• Proceedings of the Korean Society of Precision Engineering Conference
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• 1994.10a
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• pp.150-155
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• 1994

종래의 초내열합금은 원자력산업과 우주항공산업등에 주로 사용되었으며, 산업이 고도화되어짐에 따라 각종 산업기계와 자동차 분야에까지 광범위하게 사용되어지고 있다. 대표적인 초내열합금으로서의 인코넬(Inconel)은 인성과 Creep 특성이 우수하고, 특히 고온강도가 높고 화학적으로도 안정하여 부식에도 강한 장점을 지니고 있어 항공기 부품재료로서 최근 각광을 받고 있다. 본 연구에서는 일반적으로 사용되어지고 공구재종인 코팅초경합금공구와 세라믹 공구를 사용하여 초내열합금인 인코넬 600을 절삭가공하여, 절삭저항,공구의 파손 및 마모,칩의 용착현상등의 가공성에 영향을 주는 요인에 대하여 검토함으로써, 공구의 종류에 대ㄷ응하는 적절한 절삭영역을 설정하는 것을 목적으로 하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.272-273
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• 2015

DLC는 고경도, 화학적 안정성 및 고내식성, 내마모성 및 낮은 마찰계수로 인하여 여러 산업분야의 표면처리기술로 적용되고 있다. 하지만 DLC의 절연특성은 전기 산업 분야에 적용 한계가 있다. 이번 연구에서는 DLC를 연료전지 중 PEMFC(고체산화물 연료전지)의 금속 분리판 표면처리에 적용시키고자 하였으며, 높은 전도성과 고내식성의 Me-DLC박막 제작을 목표로 하였다. Cr을 Buffer layer로 하고 Cr과 DLC를 동시에 증착한 Cr-DLC 박막을 제작하였다. Cr-DLC코팅의 기계적 특성을 확인하기 위하여 나노인덴터를 이용하여 경도 및 탄성률을 측정하였으며, ball-on disk를 이용하여 마찰계수를 확인하였다. 각 샘플들의 전기전도성을 확인하기 위하여 4-point probe system을 이용하여 측정하였으며, 부식 저항 특성을 확인하기 위하여 1mole $H_2SO_4$ + 2 ppm HF 분위기의 전해질 내에서 동전위 분극시험을 통한 내식성 테스트를 하였으며, XPS를 통하여 Cr-DLC박막내의 구조적 특성을 확인하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.338-338
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• 2015

VRFB(Vanadium Redox Flow Battery)는 바나듐계 이온을 전해질로 사용하는 레독스 흐름 전지로, 전해질의 양이 전지의 용량을 결정하기 때문에 주로 대용량의 전력이 필요한 플랜트 등에서 주로 사용하는 전지이다. 이 VRFB내에는 Current collector의 부식 방지용으로 두꺼운 Graphite판을 BP(Bipolar plate)로 사용한다. 플랜트에서는 대용량 전지를 필요로 하여 Single stack으로는 사용되기 어렵고, Multi stack으로 주로 사용한다. Multi stack의 경우, 수 백장의 BP가 들어가 전지의 부피가 매우 커지게 되고, 이에 본 연구에서는 BP의 두꺼운 Graphite를 얇은 $TiO_2$ 기판으로 교체하여 성능을 비교하는 연구를 진행하였다. Ti 금속기판을 양극산화법으로 $TiO_2$ 나노튜브 구조를 만든 후, $TiO_2$의 전도도 향상을 목적으로 $IrO_2$를 코팅하였다. 결과적으로 기존의 Graphite에 비해 전기화학적 특성이 향상되었음을 확인하였으며, Cell test를 통해 VRFB의 성능을 평가하였다.

• Journal of the Korean institute of surface engineering
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• v.32 no.2
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• pp.100-108
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• 1999

The microstructure and corrosion properties of Al-Si diffusion coated PWA1426 alloy have been investigated. Experimental variables are included temperatures of heat-treatment and coating thickness. The microstructure of coated layer and corrosion properties were analysed by SEM, EDS and hot corrosion test. Two major processes have been found to contribute to microstructural changes in the coating. These are, firstly, the transformation of the NiAl to other $Ni_2Al_3$-based phase and secondly, the precipitation of Cr containing phases. Specimens heat treated at $1080^{\circ}C$ showed superior corrosion resistance to heat treated at $880^{\circ}C$. These increase in life was attributed to the transformation of NiAl and increased coating thickness of PWA1426 alloy.

