• Title/Summary/Keyword: 침출법

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Studies on Analysis of Food Additives- (I) Studies on the Determination of Nitrite in Foods (식품첨가물의 분석에 관한 연구 - (I) 아질산근 정량법에 관한 검토)

  • 천석조;천석조;송인상;노정배
    • Journal of Food Hygiene and Safety
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    • v.3 no.2
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    • pp.53-58
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    • 1988
  • This study was carried out to discuss a colorimetric method for the determination of nitrite in meat products issued by the Ministry of Health and Social Affaires of Korea (1985). 1) The recovery rates of nitrite of test solution extracted in the room temperature were higher than those obtained by the heating extraction. 2) In the room temperature, samples prepared with the sUce were more effective than the blendina method and the distlled water as extractina solvent for nitrite was more effective tban tbe phospbate buffer solution. 3) The extracting time showed that thirty minutes were enough to extract nitrite and the diazotizingcoupling reagents, 30% of sulfanilamide and N-l-naphthylethyienediamine were better than others. 4) The nitrite in a test soiution greatly decreased when the solution was distilled. In this case, the test solution should be used as a control. 5) Ten minutes were enough to couple nitrite.

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매립지 근처에서 산성오염물로 인한 토양오염의 지연에 대한 수치적 연구

  • Yoon, Do-Yeong;Han, Chun;Kim, Min-Chan
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.10a
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    • pp.61-64
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    • 1999
  • 산성침출수에 의한 광산폐기물 매립지 근처의 지하 환경의 오염 및 대처 방안의 효과를 수치적으로 예측하였다. 이를 위하여 지하토양에서 Darcy 법칙을 사용한 침출수의 흐름과 이산-분산에 의한 오염물질의 이동현상을 예측하기 위하여 Galerkin 유한요소법을 활용하였다. 토양오염의 지연을 위하여 석회석 차수막을 연직형과 수평형을 도입하여 그 효과를 조사하였다. 수평차수막에서의 수착이 오염물질의 이동을 지연시키는데 상당한 효과가 있는 것으로 나타났다. 반면에 연직차수막은 지하수의 우회유동으로 인한 오염물질의 확산이 가중되고 있는 것으로 예측되었다. 전반적으로 침출수의 흐름은 광산매립지 제방 근처에서 강하게 일어나는 것으로 나타났다. 이를 근거로 차수막의 효과적인 설치방안이 고안되어야 할 것으로 보인다.

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A Study on the Leaching of Gold and Silver from Concentrate by Acidothiouration (산성치오요소법에 의한 금정광으로부터 금, 은의 침출에 관한 연구)

  • 김성규;이화영;오종기
    • Resources Recycling
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    • v.3 no.2
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    • pp.17-23
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    • 1994
  • The dissolution of gold and silver from concentrate was studied with acidic thiourea solution. The results showed that the gold and silver extraction was severely affected by concentration of thiourea and oxidant, pulp density, etc. Especially, oxidant such as ferric ions enhanced the leching rate of gold and silver. High concentration of ferric ions, however, dissolved the sulfide ore to form electrochemically passive layer on the surface of ore particles, which caused the precious metal not to be leached out from the ore. The use of $SO_2$could not effectively enhance the recovery of precious metal but reduce to some extent the consumption of thiourea. The leaching of gold and silver was achieved with recovery more than 90% and 80%, respectively, under the following conditions; Thiourea conc. :0.4M Oxidant : None $H_2SO_4$ conc. : 0.5M Pulp density : <10% Leaching time :4 Hrs Potential :250mV The Thiourea was consumed about 10% in comparison with its initial concentration.

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Characteristic of Leaching with Incineration Fly Ash of Industrial Solid Wastes (산업폐기물 소각장에서 발생된 소각비산회의 침출특성)

  • 양종규;김종화;서명교;고태규
    • Resources Recycling
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    • v.8 no.1
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    • pp.18-22
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    • 1999
  • In order to utilize incineration fly ash of industrial wastes as resources, we present the recovery and separation of metals included in the fly ash by leaching with aqueous solution A great quantity of Cu, Pb, and Zn as well as a small amount oftoxic heavy metals are contained in the leach liquor of the fly ash, and the concentration of the ingredients of the fly ash depends on the industrial wastes which are fed into incinerators. In this paper, sequential Ieachiog operations are conducted using $H_2O$, $H_2SO_4$, $(NH_4)_2CO_3$ and NaOH as Icachants. Water soluble copper salt was leached by $H_2O$, Zn and Pb were separated by the NaOH leach liquor, and water insoluble copper was selectively leached as chelate ion with the $(NH_4)_2CO_3$ leach liquor of the third Ieaehant. Results show that the reduction percent of the fly ash in the leaching steps using $H_2O$, $H_2SO_4$, and $(NH_4)_2CO_3$ is 77%, and the other leaching procedures lose the weight of fly ash by above 60%.

