• Title/Summary/Keyword: 침투도랑

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Effect of Micelles on the Reaction of RuBPCase in Maize Leaf (옥수수 잎의 RuBPCase 반응에 미치는 미셀들의 영향)

  • 김의락;김현묵
    • KSBB Journal
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    • v.9 no.3
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    • pp.325-331
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    • 1994
  • PGA is formed in a route of CO2 fixation of RuBP catalyzed by RuBPCase, followed by reduction of the PGA by NADH to GAP This reduction is enhanced in an anionic micellar solution(SDS), in which NADH is distributed in the aqueous and the micellar pseudophases in a given ratio. This micellar bounded NADH reacts to PGA, and in higher micellar concentration than $1.25{\times}10^{-2}M$, most of NADH is oxidized to NAD+ by PGA. On the other hand, in the solutions of the positive ionic(CTABr), zwitter ionic(Chaps) and nonionic (Brij and Triton X-100) micelles, the reactions are also enhanced and the concentrations of NADH reach minima with micellar concentrations. Such minima are typical of micellar catalyzed bimolecular reactions, and the fall in concentrations of the reductant followed by a gradual increase is charataristic of reactions of hydrophobic substrates: that is, the reductions of PGA by NADH are sharply enhanced in a range of the lower micellar concentrations, and NADH amounts in ca. $1.25-2.50{\times}10^{-3}M$ micellar solutions are reached to minima, followed by gradual increases of the reductant concentration.

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Preparation of Dextran Microparticles by Using the SAS Process (초임계 반용매 재결정 공정을 이용한 Dextran 입자의 제조)

  • Kang, Dong-Yuk;Min, Byoung-Jun;Rho, Seon-Gyun;Kang, Choon-Hyoung
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.958-964
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    • 2008
  • In this work, micro-sized dextran particles, which have recently been focused as one of the candidate materials for the Drug Delivery System(DDS), were prepared by means of the Supercritical Antisolvent (SAS) process with $CO_2$. With dimethyl sulfoxide(DMSO) as the solvent, effects of the operating variables such as temperature (308.15~323.15 K), pressure(90~130 bar), solute concentration(10~20 mg/ml), and the molecular weight of the solute(Mw=37,500, 450,000) on the size and morphology of the resulting particles were thoroughly observed. The higher solute concentration led to the larger particles, however, the injection velocity of the solution and pressure did not show significant effects on the resulting particle size. With dextran of the lower molecular weight, the smallest particles were obtained at 313.15 K. On the other hand, the size of the particles from the high molecular weight dextran ranged between $0.1{\sim}0.5{\mu}m$ with an incremental effect of the temperature and pressure. For the solute concentration of 5 mg/ml, the lower molecular weight dextran did not form discrete particles while aggregation of the particles appeared when the solute concentration exceeded 15 mg/ml for the higher molecular weight dextran. It is believed that if the solute concentration is too low, the degree of the supersaturation in the recrystallization chamber would not be sufficient for initiation of the nucleation and growth mechanism. Instead, the spinodal decomposition mechanism leads to formation of the island-like phase separation which appears similar to aggregation of the discrete particles. This effect would be more pronounced for the smaller molecular weight polymer system due to the narrower phase-splitting region.

A study on the occurrence of cracks in the tunnel pavement in the soil under use (토사구간 공용중 터널 포장부 균열 발생에 관한 연구)

  • Kim, Nag-Young;Lee, Kang-Hyun;Cho, Nam-Hun;You, Kwang-Ho;Baek, Seung-Chol
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.5
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    • pp.749-760
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    • 2017
  • Recently, the proportion of tunnel structures in roads and railways has increased rapidly. Along with this trend, the rate of occurrence of cracks and dropouts in concrete lining of tunnel structures is increasing. Generally, maintenance of such concrete lining is normalized and managed as the core of maintenance work in tunnel maintenance. However, the maintenance of the tunnel pavement is important in securing driver in the tunnel. In the design of tunnels, the underground condition of the tunnel is designed to be in good rock condition, so there have not been many cases of cracks in the tunnel pavement in the past. Recently, the construction of tunnel structures has been rapidly increased, and the length of the tunnels has become longer.Tunnel pavement installed in these ground conditions is increasing the occurrence of cracks in the pavement due to decrease of bearing capacity of the pavement after a long time. In this study, FWD and GPR were conducted to analyze the types of cracks and the reduction of bearing capacity in the tunnel.

