• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.3
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• pp.708-715
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• 2016

The modelling and optimization of Methyl Ethyl Ketone (MEK)-Cyclohexane (CH) separation process were performed using pressure-swing distillation with a low-high pressure column and a high-low pressure column configuration. The optimization was performed for the number of theoretical stages, and the location of the feed tray of low column and high column to obtain high-purity MEK at the top. The total reboiler heat duty at the low-high pressure column configuration and high-low pressure column configuration were at 11.7667 Mkcal/h and at 10.3484 Mkcal/h, respectively. The results showed that total reboiler heat duty could be reduced to 12.05% using a high-low pressure column configuration.

• Resources Recycling
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• v.2 no.4
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• pp.1-9
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• 1993

A study on the recovery of nitric and hydrofluoric acids is carried out with pulsed column extractor in order to the industrial application of this process. Firstly, from the continuous experiments about the recovery of acids using domestic stainelss steel pickling solution, it is found out that the free nitric and hydrofluoric acids are only extracted by 70% TBP and the heaby metals such as Fe, Cr and Ni are not extracted. The effectiveness of extraction and stripping generally improves as the pulse velocity(product of amplitude and frequency) is increased, optimum performance typically occuring slightly below an amplitude-frequency product which results in flooding the column because of excessive emulsification. When the pickling solution is treated by 70% TBP at a phase ratio of A/O=1/2 in the extraction and by distilled water at a phase ratio of O/A=1 in the stripping, the concentration of refined acides are 102g/$\ulcorner$ $HNO_3$and 8.8g/$\ulcorner$ HF, respectively and the recovery of $HNO_3$and HF are 90.7% and 75.2%, respectively.

• Journal of the Korean Chemical Society
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• v.50 no.2
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• pp.116-122
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• 2006

In this study we extracted DNA from 100 tissues of breast cancer patients and 103 normals. Then we confirmed single-nucleotide polymorphism(SNP) using PCR-DHPLC(polymerase chain reaction-denaturing high performance liquid chromatogrphy).Also, we studied SNP of samples using several columns to identify relation between packing materials of column and resolution.As a result, we identified 4 C/A, C/G genotypes(4%) in exon 5 and 37 T del genotypes(37%) in exon 8 among 100 breast cancer tissues and 2 in exon 5, 9 in exon 8 among 103 normal samples.In resolution test, we confirmed that PS-DVB(poly styrene-divinylbenzen) column is more efficient than C18 column.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.13 no.1
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• pp.8-16
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• 2020

In this paper, a single-bit 2nd-order delta-sigma modulator with the architecture of cascaded-of-integrator feedforward (CIFF) is proposed for column-parallel analog-to-digital converter (ADC) array used in a low noise CMOS image sensor. The proposed modulator implements two switched capacitor integrators and a single-bit comparator within only 10-㎛ column-pitch for column-parallel ADC array. Also, peripheral circuits for driving all column modulators include a non-overlapping clock generator and a bias circuit. The proposed delta-sigma modulator has been implemented in a 110-nm CMOS process. It achieves 88.1-dB signal-to-noise-and-distortion ratio (SNDR), 88.6-dB spurious-free dynamic range (SFDR), and 14.3-bit effective-number-of-bits (ENOB) with an oversampling ratio (OSR) of 418 for 12-kHz bandwidth. The area and power consumption of the delta-sigma modulator are 970×10 ㎛2 and 248 ㎼, respectively.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.1
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• pp.393-401
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• 2013

Most traditional databases exploit record-oriented storage model where the attributes of a record are placed contiguously in hard disk to achieve high performance writes. However, for search-mostly datawarehouse systems, column-oriented storage has become a proper model because of its superior read performance. Today, flash memory is largely recognized as the preferred storage media for high-speed database systems. In this paper, we introduce fast column-oriented database model and then propose a new column-aware index management scheme for the high-speed column-oriented datawarehouse system. Our index management scheme which is based on enhanced $B^+$-Tree achieves high search performance by embedded flash index and unused space compression in internal and leaf nodes. Based on the results of the performance evaluation, we conclude that our index management scheme outperforms the traditional scheme in the respect of the search throughput and response time.

• Analytical Science and Technology
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• v.22 no.4
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• pp.313-318
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• 2009

Liquid chromatographic enantiomer separation of amino alcohols was performed on several chiral columns based on polysaccharide derivatives under the mobile phase conditions containing acid or base additive. The chromatographic parameters were greatly influenced by the nature of the mobile phase containing acid or base additive as well as the used chiral columns. Compared to chromatographic results obtained in the mobile phase containing base additive (0.1% triethylamine), especially, Chiralcel OD showed dramatically enhanced separation factors and resolution factors with reduced capacity factors under the mobile phase condition containing acidic additive (0.1% trifluoroacetic acid). When the mobile phase containing 0.05% trifluoroacetic acid and 0.05% triethylamine was used on Chiralcel OD, the greatest separation factors and resolution factors among all other mobile phase conditions in this study were observed.

