• Title/Summary/Keyword: 침출법

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Effect of Pre-wilting on the Forage Quality of Organic Sorghum$\times$Sudangrass Silage (예건이 수수$\times$수단그라스 교잡종 유기 사일리지의 품질에 미치는 영향)

  • Lim, Hyun-Jin;Kim, Jong-Duk;Lee, Hyun-Jin;Jeon, Kyeong-Hup;Yang, Ka-Young;Kwon, Chan-Ho;Yoon, Sei-Hyung
    • Korean Journal of Organic Agriculture
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    • v.17 no.4
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    • pp.519-527
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    • 2009
  • The main nutritional problem of sorghum$\times$sudangrass hybrid silage is low quality and dry matter (DM) contents. This experiment was conducted to evaluate whether field pre-wilting treatment of sorghum$\times$sudangrass hybrid silage increases DM content and forage quality of the silage. The experiment was a randomized complete block design with three replications. The treatments were consisted of five different wilting days: 0 day (direct cut silage), 0.5 day, 1 day, 2 days and 3 days. Sorghum$\times$sudangrass hybrid silage with pre-wilting showed low 4.00 pH values, however direct cut silage (control) showed a 4.30 value because of its high moisture content. The DM content of sorghum$\times$sudangrass hybrid silage with pre-wilting was high above 25.1% after 1 days, however that of direct cut silage had 17.6%. And the effluent of wilted silage was decreased with prolonged wilting period, but that of direct cut silage produced effluent of 183 mL/kg. Crude protein and ether extract with wilted silage were decreased, however crude ash was increased with prolonged wilting period. Silage with pre-wilting had higher acid detergent fiber (ADF) and neutral detergent fiber (NDF) contents than control silages, while its non-fiber carbohydrate (NFC) showed the opposite results. Lactic acid and total organic acid were increased with prolonged wilting period. For the palatability of dairy goat, silage with 2 days wilting was highest among silages. The experiment results indicate that wilted sorghum$\times$sudangrass hybrid silage could be recommended as effective method for reducing effluent, increasing pH and forage quality more than direct cut silage. Optimum pre-wilting day of sorghum$\times$sudangrass hybrid silage may be 1 days.

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Nitrogen and Phosphorus Loss with Runoff and Leachate from Soils Applied with Different Agricultural By-product Composts (부산물 퇴비를 시용한 토양에서 표면유거와 용탈에 의한 질소와 인의 유실)

  • Park, Chol-Soo;Joo, Jin-Ho;Lee, Won-Jung;Yoo, Kyung-Yoal;Yang, Jae-E;Ok, Yong-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.6
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    • pp.307-312
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    • 2005
  • Since alpine upland in Pyungchang-gun has been typically applied every two or three years with saprolite, agricultural by-products are inputted to raise soil properties. Therefore, the effect of saprolite application on water quality in runoff and leachate should be monitored. To investigate water quality in runoff and leachate with various treatments of agricultural by-product, lysimeter with dimension of $0.85m{\times}1.75m{\times}0.30m$ was installed in Kangwon National University. Control, mixed compost with cow, chicken and sawdust by-product (CCSC), chicken manure by-product compost (CC), food waste by-product compost (FWC), and beer sewage sludge by-product compost (BSSC) at the rate of $10Mg\;ha^{-1}$ were mixed with soil in 25 cm depth, and water qualities in runoff and leachate were monitored from Jun. 4, 2004 to Oct. 18, 2004. EC ($0.8-2.2dS\;m^{-1}$) and concentrations of total N ($25-75mg\;L^{-1}$) and total P ($0.12-0.43mg\;L^{-1}$) were highest in both runoff and leachate of CC treatment. EC values in CC and FWC treatments continuously increased during lysimeter experiment, while total N and total P concentrations continuously decreased. Average total N concentrations in runoff taken from CCSC, FWC and BSSC treatments were 41, 34 and $37mg\;L^{-1}$, and in leachate were 35, 28 and $34mg\;L^{-1}$, respectively. Average total P concentrations were not different with different treatments. EC values in leachate were higher than those in runoff, and total N concentrations in runoff were higher than those in leachate.

A Study on Fractions and Leaching Potential of Heavy Metals in Abandoned Mine Wastes (휴ㆍ폐광산지역에서 폐재내 중금속의 존재형태 및 용출특성에 관한 연구)

  • 김휘중;양재의;이재영;전상호
    • Journal of Soil and Groundwater Environment
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    • v.8 no.3
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    • pp.45-55
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    • 2003
  • This study investigates the fractional composition and the leaching characteristics of heavy metals in polluted soils due to mining activities. The fractionated composition of heavy metals is classified into five fractions; adsorbed, carbonate, reducible, organic and residual fraction. The status of humic substances in mine wastes of most sites are polyhumic except tailing from Sangdong mine. According to the sequential extraction procedures (SEPs), leaching probabilities of Cd in coal wastes and tailing are relatively low due to high percentage of residual fraction. 46.4% of Ni in tailings from Sangdong mine is probably leached under oxidized environment, and 39.4% of Cu in these tailings is readily extracted under strongly oxidized environment by organic fraction. According to leaching condition of pH 3.0 and pH 5.6, the amount of heavy metals leached out of coal wastes and tailing increases to 1/2 hours. At pH 3.0 and pH 5.6, concentration of Ni in tailing increases up three times of the initial value. Heavy metals released from coal wastes and tailing were not influenced significantly by leaching time.