Flexure and tension tests of newly developed ceramic woven fabric/ceramic matrix composites (새로 개발된 세라믹 직포 보강 세라믹 기지 복합체의 인장 및 곡강도 시험)

  • Dong-Woo Shin;Jin-Sung Lee;Chang-Sung Lim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.1
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    • pp.73-87
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    • 1996
  • The mechanical properties of 2D ceramic composites fabricated bythe newly developed powder infiltration and subsequent multiple impregnation process were characterised by both 3-point flexure and tensile tests. These tests were performed with strain gauge and acoustic emission instrument. The woven fabric composites used for the test have the basic combinations of $Al_{2}$$O_{3}$ fabric/$Al_{2}$$O_{3}$ and SiC fabric (Tyranno)/SiC. Uniaxially aligned SiC fibre(Textron SCS-6)/SiC composites were also tested for comparison, The ultimate flexural strength and first-matrix cracking stress of SiC fabric/SiC composite with 73% of theoretical density were about 300 MPa and 77 MPa respectively. However, the ultimate tensile strengths of composite were generally one third of flexural strengths, and first-matrix cracking stress in a tension test was also much lower than the value obtained from flexure test. The lower mechanical properties measured by tension test were analysed quantitatively bythe differences in stressed volume using Weibull statistics. This showed that the ultimate strength and the firs-tmatrix cracking stress of woven laminate composites were mainly determined bythe gauge length of fibres and the stressed volume of matrix respectively. Incorporation of SiC whiskers into the matrix increased first-matrix cracking stress by increasing the matrix failure strain of composites.

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Effects of Rainfall Events on Soil in Orchard Field under Herbicide Treatment. 1. Temporal Characteristics in Soil Physical and Chemical Properties (제초제 처리 과수원 포장에서 강우 사상의 효과. 1. 토양 물리성과 화학성의 변화)

  • Chung, Doug-Young;Kim, Pil-Joo;Park, Mi-Suk
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.1
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    • pp.25-35
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    • 2010
  • The periodic application effects of two different herbicides on soil physical properties were observed in a slightly hilly orchard of pear tree located on the southestern flank of the Palbong Mountain in Gongju Chungnam : (1) bare surface vegetation; (2) glyphosate-treated plot; (3) paraquat-treated plot. The slope of experimental plots ranged from 5.5%to 10.2%at an altitude of 125 mand 896 $m^2$ ($28m{\times}32m$) in area. The total respective rainfall events were 47, 52, 52 times during experimental period from 2006 to 2008, while approximately 65 percent of daily rainfall intensity from2006 to 2008 was less than 20 mm a day. The organic matter contents on the surface 15 cm soil ranging from1.23%to 1.84%in 2006 were changed into from1.35 %to 2.28%in 2008 in the order of control > glyphosate > paraquat > bare plot in 2008, indicating that the herbicide treatment influenced the accumulation organic matter in soil. The changes in soil particle contents showed that the loss of soil particles in top 5 cm soil depth was greater in a bare soil than in other treatments such as control, glyphosate, and paraquat-treated plot. The net changes in the bulk densities showed that there were little variations between May of 2006 and Nov. of 2008 even though there were some losses of the soil particles. The soil strength of the glyphosate-treated bare plots was much greater than those of other plots such as control, glyphosate, and paraquat plots. However the soil strengths in control plots were lower than those in the plots of glyphosate and paraquat treated ones.

