• Title/Summary/Keyword: 치환거동

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Characteristics of Drying and Autogeneous Shrinkage in HPC with 65% Replacement of GGBFS (고로슬래그 미분말을 65% 치환한 고성능 콘크리트의 자기 및 건조수축 특성)

  • Jang, Seung-Yup;Ryu, Hwa-Sung;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.54-59
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    • 2017
  • GGBFS (Ground Granulated Blast Furnace Slag) is a byproduct with engineering advantages and HVSC (High Volume Slag Concrete) is widely attempted due to active utilization and reduction of eco-load. In the present work, characteristics of drying shrinkage and early-aged behavior are evaluated for the concrete with 65% replacement ratio of GGBFS and 50MPa of design strength. For the work, 3 different mix conditions are considered and several tests including slump flow, compressive strength, drying and autogeneous shrinkage are performed. From the test, OPC 100 mixture without replacement shows higher strength development before 7 days, however the strength reduction in concrete replaced with GGBFS is not significant due to sufficient free water for cement hydration. OPC 100 mixture also shows significant drying shrinkage due to a great autogeneous shrinkage before 3 days. In the concrete with GGBFS replacement, the drying shrinkage behavior is improved due to relatively small deformation by autogeneous shrinkage. The mixture (OPT BS 65) with lower w/b ratio (0.27) and unit content of water ($160kg/m^3$) shows more improved shrinkage behavior than BS 65 mixture which has simple replacement of GGBFS with 0.30 of w/b and $165kg/m^3$ of water unit content.

Behaviors of Soil-cement Piles in Soft Ground (연약지반에 설치된 소일시멘트말뚝의 거동)

  • Kim, Young-Uk;Kim, Byoung-Il;Xiaohong Bai
    • Journal of the Korean Geotechnical Society
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    • v.19 no.3
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    • pp.45-51
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    • 2003
  • This study was undertaken to investigate behavior characteristics of soil-cement piles in composite foundations through computer analysis. The soil-cement piles with cushion subjected to the vertical central loading only were analyzed using the program - “ABAQUS”. The investigation was conducted for various conditions including soil property, pile dimension, replacement ratio, pile/soil modular ratio, and load intensity. The results of analysis provided not only the load transfer and settlement behaviors but also the effective pile length and load distribution between a pile and soil. It was concluded that in the design of composite foundations, the modular ratio and replacement ratio are two design parameters.

Compressive Behavior of Reinforced Nylon Fiber Slag-CB (나일론 섬유 보강 Slag-CB의 압축거동 특성)

  • Younkyoung Lee;Taeyeon Kim;Jongkyu Lee;Youngsoo Joo;Bongjik Lee
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.11
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    • pp.5-10
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    • 2023
  • Slag-CB is widely used in various fields that require groundwater control. It is a type of CB where a portion of the cement mixed with CB is replaced with GGBS. In general, Slag-CB has the advantage of long-term improvement in compressive strength, permeability, durability, and chemical resistance as the GGBS replacement ratio increases. However, there are problems such as decreased flexibility and resistance to deformation of the cut-off walls, as well as brittleness upon failure. To address these problems, some quality standards recommend designing Slag-CB with lower strength, which makes it challenging to apply high-strength Slag-CB with a high GGBS replacement ratio in the field.In this study, we aimed to improve the flexibility and resistance to deformation of Slag-CB to prevent brittle failure and improve the field applicability of Slag-CB. To achieve this, we evaluated the compressive behavior of nylon fiber-reinforced Slag-CB and proposed measures for enhancing the flexibility and resistance to deformation of Slag-CB.