A Feasibility Study on the Polymer Solidification of Evaporator Concentrated Wastes (폐액증발기 농축폐액 폴리머고화 타당성 연구)

  • Yang, Ho-Yeon;Kim, Ju-Youl
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.4
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    • pp.297-308
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    • 2007
  • The granulation equipment of concentrated wastes is manufactured for the polymer solidification of concentrated wastes. It uses liquid sodium silicate as a granulating agent for the granulating of dried powder containing boric acid. The granulating agent is sprayed in the form of droplet and mean size of dried granules is $2{\sim}4mm$. The new technology which has been used for the polymer solidification of spent resin in U.S. and certified by Nuclear Regulatory Commission (NRC) is successfully applied to concentrated wastes. This uses in-situ solidification process within drum without mechanical mixing. Maximum loading of waste can be achieved without increasing of waste volume. Polymer waste forms were evaluated with several test such as fire test, compressive strength test, leaching test, immersion test, irradiation test, and thermal cycling test according to standard test procedures.

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Effect of Green Tea Beverage on the Removal of Cadmium and Lead by Membrane Filtration (막투과법에 의한 녹차음료의 카드뮴 및 납 제거효과)

  • Choi, Sung-Inn;Lee, Jung-Hi;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.26 no.6
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    • pp.740-744
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    • 1994
  • This study was undertaken to prove the suppressing effect of green tea on the intestinal absorption of heavy metals using in vitro membrane filtration system. From drinking water contaminated with 10 and 100 times level of water quality standard for heavy metals, the removal ratio of lead (Pb) was $50{\sim}70%$ by green and black teas, and $30{\sim}40%$ by roasted barley tea. The removal ratio of cadmium (Cd) was $30{\sim}40%$ by green tea and black teas, and $10{\sim}20%$ by roasted barley tea. The removal effect from drinking water contaminated with both lead and cadmium was lower than that from water contaminated singly with lead or cadmium. It appears that tea components and filter membrane compete toward the adsorption of two heavy metals. Among the extraction conditions of raw tea materials at $70^{\circ}C$, 2 minutes and $95^{\circ}C$ , 10 minutes, the removal ratios of heavy metals were similar.

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국내 가행광산 채굴적 활용 방안

  • 윤철헌
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.11a
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    • pp.213-234
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    • 2002
  • 우리 나라는 70년대까지 광업은 부흥하였으나, 그 이후 급속히 위축되면서 80년대 이후 거의 대부분 광산들이 폐광 또는 휴광된 실정이다. 그 결과 현재 전국 각지에 다수의 폐갱도가 존재하게 되었으며, 이제는 지반침하 및 각종 침출수의 원인자로 간주될 정도이다. 최근 지자체에서는 이런 폐갱도를 지역 자원으로서 가치를 인정하고 지역 활성화를 위해 재 이용하려는 움직임이 보이고 있는데, 구체적으로는 관광시설, 연구시설, 농업생산시설, 저장시설, 폐기물처리시설 등이다. 일본은 폐광된 금속광산 재활용을 위해 입지여건과 주변지역, 입갱 가능성 등 기초조사를 하였다. 조사결과 폐갱도의 문제점으로 입갱이 가능한 광산이 적다는 점을 들 수 있다. 대부분의 광산은 갱구가 함몰되었거나, 갱내에 지하수가 차 있어 접근이 불가능한 경우가 대부분이다. 비교적 양호한 암반 경우는 서브 레벨 스토핑, 잔주, 주방식 등의 채굴법에 의해 대규모 공동이 잔존하고 있는 경우도 있지만 그리 많지 않았다. 폐광된 광산 재활용 여건은 우리 나라와 일본이 대동소이 경우로 현실적으로 활용이 가능한 폐광은 많지 않으며 활용코자 할 때에는 기존갱도를 활용하면서 암반이 견고한 곳에 새로운 갱도를 설치하여야 한다. 그러나 몇몇 곳에서는 매우 유용하게 잘 활용되고 있는 곳도 있고, 연구 검토하면 충분한 활용성이 있다고 생각되는 곳도 있다. 그러므로 현재의 상황을 보고 판단할 것이 아니라, 활용기술과 접목해서 활용성을 검토함으로써 불용 자산의 유용화 방안이 검토되어야 할 것이다. 현재 가행중인 광산은 입지여건 및 암반이 양호하고, 대형갱도를 굴착하는 석회석광산 등을 선택하여 폐광 후 활용이 가능토록 채광기술 발전시켜 나가야 하며, 인간 중심적인 시설 또는 산물 중심적인 시설로 구분하여 폐광 후 복구비용을 우선 지원하는 방식 등을 통하여 시추, 탐광굴진, 현대화, 수갱굴착, 자금융자 등을 지원하는 우리 공사와 산업자원부가 지자체, 산림청, 건교부, 농림부 등과 연계하여 종합적인 지원육성책을 마련하여야 할 것이다. 결과적으로, 지방자치단체 등에서 관심을 갖고 있는 저장시설, 폐기물처리시설, 관광시설, 농업생산시설, 연구시설 등을 중심으로 '광산 채굴적을 미래에 어떻게 활용한 것인가'를 선진외국 사례를 벤치마킹하고, 연구ㆍ검토하여 친환경적인 광산개발이 되도록 기본적인 방향과 개념을 갖도록 하여 관련 정책을 계획적이고, 체계적으로 수립 일관성 있게 추진해 나가야 할 것이다.