The classification and comparison of genetic diversity of genus Malus using RAPD (RAPD를 이용한 능금속 식물종의 계통관계와 유전적 다양성)

  • Huh, Man-Kyu
    • Journal of Life Science
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    • v.17 no.6 s.86
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    • pp.756-761
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    • 2007
  • Cenus Malus is a long-lived woody species primarily distributed throughout Asia. Many species of this genus are regarded as agriculturally and ecologically important. The phynetics and genetic diversity among eight species of genus Malus were reconstructed using the random amplified polymorphic DNA (RAPD) markers. In a simple measure of intraspecies variability by the percentage of polymorphic bands, the M. micromalus exhibited the lowest variation (34.7%). The M. pumila showed the highest (50.0%). Mean number of alleles per locus (A) ranged from 1.347 to 1.500 with a mean of 1.437. The phenotypic frequency of each band was calculated and used in estimating genetic diversify (H) within species. The mean of H was 0.190 across species, varying from 0.155 to 0.220. In particular, two cultivated species, M. pumila and M. asiatica, had high expected diversity, 0.314 and 0.307, respectively. On a per locus basis, the proportion of total genetic variation due to differences among species ranged from 0.388 to 0.472 with a mean of 0.423, indicating that 42.3% of the total variation was found among species. The phylogenetic tree showed three distinct elates. One includes M. sieversii, M. pumila, and M. asiatica. Another includes three M. baccata taxa. The other includes M. sieboldii, M. floribunsa, and M. micromalus. One variety and one form of M. sieboldii were well separated each other. RAPD markers are useful in germ-plasm classification of genus Malus and evolutionary studies.

Behaviors of Arsenic in Paddy Soils and Effects of Absorbed Arsenic on Physiological and Ecological Characteristics of the Rice Plant;V.Effect of arsenic added to soil on ecological characteristics of the rice plant (토양중(土壤中) 비소(砒素)의 행동(行動)과 수도(水稻)의 비소흡수(砒素吸收)에 의(衣)한 피해생리생태(被害生理生態)에 관(關)한 연구(硏究);V. 토양중(土壤中)의 비소함량(砒素含量)이 수도근(水稻根)의 생태(生態)에 미치는 영향(影響))

  • Lee, Min-Hyo;Lim, Soo-Kil;Park, Young-Dae;Lee, Suk-Hee
    • Korean Journal of Environmental Agriculture
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    • v.7 no.1
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    • pp.21-25
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    • 1988
  • A pot experiment was conducted to find out the effect of arsenic(As) added to soil on the number of roots, root diameter, root length and root tissue of the rice plant. The results obtained were as follows: Higher As levels in soil remarkably reduced not only the number of roots, root length and root diameter, but also the diameter of the central cylinder, the route of the water and inor ganic nutrients of the roots. When arsenic was treated in soil, abnormal cells in the cortex of rice root were developed and considerably increased with higher As levels in the soil. These were only observed in the middle and upper parts of root segments except root tips and they looked like rice roots without epidermis in shape. Therefore, the occurrence of the abnormal cells in the root was attributed to high arsenic accumulation in the root. Its mechanism is not clear. However, it is assumed that the abnormal cells had occurred to compensate for lower amount of water and inorganic nutrient absorption by the injured rice root or self-defense against the penetration of arsenic within the rice root.

