In order to choose alternative environmental-friendly cleaning agents, it is very important in the present point that the systematic selection procedures should be introduced and applied to the industry through the evaluation of their cleaning ability, environmental characteristics, and economical factors, and that the objective and effective evaluation methods of cleanliness should be established for the industry. Thus, a novel cleaning evaluation method utilizing optically stimulated electron emission (OSEE) among various methods of cleaning ability was studied in this study. The contaminants used in this cleaning experiments were flux, solder, grease, cutting oil, and mixed soil of 35% grease and 65% cutting oil. The cleaning agents developed or prepared in our laboratory were employed and their cleaning ability were comparatively evaluated by the OSEE, gravimetry and contact angle methods. The experimental results in this work showed that flux cleaning efficiency measured by the OSEE method was similar to that of the gravimetric method, but that the OSEE method could not be compared with gravimetric method for the case of solder or grease cleaning because the contaminants radiate or absorb ultra-violet light. In case of cutting oil cleaning, the gravimetric method indicated its limitation of cleaning efficiency of cutting oil since it showed cleaning efficiency of 100%, even though residual soil remaining on the substrate surface a little after its cleaning. The comparative experimental results of cleaning ability evaluated by the OSEE- and contact angle measurement methods showed that they were similar in case of cleaning of flux, mixed soil and cutting oil. It was judged that the contact angle measurement method could evaluate the cleaning ability more precisely than the OSEE method for cleaning solder and grease.
The waste solution, which was discharged from the recovery process of LCD etching solution, consists of 15 wt% nitric acid and 20 wt% acetic acid. In this study, it was conducted to separate acid individually from the mixed acid by vacuum evaporation under -760 mmHg gauge and at $40^{\circ}C$. We have investigated evaporation behavior of acid as a function of temperature. There have been problems that tiny amount of nitric acid were evaporated simultaneously above $33^{\circ}C$. Thus, efforts were conducted to recover acetic acid by vacuum evaporation with adding $H_2O$, waste mixed acid and 20 g/L NaOH for a curb on evaporation of nitric acid. By adding $H_2O$, evaporation of nitric acid was reduced from 7% to 0.78%. However, it was reduced from 7% to 0.25% by adding mixed acid. In view of the results achieved so far, we may expect to separate the etching solution individually by controlling vacuum conditions.
Kim, Eun-Young;Kim, Min-Seuk;Lee, Jae-Chun;Jung, Jin-Ki
Resources Recycling
/
v.15
no.6
s.74
/
pp.33-40
/
2006
Leaching behavior of copper using electro-generated chlorine was investigated in hydrochloric acid solutions. When leached copper concentration was lower than 3.6g/L, the utilization efficiency of the electro-generated chlorine was close to 100% at $10mA/cm^2,\;25^{\circ}C$, 400 rpm in 1M HCl solutions. The concentration ot the leached copper over 3.6g/L caused the electrode potential to drop quietly, leading to a change or leaching mechanism. The leaching rate oi copper began to decrease at the concentration of copper 5.2g/L. This is probably due to the formation of a layer of CuCl on Cu metal in 1M HCl solutions. The leaching rate, however, was not retarded in a solution ot high chloride concentration. The high solubility of CuCl in the solution may prevent the formation of CuCl on Cu metal.
Jung, Kyungbae;Park, Hongki;Yoo, Kyoungkeun;Park, Jay Hyun;Choi, Ui Kyu
Resources Recycling
/
v.22
no.5
/
pp.13-19
/
2013
The effect of pH on the citrate leaching behavior of heavy metal ion was investigated to develop an eco-friendly process for removing heavy metals from soil contaminated with copper, zinc, and lead. The leaching tests were performed using citrate solution with pH adjusted by mixing citric acid and sodium citrate under the following leaching conditions: particle size, under $75{\mu}m$; temperature, $50^{\circ}C$; citrate concentration, $1kmol/m^3$; pulp density, 5%; shaking speed, 100 rpm; leaching time, 1 hour. The difference of pH before and after the leaching test was not observed, and this result indicates the direct effect of hydrogen ion concentration on the leaching of metals was insignificant. The removal ratios of copper, zinc, and lead from the contaminated soil decreased with increasing pH. The thermodynamic calculation suggests that the leaching behaviors of metal ions were determined by two reactions; one is the reaction to form complex ions between heavy metal ions and citrate ion species, and the other is the reaction to form metal hydroxide between heavy metal ions and hydroxide ion.
