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http://dx.doi.org/10.6111/JKCGCT.2016.26.5.181

Synthesis of the orange color pigment in the system of TiO2-SnO-ZnO by solid state reaction  

Kim, Soomin (Korea Institute of Ceramic Engineering and Technology)
Kim, Ungsoo (Korea Institute of Ceramic Engineering and Technology)
Cho, Woo Seok (Korea Institute of Ceramic Engineering and Technology)
Publication Information
Journal of the Korean Crystal Growth and Crystal Technology / v.26, no.5, 2016 , pp. 181-187 More about this Journal
Abstract
In this study, new composition of orange color pigment was developed by replacing formerly used lead and chromium with environment-friendly elements. $TiO_2-SnO-ZnO$ composite was synthesized using the solid state reaction under the reducing atmosphere with the LPG and air mixture gas. The synthesized pigments were characterized by spectrophotometer, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and X-ray Photoelectron Spectroscopy (XPS). The colorimetric analysis of pigments exhibited color values ranging from yellow to orange-red. Five different crystalline phases were formed after the heat treatment for 4 and 6 hours. The color of pigments was strongly influenced by the crystalline structure of $SnO_2$, having either cubic or tetragonal structure. The oxidation state study of elements revealed that the color of pigment is getting close to rYR with the increase of $Sn^{4+}$ ratio.
Keywords
Orange pigment; Solid state reaction; Raw material; Crystal structure; Oxidation state;
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Times Cited By KSCI : 2  (Citation Analysis)
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