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An Evaluation of the Structural Integrity of the Polymer-Modified Cement Waste Form (폴리머 시멘트 고화체에 대한 구조적 건전성 평가)

  • Ji, Young-Yong;Kwak, Kyung-Kil;Hong, Dae-Seok;Kim, Tae-Kuk;Ryu, Woo-Seog
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.2
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    • pp.81-86
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    • 2011
  • Polymer-modified cement is the composite material made by partially replacing and strengthening the cement hydrate binders of conventional mortar with polymeric modifiers such as polymer latexes and redispersible polymeric modifiers. It is known that the addition of polymer to cement mortar leads to improved quality, which would be expected to have a high chemical resistance. Therefore, the purpose of this study is to identify the improved chemical resistance, such as low permeability and low ion diffusivity, of the polymer-modified cement as a solidification agent for the radwaste. First, polymer-modified cement specimens by latex modification were prepared according to the polymer content from 0% to 30% to select the optimized polymer content. At those specimens, the water-to-cement (W/C) ratio was maintained to 33% and 50% respectively. After the much curing time, the structural integrity of specimens was evaluated through the compressive strength test and the porosity evaluation by the water immersion method. From the results, 10% of the polymer content at 33% of the W/C ratio was shown to have the most improved quality. Finally, the leaching test referredfrom ANS 16.1 for the specimens having the most improved quality was conducted. Dedicated specimens for the leaching test were then mixed with radioisotopes of $^{60}Co$ and $^{137}Cs$ at the specimen preparation.

Organic-inorganic Nanocomposite Adhesive with Improved Barrier Property to Water Vapor for Backsheets of Photovoltaic Modules (태양광모듈용 저가형 백시트 제조를 위한 고수분차단성 유무기 나노복합형 접착제)

  • Hwang, Jin Pyo;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.6
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    • pp.530-537
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    • 2015
  • Photovoltaic (PV) modules are environmentally energy conversion devices to generate electricity via photovoltaic effect of semiconductors from solar energy. One of key elements in PV modules is "Backsheet," a multilayered barrier film, which determines their lifetime and energy conversion efficiency. The representative Backsheet is composed of chemically resistant poly(vinyl fluoride) (PVF) and cheap poly(ethylene terephthalate) (PET) films used as core and skin materials, respectively. PVF film is too expensive to satisfy the market requirements to Backsheet materials with production cost as low as possible. The promising alternatives to PVF-based Backsheet are hydrocarbon Backsheets employing semi-crystalline PET films instead of PVF film. It is, however, necessary to provide improved barrier property to water vapor to the PET films, since PET films are suffering from hydrolytic decomposition. In this study, a polyurethane adhesive with reduced water vapor permeation behavior is developed via a homogeneous distribution of hydrophobic silica nanoparticles. The modified adhesive is expected to retard the hydrolysis of PET films located in the core and inner skin. To clarify the efficacy of the proposed concept, the mechanical properties and electrochemical PV performances of the Backsheet are compared with those of a Backsheet employing the polyurethane adhesive without the silica nanoparticles, after the exposure under standard temperature and humidity conditions.

Characterization of Water Absorption by CFRP Using Air-Coupled Ultrasonic Testing (공기결합 초음파탐상에 의한 CFRP 복합재의 흡습 특성 평가)

  • Lee, Joo-Min;Lee, Joo-Sung;Kim, Yong-Kwon;Park, Ik-Keun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.2
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    • pp.155-164
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    • 2014
  • Carbon-fiber-reinforced plastic (CFRP) composites are increasingly being used in a variety of industry applications, such as aircraft, automobiles, and ships because of their high specific stiffness and high specific strength. Aircraft are exposed to high temperatures and high humidity for a long duration during flights. CFRP materials of the aircraft can absorb water, which could decrease the adhesion strength of these materials and cause their volumes to change with variation in internal stress. Therefore, it is necessary to estimate the characteristics of CFRP composites under actual conditions from the viewpoint of aircraft safety. In this study air-coupled ultrasonic testing (ACUT) was applied to the evaluation of water absorption properties of CFRP composites. CFRP specimens were fabricated and immersed in distilled water at $75^{\circ}C$ for 30, 60, and 120 days, after which their ultrasonic images were obtained by ACUT. The water absorption properties were determined by quantitatively analyzing the changes in ultrasonic signals. Further, shear strength was applied to the specimens to verify the changes in their mechanical properties for water absorption.