A Study on reforming product characteristics by gas phase secondary pyrolysis (기상2차 열분해에 의한 개질 생성물 특성에 관한 연구)

  • Son, Young-Il;Yoon, Sang-Jun;Choi, Young-Chan;Ra, Ho-Won;Lee, Jae-Goo
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.243-246
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    • 2008
  • 목질계 바이오매스 가스화 발전에 있어서는 가스화 가스중에 함유되어있는 타르를 가능한 한 가연성 가스로 전환하여 냉가스효율을 향상시키는 것 및 잔유하는 타르는 후단기기에 악영향을 초래할 우려가 있기 때문에 타르를 저감 제거하는 것이 바람직하다. 본 연구에서는 공기 수증기를 사용하여 타르개질 프로세스의 개선을 위해서 타르에서 가스성분으로의 전환에 관한 개질 실험을 실시하여 Wood chip 타르의 열분해 개질 생성물 거동에 대하여 검토하였다. Wood chip 열분해로 생성된 타르의 원소분석 및 $^1H$ NMR분석의 결과로 타르를 치환기를 가지지 않는 방향족, alkyl-기를 가지는 방향족, 산소 함유 방향족, 지방족의 4개로 분류하였다. 개질제에 의해 경질 타르, 중질 타르 모두 감소하였다. 개질 공기는 타르를 연소시키지만 그 속도는 가연성 가스와 경합하고 $900^{\circ}C$에서는 타르의 연소는 나타나지 않았다. alkyl-기를 가지는 방향족은 메탄과 치환기를 가지지 않는 방향족으로 전환되고, 치환기를 가지지 않는 방향족은 수소와 soot로 전환되고, 산소 함유 방향족은 일산화탄소와 치환기를 가지지 않는 방향족으로 전환되는 것을 알았다. 또한, 개질제에 의해alkyl-기를 가지는 방향족, 치환기를 가지지 않는 방향족, 산소 함유방향족 모두가 일산화탄소,이산화탄소로 전환되는 것을 알았다.

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Behavior of Soft Ground Improved with Fully-Partly Penetrated Sand Compaction Piles (관통-미관통 모래다짐말뚝으로 개량된 연약지반의 거동)

  • Jeong, Geunchae;Heo, Yol;Bae, Wooseok
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.9
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    • pp.91-99
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    • 2012
  • This study describes the investigation based on centrifuge model tests for the clay ground improved by sand compaction pile. In order to clarify the failure behavior of composite ground improved by partly and fully penetrated SCPs. And, in order to compare the effect of the penetration ratio and the replacement area ratio, nine of the centrifuge tests were carried out. From the test results, settlement reduce ratio in the fully penetrated SCPs ground is bigger than that in the partly penetrated SCPs ground. It is also evaluated that angle of the failure of composite ground improved by SCP are 26, 25, $34^{\circ}$ for As=10%, 22, $29^{\circ}$ for As=30%. And as a result of rigid loading tests, surface displacement decreases linearly with the partly penetration ratio increased.

Mossbauer Study for the Cation Distribution of Co-ferrite (CoxFe1-xO4) Thin Films (Co-ferrite 박막에서 양이온 거동에 관한 Mössbauer 분광 연구)

  • Park, Jae-Yun;Park, Young-Ran;Kim, Hee-Kyung;Kim, Kwang-Joo
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.1-5
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    • 2006
  • The crystallographic properties and cation distribution of oxyspinels ferrite $Co_xFe_{1-x}O_4$ thin films have been explored by X-ray diffraction, vibrating sample magnetometer (VSM), and conversion electron $M\"{o}ssbauer$ spectroscopy (CEMS). Thin films are prepared by sol-gel method. Normal spinel structure is transformed to inverse spinel structure with increasing Co concentration CEMS results indicate that most of $Fe^{3+}$ ions are substituted to $Co^{3+}$ions. Accordingly $Co^{2+}$ ions on octahedral site migrate to tetrahedral site. Magnetic moment is decreased with increasing Co concentration, which means high spin $Fe^{3+}$ ions are replaced by low spin $Co^{3+}$.

