reinforced Plastics) wastes fine powder as a part of fine aggregate were investigated. Styrene-butadiene rubber(SBR) latex, polyacrylic ester(PAE) emulsion and ethylene-vinyl acetate(EVA) emulsion were used as Polymer modifier. Polymer modified mortars containing FRP wastes fine powder were prepared with various FRP wastes fine powder replacement(5∼30 wt%) for fine aggregate and polymer-cement ratios(5∼20 wt%). The water-cement ratio, water absorption rates and hot water immersion test, compressive and flexural strengths of polymer modified mortars were tested and the results compared to those of ordinary portland cement mortar. As the results, compressive and flexural strengths of polymer modified mortar containing FRP wastes fine powder depend on the contents of FRP wastes fine powder, type and additional amounts of polymer modifier. Some of them showed higher compressive and flexural strengths than those of ordinary portland cement mortar. Especially, SBR-modified mortar showed the highest strengths properties among three types of polymer modifier. Also water absorption rates, compressive and flexural strengths of SBR-modified mortar were more superior than those of PAE or EVA-modified mortar. The optimum mix proportions of SBR-modified mortar was 20 wt% of polymer-cement ratio and 20 wt% of FRP wastes fine powder replacement. Otherwise heat cured polymer modified mortar accelerated the improvement of early compressive and flexural strengths.