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Evaluation of Fly Ash Disposal Methods by Analysis of Leachate Migration (침출수 이동 해석을 통한 석탄재 처분방식의 평가)

  • 이상일
    • Water for future
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    • v.25 no.4
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    • pp.61-73
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    • 1992
  • There are needs to examine the consequences of a regulation in effect to control the migration of leachates from disposal sites. The main objective of this study is to illustrate the methodology to evaluate basic disposal designs for compliance with a certain regulation, The "100/100 rule" is selected for demonstration purpose which dictates that the time for the leachates to travel a horizontal distance of 100feet (30.5m) away from the property where the landfill or pond is located must exceed 100 years. The two primary methods for disposal of ash from coal-fired utility plants, landfill and pond, are studied, Numerical groundwater flow analysis resulted in pressure head distribution and flux information in the cross-section of the domain while path line analysis provided travel path and time of leachate migration to compliance zone.ance zone.

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Characterization of Pretreatment by NaOH Leaching for Production of Bioethanol from Palm Waste (팜 부산물 활용 바이오 에탄올 생산을 위한 NaOH 전처리 공정의 특성)

  • Woo, Sang Sun;Park, Ji-Yeon;Na, Jong-Boon;Lee, Joon-Pyo;Lee, Jin-Suk
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.106.1-106.1
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    • 2010
  • 본 연구는 팜 부산물로부터 바이오 에탄올을 생산하는 전처리-당화-발효 공정의 첫 번째 단계인 전처리 공정에서 팜 부산물을 NaOH를 이용하여 효율적으로 전처리하고자 하였다. 암모니아 침지법과 NaOH 침출법을 비교한 결과 팜 부산물에 대해서는 암모니아 침지에 의한 탈리그닌 효과가 적으며 NaOH 전처리가 적합한 방법임을 알 수 있었다. 40-100 mesh 크기의 팜 부산물을 이용하여 반응온도(110, 130, $150^{\circ}C$), 반응시간(20, 40, 60분) 및 NaOH 농도(5%, 11%)의 변화에 따른 팜 부산물의 탈리그닌율과 글루코스 및 자일로스 회수율 간의 상호관계를 확인하였다. $150^{\circ}C$까지의 온도 조건에서 온도에 의한 자일로스의 분해는 일어나지 않는 것으로 확인되었다. 팜 부산물의 탈리그닌율은 시간이 증가할수록 증가하였으며, 높은 NaOH 농도에서 더 높은 것으로 나타났다. 그러나 글루코스 및 자일로스의 회수율은 높은 농도에서 낮게 나타났으며, 시간이 지날수록 감소하여 손실이 많은 것으로 나타났다. 따라서 NaOH 농도가 낮을수록 당 회수율은 높게 나타나지만, 탈리그닌율이 낮아 당화 효율이 떨어지므로 효소 당화 후에 최종 당 회수율이 높은 NaOH 농도 조건을 결정하여야 하겠다.

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Comparative Evaluation of Various Standard Methods in Leaching Test of Radioactive Waste Form (방사성고화체로 부터의 Co, Cs침출에 대한 표준시험법의 상호비교)

  • Kim, Gi-Hong;Yoo, Yeong-Geol;Jeong, Gyeong-Gi;Hong, Gwon-Pyo;Lee, Rak-Hui;Jeong, Ui-Yeong;Koh, Deok-Jun;Kim, Heon
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.21-31
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    • 2003
  • IAEA, FT-04-020, and ANS 16.1, standard leaching test methods, were evaluated comparatively with their test results. Leaching index of Co-60 and Cs-137 for all waste forms were above 6.0. Their leaching behavior were contrary according to the type of matrix and leachant. Leachability of Co in cement waste form was higher in simulated seawater than demi. water, and higher in demi. water in paraffin waste form. Leachability of Cs was contrary to Cs. Cumulative fraction leached of Co was higher such as IAEA>ANS>FT in cement waste form.

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Recovery of Mg-Ferrite Powder from Acid Leaching Mg Waste by Hydrothermal Method (산 침출 Mg폐액으로부터 수열법에 의한 Mg-Ferrite 분말회수)

  • 김영순;윤기석;안찬영;이종현;원창환
    • Resources Recycling
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    • v.6 no.4
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    • pp.31-37
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    • 1997
  • The Mg-ferrite powders were recovered from acid leaching Mg waste by hydrothermal method. Recovering conditions ofMg-Ferrite were investigated m this system and the powders prepared were characterized, using X-ray analysis, chemicalanalysis, SEM. TEM, and VSM. In this study, pH of solution and the kind of neutralizer wcre important factors on thecharacteristics of the product. The optimum condition of recovering MgPenite was the mole ratio of Fe" : Mg"=2'1, reactiontemperature : ZOWC, reaction time.lhr, at pH=lZ, and Oi partial pressure af 2000 psi. And the powders ~ccovered have amonodispersed and spherelike shapes with the narrow sue distribulion.ow sue distribulion.

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