• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.37-42
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• 2006

In this study, $20Nm^3/hr$ scale compact hydrogen generator which can be apply to the hydrogen station was tested for hydrogen station application. $20Nm^3/hr$ scale compact hydrogen generator was developed by upgrading concept of stacking plate reactor from former $20Nm^3/hr$ scale plate hydrogen generator. concepts for improving system efficiency and performance include such as idea of heat recovery from the exhaust, exhaust duct which is especially design for plate type reactor reinforcement of insulation, enlargement of heat exchange area of reactor, introduction of desulphurizer reactor and PROX rector in a compact design, introduction of back fire protection structure of plate burner and so on, We can learn that final prototype of scale-up $20Nm^3/hr$ scale compact hydrogen generator can be operated steadily in 100% road at which over 94% of methane conversion(S/C=3.75) was obtained. In case of making up the weak point, we expect that it is possible to apply to hydrogen station by way of showing an example.

• 한국수소및신에너지학회논문집
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• 제31권1호
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• pp.57-64
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• 2020

The water-gas shift reaction for the compact reformer was carried out at a gas hourly space velocity of 72,152 h^-1 over the Cu-Nb-CeO₂ catalysts prepared by co-precipitation method. In order to investigate the effect of Nb₂O₅ promotion over a Cu-CeO₂ catalyst, the Nb₂O₅ loading amount was systematically changed from 0 to 5 wt.%. Among the prepared catalysts, the Cu-Nb-CeO₂ (1%) catalyst showed the highest catalytic activity (CO conversion=61% at 400℃) as well as 100% CO₂ selectivity. The high activity and stability of Cu-Nb-CeO₂ (1%) catalyst are correlated to high Brunauer-Emmett-Teller surface area, small metallic Cu crystallite size, and enhanced redox property.