Journal of the Korea Institute of Building Construction
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v.16
no.2
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pp.97-105
/
2016
Recently, application case of the ultra rapid hardening concrete-polymer composite(URHCPC) are increasing to repair for the deterioration of pavement. But it is a major disadvantage that the main material is expensive and has environmental load. For these reasons, the development of the economic, eco-friendly materials is needed. Calcium Aluminate Composite (CAC), produced by rapid cooling of atomizing method with molten ladle furnace slag, is a material capable of improving the economic feasibility and reducing the environmental load of URHCPC. In this paper, the properties of CAC and gypsum mixed CAC (GC) as alternative materials of RSC according to the types of polymer dispersion were studied. The results were as follows; compressive strength, tensile strength, flexural strength, bonding strength and modulus of elasticity of the composites using CAC or GC showed higher values than those of plain proportion in 3 hour. In later age, they were at the same level as the general proportions. URHCPC using BPD as polymer dispersion had superior strength properties generally. But modulus of elasticity was the same level as the case of using a SBR latex. According to these results, CAC or GC can partially substituted for RSC to product the URHCPC. When URHCPC uses the BPD as the polymer dispersion, it can be improved performance.
Nowadays, there are increasing demands of golf courses and it is necessary to make more golf courses than the present. To do this, we need to improve the environmental problems with the regional inhabitants, and it is said that the first thing to be considered in developing any golf course in Korea is to preserve the environment. In this context, the purpose of this study is to set forth several design factors to lessen the negative impacts which are accompanied with the development of golf courses. 1. The present conditions of golf courses in Korea Many new golf courses have come into being, particularly since the late 1980s, and now, in the year of 1997, over one hundred of golf courses are doing their business, yet the number of golf course is still less than required. So far, over a half of them have been made in the vicinity of Seoul on account of various reasons, and this has adversely affected on our natural environment. This unreasonable development of golf courses has caused serious water pollution, landslides and the other problems. Also, the topography of Korea is not good for golf courses. Although the demands of golf courses are increasing, the suitable sites for them are very limited, and therefore it is sometimes unavoidable to make golf courses on steep hills. Consequently, in designing golf courses in Korea, the most important thing is the balance between natural environment and artificial environment. 2.Eco-friendly golf course design factors 1) The concept of eco-friendly golf courses Ecologically sustainable and sound golf courses which are made by eco-friendly approaches 2)Basic conditions of eco-friendly golf courses (1)The most suitable sites (2) Conservation of existing ground as much as possible (3)Proper use of agricultural chemicals which have great impacts on the environment (4) Reasonable use of fertilizers (5) Developing a specialized fertilizer only for grass (6) Adaptation of organic agriculture (7) Improvement of grass sorts (8) Establishing reservoirs for purifying the water from golf courses 3) Eco-friendly golf courses (1) Location-Enough area /Gentle slope/Winding ground/Including lakes or streams /Not crossing wind's main direction Facing south or southeast /Suitable soIl for grass /Good drainage /Low level of underground water (2)Course layout and design -Consideration about existing contours as much as possible -Adaptation of Scotish design trend -Various holes' configuration -Consideration toward surrounding landscapes -Reducing grass areas -Giving buffer zones -Adapting computer methods in the process of site analysis and design (3) Eco-friendly considerations in constructing and managing golf courses -Protection of wildlife -Reuse of existing forests and preservation of topsoil -Renovation of old-fashioned courses -Reducing grass areas -Purification of water -Standization of management -Strict regulations against chemicals -Recycling organic materials -Through separation of the water inside golf courses and out of bounds -Getting proper construction works done in a due time 4.Eco-friendly considerations from a viewpoint of cultural environment 1) Well-matched landscape design and events planning 2) Implement of identifications and awarding systerns 3)Acknowledgement of superintendents' qualitications in the maintenance of golf courses 4)Increasing public golf courses and keeping good relationships with the neighbors near golf courses Key words: Pro-environmental development, Golf course.