• Journal of the Korean institute of surface engineering
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• v.33 no.1
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• pp.17-24
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• 2000

The microstructures and corrosion properties of Al-Si diffusion coated PWA1426 and PWA658 alloys have been investigated. The coated layer and corrosion properties were analysed by SEM, EDS and hot corrosion test. According to the results of SEM, it is supposed that the coated layers were composed of mixed, denuded and inter-diffusion layer. The coated PWA1426 alloy improved corrosion properties, compared to the PWA658 alloy. Corrosion debris generated during hot corrosion test of PWA658 alloy are identified as NiO, $TiO_2$and $NiAl_2$$O_4$from coated layer which increase oxidation rate and decrease adhesion. The PWA1426 alloy heat treated at $1080^{\circ}C$ showed that NiAl and $Al_2$$O_3$formed on coated layer.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.19-20
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• 2014

연료전지 스택을 구성하는 핵심 부품 중 하나인 분리판(Bipolar plate)은 반응 연료인 수소와 산소를 분리하여 셀(cell)의 전면적에 균일하게 분배, 공급, 배기 및 전기화학반응에 의해 생성된 전류를 수집하며, 높은 가스밀폐성, 전기전도성 및 내식성이 요구된다. 분리판 소재로는 흑연, 고분자-탄소 복합체 및 금속 등이 사용되고 있으며, 이중 연료전지 스택의 부피, 무게 및 제조비용 감소를 위하여 금속분리판이 주목받고 있다. 그러나 금속분리판의 경우 연료전지 작동환경에서 부식반응에 의한 이온 용출로 인해 전극촉매나 고분자전해질막의 오염을 유발할 수 있다는 단점이 있어 최근 금속계 분리판의 코팅을 통하여 분리판의 내식특성 및 전기적 특성을 향상시키는 연구가 활발히 진행되고 있다.

• Korean Journal of Optics and Photonics
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• v.3 no.4
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• pp.273-279
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• 1992

Position reading devices such as optical encoders are most essential components in numerical control (NC) machines and robots. Fabrication process of optical NC-scales was developed for domestic production. The whole process using photo-lithographic techniques consists of about 10 steps. The process parameters were to be carefully determined through many trial experiments. The scale marks of metal film was printed on a glass substrate. The optimum values of various process parameters were extrilcted. The quality of scale marks was attributed to the each process parameters.

• Corrosion Science and Technology
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• v.15 no.2
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• pp.92-107
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• 2016

Graphene was coated on austenitic and martensitic stainless steels to simulate the metallic bipolar plate of proton exchange membrane fuel cell (PEMFC). Graphene oxide (GO) was synthesized and was reduced to reduced graphene oxide (rGO) via a hydrazine process. rGO was confirmed by FE-SEM, Raman spectroscopy and XPS. Interfacial contact resistance (ICR) between the bipolar plate and the gas diffusion layer (GDL) was measured to confirm the electrical conductivity. Both ICR and corrosion current density decreased on graphene coated stainless steels. Corrosion resistance was also improved with immersion time in cathodic environments and satisfied the criteria of the Department of Energy (DOE), USA. The total concentrations of metal ions dissolved from graphene coated stainless steels were reduced. Furthermore hydrophobicity was improved by increasing the contact angle.

• Corrosion Science and Technology
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• v.8 no.4
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• pp.157-161
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• 2009

The corrosion resistance of reinforcing bar was studied to endure the marine environment during shipment. The red rust on the surface did not damage the adherence in the concrete structures, especially in highly alkaline environment, but made the consumer doubt of the quality. The passivation process by alkalization of the quenching water in the tempcore process failed to endure the long shipping period. The ceramic coating by sol-gel process improved the corrosion resistance without damaging the mechanical properties and adherence between concrete and reinfiorcing bar. Optimal concentration of the coating solution and coating temperature were tested. No additional energy was necessary for the coating process by spraying during cooling process, resulting simplified process and low cost. Salt spray test, cyclic corrosion test and atmospheric test were employed to confirm the resistance. The corrosion rates were presented by rating number and polarization resistance. The coating layer was examined by FIB, XRD and SEM etc.

• Corrosion Science and Technology
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• v.10 no.2
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• pp.65-70
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• 2011

DLC is considered as the candidate material for application of moving parts in automotive components relatively in high pressure and temperature operating conditions for its high hardness with self lubrication and chemical inertness. The properties of interlayer between the substrate and the DLC film were studied. Arc ion plating method have been employed to deposit onto substrate and sputtering method was used for synthesizing DLC onto interlayer. Among these six types of interlayer, deposited DLC film onto TiCN showed excellent value for characteristics. From the results of analysis for physical properties of DLC films, it seems that the adhesion forces were more important factors than intrinsic mechanical properties such as hardness, roughness and wear resistance of DLC films. AFM(Atomic Force Microscope) was used for understanding roughness of DLC films. Hardnesses of the coating layers were identified by nano-indentation method and adhesions were checked by scratch method.