Flexural Behavior of Reinforced Recycled Aggregate Concrete Beams (순환골재를 사용한 철근콘크리트 보의 휨거동 특성)

  • Song, Seon-Hwa;Choi, Ki-Sun;You, Young-Chan;Kim, Keung-Hwan;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.21 no.4
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    • pp.431-439
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    • 2009
  • These days the amount of demolished concrete waste has been increasing due to reconstruction and redevelopment of aged buildings. So the use of recycled aggregates is recommended to solve environmental problems. Some investigations have been carried out to study the flexural behavior of reinforced concrete beams with recycled aggregates. But these have some limitation due to the use of low quality recycled aggregates and small-scale specimens in the laboratory. The purpose of this experimental study is to evaluate the flexural behavior of simply supported RC beams subjected to four-point monotonic loading and made with recycled aggregates. Seven full-scale RC beams were manufactured with different replacement level of recycled aggregates. The main parameters of the study are combination of aggregates. From the test results, the flexural behavior of the beam is described in terms of crack patterns and failure modes. And the flexural strength of RC beam with different types of recycled coarse aggregates and recycled fine aggregates is compared with the provision of KCI code.

Non-Fickian Diffusion of Organic Solvents in Fluoropolymeys (불소고분자내 유기용매의 비-픽 확산)

  • 이상화
    • Polymer(Korea)
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    • v.28 no.1
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    • pp.24-34
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    • 2004
  • Transient sorption experiments were conducted among several combinations of fluoropolymers and various organic solvents. Fully fluorinated polymer tended to exhibit ideal sorption behavior, while partially fluorinated polymers showed anomalous sorption behaviors with a drastic acceleration at the final stage of uptake. Minimization of least-squares of the measured and predicted fractional uptake, which indicated the increasing degree of deviation from Fickian diffusion, gave values of 3.0${\times}$10$\^$-4/, 1.75${\times}$10$\^$-3/, 8.68${\times}$10/sup-3/, 1.75${\times}$10$\^$-2/, respectively, for perfluoroalkoxy copolymer, poly(ethylene-co-tetrafluoroethylene), poly(vinylidene fluoride), poly(ethylene-co-chlorotrifluoroethylene). From stress-strain tests, it was confirmed that non-Fickian diffusion is closely related to the significant variation of mechanical properties (such as modulus and tensile strength) of swollen polymer. Anomalous sorption behavior stemmed from non-Fickian diffusion caused by nonlinear disruption of polar inter-segmental bonds due to solvent-induced plasticization. Thus, it is imperative to investigate the diffusion behavior of swelling solvents in partially fluorinated polymers, especially for the application to barrier materials or perm-selective membranes.

The Bond Behavior between Deformed bars and Recycled Fine Aggregate Concrete according to Bar Position. (철근 위치에 따른 이형철근과 순환잔골재 콘크리트의 부착거동)

  • You, Young-Chan;Jang, Yong-Heon;Lee, Min-Jung;Yun, Hyun-Do;Choi, Ki-Sun;Lee, Do-Heun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1089-1092
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    • 2008
  • The bond behavior between concrete and reinforcement is a important requirement for reinforced concrete constructions. For practical application, it is very important to study bond behavior of reinforcing bars in recycled fine aggregate concrete. Therefore, pull-out test in order to investigate the bond behavior between recycled fine aggregate concrete and deformed bars was performed. Recycled fine aggregate concrete replacement ratios (i.e., 0% and 100%) and positions of deformed bars (i.e., vertical and horizontal position) were considered as variables in this study. Test results were compared with the bond strength requirement recommended by CEB-FIP code. Based on the test results, It was found that the bond strength between the recycled fine aggregate concrete and deformed bars were influenced by both recycled fine aggregate concrete replacement ratios and positions of deformed bars. The reduction of bonded area at the soffit of horizontal reinforcement caused by concrete bleeding was observed in H type specimen. So, Only V type and HB specimen satisfied the bond strength requirement recommended by CEB-FIP code.

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