Transactions of the Korean Society of Mechanical Engineers B
/
v.40
no.7
/
pp.449-455
/
2016
Fog causes economic losses in transportation. It also results in health problems when it is combined with air pollutants. Considerable research efforts have focused on developing fog removal systems. However, most systems operate themselves after monitoring the fog. Additionally, continuous energy supply and maintenance are required to retain the fog-removal efficiency of the system. This study included the demonstration of a moss filter (a polyolefin mesh interlaced with moss) as a fog-removal method overcoming the limitations of the fog removal system. Three types of mosses with different surface structures were investigated to elucidate the relation between the moisture absorption rate and the structures. Among the different moss types, Hypopterygium japinicum showed the highest efficiency based on the smallest pore diameter and the largest total pore area. The visibilities with the moss filter and the polyolefin mesh were compared to perform the fog removal tests. The moss filter could provide a cost-effective and eco-friendly fog removal system with sustainability.
Journal of the Korean Crystal Growth and Crystal Technology
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v.26
no.5
/
pp.181-187
/
2016
In this study, new composition of orange color pigment was developed by replacing formerly used lead and chromium with environment-friendly elements. $TiO_2-SnO-ZnO$ composite was synthesized using the solid state reaction under the reducing atmosphere with the LPG and air mixture gas. The synthesized pigments were characterized by spectrophotometer, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and X-ray Photoelectron Spectroscopy (XPS). The colorimetric analysis of pigments exhibited color values ranging from yellow to orange-red. Five different crystalline phases were formed after the heat treatment for 4 and 6 hours. The color of pigments was strongly influenced by the crystalline structure of $SnO_2$, having either cubic or tetragonal structure. The oxidation state study of elements revealed that the color of pigment is getting close to rYR with the increase of $Sn^{4+}$ ratio.
Journal of Korean Society of Environmental Engineers
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v.31
no.3
/
pp.217-222
/
2009
This study was conducted to search possibilities of the use of sludge from waterworks industry in the manufacturing of red clay bricks. Different compositions of the sludge were added into the raw materials of the bricks and required engineering characteristics of the manufactured bricks were examined. Compressive strength, plasticity, and surface absorption of the recycled bricks were analyzed and were compared with the bricks quality standard rules and regulation for quality assurance of the product. Compressive strength of the bricks made in a ratio 75% clay, 5% sludge and 20% silica was found 261.3 $kg_f/cm^3$ and that was comparable with first grade bricks standard. Compressive strength of the bricks made in a ratio 70% clay, 10% sludge, and 20% silica was found 249.9 $kg_f/cm^3$ while it was decreased to 217.3 $kg_f/cm^3$ when bricks were made in a ratio 65% clay, 15% sludge and 20% silica. However, these values of compressive strength were in agreement with the bricks quality standard. Surface absorption of the bricks made by the mixing of 20% silica with varying amount of sludge, i.e., 5%, 10%, and 20% was found 10%, 9.65% and 10.92% respectively. These values satisfied the quality standard of bricks of grade 1 and 2. Recycling of proper amount of sludge in bricks making could produce bricks of high engineering characteristics.
This study presents measures to enhance the efficiency of Successive Alkalinity Producing Systems(SAPS), a natural biological purification method that prevents environmental pollution arising from the release of Acid Mine Drainage(AMD) from abandoned mines into rivers and groundwater. The treatment of AMD using SAPS is based on biological processing technology that mostly involves sulfate reducing bacteria(SRB). It has been proven effective in real-world applications, and has been employed in various projects on the purification of AMD. However, seasonal decrease in temperature leads to a deterioration in the efficiency of the process because sulfate-reducing activity is almost non-existent during cold winters and early spring even if SRB is able to survive. Against this backdrop, this study presents measures to enhance the activity of the SRB of the organic layer by integrating light emitting diode(LED)s in SAPS and to maintain the active temperature using LEDs in cold winters. Given that mine drainage facilities are located in areas where power cannot be easily supplied, solar cell modules are proposed as the main power source for LEDs. By conducting further research based on the present study, it will be possible to enhance the efficiency of AMD treatment under extreme cold weather using solar energy and LEDs, which will serve as an environmentally-friendly solution in line with the era of green growth.
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