• Proceedings of the Korean Geotechical Society Conference
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• 2008.10a
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• pp.296-296
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• 2008

국내 절토비탈면은 이상 기후 및 건설공사의 증대로 인해 증가하고 있는 추세이며 장마철 및 태풍으로 인해 비탈면의 붕괴로 많은 인명 및 재산피해가 발생되고 있는 실정이다. 국내에서 사용되고 있는 기존의 비탈면의 설계기준은 암반의 불연속면에 대한 조사를 실시하고는 있지만 주로 암반의 굴착난이도를 토층, 리핑암, 발파암으로 구분하여 각각의 비탈면 절취경사를 결정하여 사용하는 방법을 사용하였으며 이러한 기준은 단순히 암석의 강도를 기준으로 설정되어 있으므로 암석의 공학적 특성 즉, 암반내 불연속면 방향성, 연속성, 충진물질, 마찰각, 풍화속도 등의 영향으로 공용후 비탈면 구배의 재조정 및 보강이 빈번하다. 국내외 절토비탈면의 설계기준은 각 기관별로 산재되어 있었으며 비탈면에 대한 설계 및 시공 등에 관한 기준은 도로와 철도 설계기준에 일부 반영되어 있을 뿐 항만, 댐, 택지조성 등 기타 시설 설계기준에는 비탈면에 대한 기준이 마련되어 있지 않아 표준적인 비탈면 설계기준 및 유지관리지침이 등이 필요하였다. 이러한 문제점을 보완하기 위해 2004년부터 2006까지 한국시설안전공단, 한국도로공사, 대한주택공사가 협동으로 연구한 건설공사 비탈면 설계 시공 및 유지관리에 관한 연구의 결과로 2006년도에 "건설공사 비탈면 설계기준"이 수립되었다. 이 설계기준은 건설공사에서의 기존 상이한 기준들을 정리하고 동일화하는 작업을 수행하였으며 지반의 조사에서부터 대책공까지를 막나하여 정리하였다. 그러나 최근에 급격한 기후변화로 인한 비탈면붕괴 빈번함에 따라 과거 적용되어 왔던 이들 기준을 적용하는 경우, 특히 상부 토층 및 풍화암 구간에서 많은 설계안전율을 만족하지 못해 많은 보강을 수반해야 하는 문제가 발생되고 있어 그 원인에 대한 분석을 수행하고자 하였다. 2006년도 정리된 기준은 과거에 적용하여 온 유기시의 안전율 조건을 Fs > 1.1~1.2을 적용하였던 것을 Fs > 1.2로 통일하였으며 지하수위 조건은 지표면에 위치하도록 하였다. 지하수위 조건은 풍화암 및 토층의 경우, 과거 지표면에 -3m를 적용한 시기가 있었으나 지표면에 지하수위를 적용하는 것이 일반적인 해석방법이다. 이러한 결과의 원인을 검토해 보면 다음과 같다. 첫째, 풍화암 및 토층에 적용되어 온 지반강도 정수가 과거 적용한 값보다 최근에는 작아지는 경향을 보이고 있다. 둘째, 지하수위 적용문제로 현재 지표면에 지하수위를 두어 안전율을 감소시키는 문제로 이는 최근 들어 많은 연구기관에서 강우시 간극수압의 증가에 대한 연구가 활발하게 진행되고 있다. 그러나 침투수 해석은 현행 기준에도 강우의 침투를 고려한 해석을 실시하는 경우 FS > 1.3 적용하는 것으로 되어 있으나 대부분의 해석에서는 적용이 되지 못하고 있는 실정이다. 셋째, 안전율이 과거에 주로 적용된 Fs > 1.1에서 Fs > 1.2로 상향 조정되어 우기시의 설계안전율 만족시키지 못하는 문제이다. 그러므로 이러한 문제점을 개선하기 위한 검토가 필요하며 장기적으로 이에 대한 합리적인 기준을 개정하는 작업이 추후에 수행되어야 할 것으로 판단된다.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.840-845
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• 2011