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Changes of Cadmium Content Added to Foods During Cooking (식품(食品)에 첨가(添加)한 카드뮴의 조리(調理)에 의(依)한 함량(含量) 변화(變化))

  • Park, Geum-Soon;Lee, Man-Jeung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.8 no.1
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    • pp.43-50
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    • 1979
  • This experiment was designed to investigate the changes of cadmium content of different foods during cooking. 1. By addition of standard cadmium to different foods, recovery percentage was 98.3% by Dithizone Method and 97.9% by APDC. 2. At various pH levels the highest cadmium was extracted at pH 1.0. 3. Cadmium was contaminated at first to six hours of immersion and did not increased after this period. 4. About 2/3 of added cadmium was extracted by different concentrations of acetic acid.

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Characteristic of Flotation for Recovery of Copper from Copper Slag in Kazakhstan (카자흐스탄 구리제련소 슬래그 내 구리회수를 위한 선별 특성)

  • Park, Jayhyun;Choi, Uikyu;Choe, Hongil;Shin, Shunghan
    • Resources Recycling
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    • v.24 no.4
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    • pp.12-21
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    • 2015
  • Almost all copper slags contain a considerable amount of Cu (0.5 - 3.7%) close to or even higher than copper ores. A number of methods for metal recovery from copper slag were reported These methods can be classified into three categories, flotation, leaching and roasting. Sulfide flotation method for the recovery of copper from Kazahstan copper furnace slag is discussed in this investigation. 50% of copper from the slag was recovered by sulfide flotation at pH 4. meanwhile 67% of copper from the slag was recovered at pH 11. Higher copper recovery result at pH 11 rather than that at pH 4 was caused by the fact that copper sulfides were floated in particle size fraction over $100{\mu}m$ in concentrates at pH 11. When the slag were ground below $74{\mu}m$by ball milling, the recovery of copper by floation in slag improved to 78 - 83% because of copper liberation effect.

Recovery of Gallium from Zinc Residues by Solvent Extraction (아연제련잔사로부터 용매추출법에 의한 갈륨의 회수)

  • 김성규;이화영;오종기
    • Resources Recycling
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    • v.9 no.3
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    • pp.29-36
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    • 2000
  • A study on the recovery of gallium from leaching solutions is carried out by solvent extraction in order to produce gallium oxide of high purity. The results show that the extraction of gallium is found to be increase with acidities of aqueous solution up to 7.4 M/L when pure isopropyl ether is used. And the extraction of iron also increases with increasing acidity of aqueous solution. It appears that the separation of gallium from iron cannot be satisfactorily accomplished with isopropyl ether. But, in the case of extaction with D2EHPA, almost complete extraction of iron is achieved-leaving all the gallium in the aqueous solution-by maintaining the acidity of aqueous solution at 2 M/L. Accordingly, $Ga_2O_3{\cdot}H_2O$ of more than 99wt.% in purity can be produced from zinc residues through the processes comprising of alkali leaching, precipitation by neutralization and solvent extraction using isopropyl ether and D2EHPA as extractants.

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A Study on the Electrochemical Behavior of Au and Pd in Hydrochloric Acidic Solution (염산 수용액 중에서 Au와 Pd의 전기화학적 거동에 관한 연구)

  • Yu, Yeon-Tae;Kim, Chi-Kwon
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.76-81
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    • 2001
  • In order to recover Au and Pd from the leaching solution of various electronic wastes by electrowinning, the electrochemical behavior of Au and Pd in hydorchloric acidic solution was investigated by means of voltammetry. The reduction potential of Au ion was 800mV and the limiting current appeared at 470mV in electrolytic solution of gold. The reduction potential of Pd ion was 500mv and the limiting current appeared at 150mV in electrolytic solution of Palladium. However, in Au-Pd electrolytic solution, the Potentials for reduction and the limiting current of Au decreased as the content of Pd in electrolyte increased, and the potentials for the limiting current of Au and Pd closed nearest together when percentage of Pd electrolytic solution was 37v71% in Au-Pd electrolyte.

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