• Title/Summary/Keyword: 크롬 카바이드

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Characteristics of the HVOF_sprayed $\textrm{Cr}_{3}\textrm{C}_{2}$-NiCr Coationg Layer (HVOF 용사된 $\textrm{Cr}_{3}\textrm{C}_{2}$-NiCr 용사층의 특성)

  • Kim, Byeong-Hui;Seo, Dong-Su
    • Korean Journal of Materials Research
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    • v.8 no.9
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    • pp.849-855
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    • 1998
  • The purpose of this study was performed to compare to the characteristics (microstructure, phase change and hardness, erosion rate) of HVOF sprayed coatings with 20wt% NiCr claded and 7wt%NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$ powder. In the case of the 20wt% NiCr claded $\textrm{Cr}_{3}\textrm{C}_{2}$ powder, microstructural feature showed that the primary $\textrm{Cr}_{3}\textrm{C}_{2}$ was remained in the coating but was barely remained in the mixed $\textrm{Cr}_{3}\textrm{C}_{2}$ coating. As a results of XRD analysis, both 20wt%NiCr claded and 7wt% NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$ powder was decomposed during spraying but the degree of decomposition of the 20wt%NiCr claded was lower than 7wt%NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$ powder. After spraying the mixed powder for microhardness was higher than claded $\textrm{Cr}_{3}\textrm{C}_{2}$ powder and which was increased up to $\textrm{Hv}_{300}$= 1665 after heat treatment to $1000^{\circ}C$. however. 20wt%NiCr claded $\textrm{Cr}_{3}\textrm{C}_{2}$ became to decrease at $600^{\circ}C$ which was the maximum.

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Oxidation Behavior of the HVOF-sprayed $\textrm{Cr}_{3}\textrm{C}_{2}$-NiCr Coating Layer (HVOF 용사된 $\textrm{Cr}_{3}\textrm{C}_{2}$-NiCr 용사층의 산화 거동)

  • Kim, Byeong-Hui;Seo, Dong-Su
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.757-765
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    • 1998
  • This study was performed to investigate the influence of fuel/oxygen ratio (F/O= 3.2, 3.0, 2.8) on the oxidation behavior of two kinds of (20wt%NiCr claded $\textrm{Cr}_{3}\textrm{C}_{2}$, and 7wt%NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$) composite powder with different manufacturing method. The results show that the oxidation behavior between the 20wt% NiCr claded $\textrm{Cr}_{3}\textrm{C}_{2}$ and 7wt% NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$ coating was widely different. The surface morphology of the coating composed of 7wt% NiCr mixed $\textrm{Cr}_{3}\textrm{C}_{2}$ was changed to porous with F/O ratio by the aggressive evolution of gas phases($\textrm{CO}_2$, CO and $\textrm{CrO}_3$) and the oxide cluster composed of Ni and Cr were grown after oxidation at $1000^{\circ}C$ for 50 hours. But the surface morphology of the coating composed of 20wt% NiCr claded $\textrm{Cr}_{3}\textrm{C}_{2}$ was not changed to porous after oxidation at $1000^{\circ}C$ for 50 hours. Therefore, the reason for high oxidation rate is due to activation of $\textrm{Cr}_{3}\textrm{C}_{2}$ to oxidation by entrapped oxygen gases within coating layer, and to closely relate with the decomposition of $\textrm{Cr}_{3}\textrm{C}_{2}$ to $\textrm{Cr}_{7}\textrm{C}_{3}$ phase. Accordingly, On the evidence of these results, the study about the oxidation behavoir of the HVOF sprayed $\textrm{Cr}_{3}\textrm{C}_{2}$ coating depending on hydrogen flow rate must be done.

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Abrasive wear characteristics of high Cr cast iron hardfacing (고 Cr 주철계 육성용접부의 연삭(abrasion)마모 특성에 대한 연구)

  • 이형근
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.154-165
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    • 1997
  • Abrasive wear characteristics of high Cr white cast iron-based hardfacing were investigated using the rubber wheel abrasion wear test method according with the ASTM G65-85. Mild steel was also tested for comparison with high Cr cast iron hardfacing. Wear experiments, where the applied force, wheel revolution rate and abrasive powder feed rate were selected as test valuables, were planned and analyzed by response surface method to evaluate wear statistically and quantitatively. Weight loss of high Cr cast iron hardfacing was mostly affected by the applied force and wheel revolution rate, and little by the powder feed rate. Weight loss of mild steel was greatly affected by the wheel revolution rate and powder feed rate, and slowly and steadily increased with the applied force. Abrasive wear mechanism of high Cr cast iron and mild steel was discussed in the light of the wear test results.