• Journal of the Korean Wood Science and Technology
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• v.18 no.2
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• pp.16-24
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• 1990

아세틸화(化) 고분자(高分子) 축합(縮合)탄닌의 젤침투 크로마토그래피 분석(分析)을 위해 일반적(一般的)으로 사용(使用)되고 있는 폴리스타이렌 표준물질(標準物質)은 부정확(不正確)한 교정(矯正)값을 준다. 한편 유도체화 하지않은 축합탄닌의 젤침투 크로마토그래피는 폴리스타이렌 디비닐벤젠 코폴리머 컬럼과 디메틸 포름아미드를 용매(溶媒)로 사용(使用)하여 매우 만족스럽게 분석(分析)될 수 있었다. 그 컬럼의 교정은 유도처리 되지않은 고분자(高分子) 축합(縮合)탄닌을 이용(利用)하여 수행되었으며 고분자 탄닌을 유도처리 할 필요가 없으므로 탄닌의 신속한 분자량(分子量) 결정(決定)이 가능하고 컬럼 크로마토그래피로 분리(分離)되어지는 탄닌을 연속적으로 분석(分析)할 수 있는 장점(長點)을 가진다.

• Proceedings of the Korean Nuclear Society Conference
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• 1995.05a
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• pp.945-950
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• 1995

핵융합의 원료로 고려되고 있는 삼중수소는 $^{6}$Li(n,$\alpha$)T의 반응을 이용하여 얻을 수 있는데 이때 이 반응의 정보를 보다 많이 알기 위해서는 삼중수소의 분리는 물론 헬륨의 분리도 필요하다. 이를 위해서 MnC1$_2$로 코팅된 알루미나 컬럼을 이용한 방사선 가스크로마토 그래피의 방법을 이용하였다. 기존의 알루미나 컬럼으로는 수소 동위원소들의 분리가 가능하였는데 헬륨동위원소의 경우 컬럼내에서 같은 체류시간 때문에 분리가 어렵다 이를 위해서 두개의 다른 캐리어 가스를 사용함으로서 이를 분리하였다. 본 연구는 두개의 다른 캐리어 가스를 사용하여 수소 동위원소의 분리는 물론 헬륨 동위원소를 분리하였다. 헬륨동위원소의 분리중 두 원소가 서로 Azeotrophy의 성질을 갖는다는 것을 발견하였으며 따라서 헬륨 동위원소의 분리를 위해서는 반드시 서로 다른 두개의 캐리어 가스를 사용해야만 가능하다는 것을 밝혔다

• Journal of the Korean Chemical Society
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• v.37 no.5
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• pp.503-512
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• 1993

The purpose of this study was to investigate the retention behavior of phenols and to predict their retention in RPLC. The retention data of twenty-five phenols were measured on a $\mu-{Bondapak}\;C_{18}$ and a polymeric $C_{18}$ columns with methanol-water and acetonitrile-water as a mobile phase. From the observation of enthalpy-entropy compensation phenomenon, the following conclusions are drawn with regard to the retention mechanism: 1) the retention mechanism of nitrophenols in different from that of metheyl-and chlorophenols in both mobile phase; 2) in methanol-water mobile phase, the retention mechanism of methyl-and chlorophenols is consistent in the range of methanol-water composition; 3) on the other hand, in the case of acetonitrile-water mobile phase, the retention mechanism depends on the volume fraction of acetonitrile. It means that the retention mechanism can not be explained only by a simple interaction. Based on retention data as compared with two columns, it may be said that the hydrophobic interaction of phenols with polymeric $C_{18}$ column was greater than that with monomeric $C_{18}$ column. The equations for predicting the retention of phenols were derived by using hydrophobic substituent constant $(\pi)$ and the sum of Hammett's constant $(\sigma)$ and Taft's steric constant $(E_s)$.

• Journal of Korea Soil Environment Society
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• v.2 no.1
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• pp.35-44
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• 1997

A column study using artificial acid rain was conducted to evaluate the buffering capacities in soil layer and host rock. In an effort to compare the effect of composition of host root two valleys of which compositions of host rock are different were chosen within the study area and the pHs of the water flowing in the valleys were measured from May, 1996 to October, 1996. The pHs of the artificial acid rain prepared by adding appropriate amounts of both sulfuric and nitric acids to distilled water were 3, 4, and 5, and the column effluents were analyzed for major cations and anions. The cation exchange capacities(CECs) of A Horizon and the B Horizon were 9.68 and 6.16 meq/100g, respectively, Compared to the B Horizon, the pH in the column effluent of A Horizon with larger CEC was higher. The sums of $Ca^{2+}$, $Mg^{2+}$, $Na^{+}$in the column effluents gradually decreased, indicating the loss of CEC by acid rain. The field study showed that pHs of the surface water in the valleys increased as the water flows downwards. The magnitude of this buffering capacity was greater for the valley in which smectite in addition to kaolinite and illite was a weathered product of host rocks. This also indicates that host rock as well as soil layer retains the buffering capacity.