Degradation products of agarose are biologically active and thus used as an ingredient in pharmaceuticals or functional cosmetics. Furthermore, it has been strongly considered as a substrate for bio-ethanol fermentation. Recently, we isolated new agarase-producing microorganism, Pseudoalteromonas sp. from south sea of Korea. In this study, we aimed to separate and purify the agarase from culture broth of this strain. Separation of agarase was performed by ion- exchange chromatography on DEAE-Sepharose resin. Equilibrium pH and volume ratio of resin to the amount of protein were optimized for the efficient adsorption of protein. 410 ${\mu}g$ of protein was completely adsorbed to 3 mL of resin at pH 7.5. The total amount of eluted protein increased as NaCl concentration increased to 400 mM at isocratic elution. Agarase was separated by linear gradient elution of NaCl (0~1,000 mM). Three major protein peaks were observed and the presence or absence of agarase in these eluted proteins was measured by Lugol's staining technique. Only six eluted protein fractions showed strong agarase activity.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.310-316
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• 2012

The chromaticity of polyethylene glycol (PEG) generated from the recyling of a silicone slurry waste was improved by using activated carbon powder and a carbon filter. The color change of the PEG waste was investigated by changing the amount of adsorbent, adsorption time and temperature. The surface area of activated carbon did not have a significant impact on improving the color of the PEG waste. According to the results for the APHA color variation of the PEG waste changing the amount of the carbon adsorbent, the optimal usage to achieve the low APHA value was 100~150 mg-C/g-PEG. From the investigatnion on the effect of the adsorption temperature range from $25^{\circ}C$ to $100^{\circ}C$, it was found that the optimal temperatures were $40{\sim}50^{\circ}C$ in terms of achieving the lowest APHA value. The variation of the APHA color was investigated by changing the operation condition of the activated carbon filters. The use of ACF was a good way to enhance the chromaticity of the PEG waste. As a result, the APHA value of the PEG waste (APHA=53 at the initial waste) was reduced to be 10 through the ACF purification. It was also confirmed that the performance of the used carbon adsorbent can be recovered by the washing with purified water.

• Korean Chemical Engineering Research
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• v.51 no.5
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• pp.561-567
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• 2013

Mixed hardwood chips were pre-pulping extracted with green liquor prior to kraft pulping in order to recover hemicelluloses for use as biofuels. This green liquor solution containing mainly sodium sulfide and sodium carbonate was applied at different alkali charges (expressed as $Na_2O$) of 0, 1, 3, and 5% on dry wood weight. The extractions were performed at $160^{\circ}C$ for residence times ranging from about 1-2 h to determine the effect of extraction severity on composition of the pre-pulping extract. The severity of hemicellulose extraction time and green liquor charge controls the concentration of acetic acid and monosaccharide sugars available for downstream processing, the accumulation of degradation products such as organic acids and furans in the extract. As the alkali charge was increased, the amount of acetate side chains on the hemicelluloses and the dissolved lignin in the extract increased but the carbohydrate and sugars in the extract decreased appreciably. Hot water extraction (0% alkali addition) released the greatest amount of carbohydrates, up to 29.80 g/L measured as component sugars, but resulted in the greatest decrease in pulp yield. Meanwhile, pre-pulping extraction with 3% green liquor increased the pulp yield while greatly reducing the component sugars to 7.08 g/L. Fundamental data obtained in this study will allow selection of optimum hemicellulose extraction conditions for integrating the extraction operation into the Kraft pulping process.