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High Temperature Creep Behavior of Cr3C2 Composites (크롬-카바이드 복합체의 고온 크리프 거동)

  • 김지환;한동빈;김기태
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1219-1226
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    • 1995
  • Creep behaviors of Cr3C2 composites containing 90 wt% Cr3C2 and 10 wt% Ni were studied at high temperature. Compression tests at 100$0^{\circ}C$ and bending tests at 100$0^{\circ}C$ and 105$0^{\circ}C$ were done in argon environment. In all test conditions primary and steady-state creep behaviors were observed. Stress exponent and activatiion energy were determined from the experimental data. By microstructural analysis of Cr3C2 composites after creep test, the separate agglomerations of Ni phase were observed. Numerical analysis was also studied to analyze bending creep behaviors of Cr3C2 by assumming different tensile and compressive creep behavior in a bending sample. From the analysis, it was found that the stress state at the compressive region as applied stress increased. The observed creep rates were compared with the predicted creep rates by estimating power-law creep parameters from bending test data.

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Tribological Behaviors of Chromium Carbide Coatings by HVOF Thermal Spraying (HVOF 열용사에 의한 크롬 카바이드 코팅의 마모.마찰거동)

  • 김장엽;임대순;이상로;변응선;이구현
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1315-1321
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    • 1995
  • The optimal coating condition for chrominum carbide coating was selected by Taguchi method. The wear tests with coated specimens by HVOF method were performed in the temperature to 80$0^{\circ}C$. Applied normal loads were selected to be from 8N to 30N. The worn surfaces and subsurfaces were characterized by XRD, EPMA, AES and SEM. The wear track increased with increasing applied normal load, and in terms of the temperature range from 400 to $600^{\circ}C$, below that range, the wear track increased, and above that temperature ragne, the wear track decreased. The degree of oxidation caused by the test temperature and the frictional heating was responsible to the unique high temperature wear behavior chromium carbide coatings.

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LASER CONSOLIDATION OF THE PLASMA COATED CHROME CARBIDE LAYER (레이저를 이용한 크롬카바이드 플라즈마 용사층의 특성향상)

  • An, Hui-Seok;Lee, Chang-Hui
    • Korean Journal of Materials Research
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    • v.7 no.3
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    • pp.203-212
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    • 1997
  • This paper evaluated the feasibility of laser consolidation for improving the properties of the plasma coated layer, Further, the mechanim of the degradation sequence of the chrome carbide layer applied on the turbine blades was postualted. The laser consolidation could be successfully applied for improcing the surface properties of the plasma coated blade, if a proper condition was carefully chosen. The consolidated layer had erosion & corrosion resistance and vond strength superiro to those of the as-plasma coated layer. The properties of the consolidated layer were strongly dependent upon the degree of dilution, especially on the Fe pickup from the substrate. The degradation of the plasma coating layer was thought to be a reault of the repeating action of the solid particle erosion, corrosion penetration through the pores and oxide films formed along the interlayer surface and impact spalling.

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Electrochemical Evaluation on Corrosion Property of Welding Zone of 22APU Stainless Steel (22APU 스테인리스강의 용접부위의 부식특성에 관한 전기화학적 평가)

  • Moon, Kyung-Man;Kim, Yun-Hae;Lee, Sung-Yul;Kim, Jong-Do;Lee, Myung-Hoon;Kim, Jin-Gyeong
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.8
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    • pp.1162-1169
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    • 2009
  • Two kinds of welding methods were carried out for 22APU stainless steel, one is a Laser welding and the other is the TIG welding. In this case, difference of corrosion characteristics of welded zone with two welding methods mentioned above was investigated with electrochemical methods such as measurement of corrosion potential, polarization curves and cyclic voltammogram etc.. Vickers hardness of all welded zone (WM:Weld Metal, HAZ:Heat Affected Zone, BM:Base Metal)in the case of Laser welding showed a relatively higher value than those of TIG welding. Futhermore their corrosion current density in all welding zone were also observed with a lower value compared to TIG welding. In particular corrosion current density of BM regardless of welding method indicated the lowest value than those of other welding zone. Intergranular corrosion was not observed at the corroded surface of all welding zone in the case of Laser welding, however it was observed at WM and HAZ with TIG welding, which is suggested that chromiun depletion due to forming of chromium carbide appears to WM and HAZ which is in the range of sensitization temperature. Therefore their zone can easily be corroded with more active anode. Consequently we can see that corrosion resistance of all welding zone of 22APU stainless steel can apparently be improved by using of Laser welding.