• KSBB Journal
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• v.22 no.2
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• pp.102-108
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• 2007

A sewage was treated using a vertical flow zeolite-filled reed bed. The sewage from the student dormitory of Changwon National University was fed into the reed bed for 10 minutes every 6 hours at the hydraulic load of $314L/m^3{\cdot}$day. The filtering height of the reed bed was 100 em and the zeolite mixture was filled in the reed bed. The mixture consisted of the same volume of two types of zeolite: 0.5$\sim$1 mm and 1$\sim$3 mm in diameter. Annual average removal efficiency was 88 89.9%, $COD_{Cr}$ 86.1 %, $COD_{Mn}$ 81.2%, T-N 34.0%, $NH_4^+$-N 97.3% and T-P 34.6%. T-N of effluent was mostly $NO_3^-$-N and the concentration of $NO_2^-$-N in effluent was lower than 0.1 mg/L. All removal efficiencies did not show a remarkable seasonal change. The ranking of phosphorous fractions fixed to the zeolite in column test was Ca-P > Fe-P > reductant soluble Fe-P > occluded P > saloid P > AI-P at all depths of the filter. All phosphorous fractions except for AI-P reduced at deeper filter layer, while their content ratios increased at deeper filter layer. Organic matter content was the highest at the highest layer (0$\sim$5 cm from the top of the filter) and only small differences were observed at the deeper filter layer than 5 em from the top. Organic matter content increased at all depths of the filter with the operating time.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.931-937
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• 2008

Rigorous multiscale modelling and simulation of the MTR for WGSR was carried out to accurately predict the behavior of process variables and the reactor performance. The MTR consists of 4 fixed bed tube reactors packed with heterogeneous catalysts, as well as surrounding shell part for the cooling purpose. Considering that fluid flow field and reaction kinetics give a great influence on the reactor performance, employing multiscale methodology encompassing Computational Fluid Dynamics (CFD) and process modeling was natural and, in a sense, inevitable conclusion. Inlet and outlet temperature of the reactant fluid at the tube side was $345^{\circ}C$ and $390^{\circ}C$, respectively and the CO conversion at the exit of the tube side with these conditions approached to about 0.89. At the shell side, the inlet and outlet temperature of the cooling fluid, which flows counter-currently to tube flow, was $190^{\circ}C$ and $240^{\circ}C$. From this heat exchange, the energy saving was achieved for the flow at shell side and temperature of the tube side was properly controlled to obtain high CO conversion. The simulation results from this research were accurately comparable to the experimental data from various papers.

• Korean Chemical Engineering Research
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• v.45 no.4
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• pp.400-409
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• 2007

Morphology of methane/propane clathrate hydrate crystal was investigated under different undercooling conditions. After the water pressurized with compound guest gas was fully saturated by agitation, medium within the vessel was rapidly undercooled and maintained at the constant temperature while the visual observations using microscope revealed detailed features of subsequent crystal nucleation, migration, growth and interference occurring within liquid pool. The growth of hydrate was always initiated with film formations at the bounding surface between bulk gas and liquid regions under all tested experimental conditions. Then a number of small crystals ascended, some of which settled beneath the hydrate film. When undercooling was relatively small, some of the settled crystals slowly grew into faceted columns. As the undercooling increased, the downward growth of crystals underneath the hydrate film became dendritic and occurred with greater rate and with finer arm spacing. The shapes of the floating crystals within liquid pool were diverse and included octahedron and triangular or hexagonal platelet. When the undercooling was small, the octahedral crystals were found dominant. As the undercooling increased, the shape of the floating crystals also became dendritic. The detailed growth characteristics of floating crystals are reported focused on the influences caused by undercooling and memory effect.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.357-363
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• 2015

The development of the environment-friendly tire that meets the standard requirements according to tire labeling system can be improved through using highly homogeneous silica immobilized zinc oxide nanoparticles. In this study, a considerable amount of nanoporous silica was essentially added into nano zinc oxide to improve the physiochemical properties of the formed composite. The introduction of nanoporous silica materials in the composite facilitates the improvement of the wear-resistance and increases the elasticity of the tread. Therefore, the introduction of nanoporous silica can replace carbon black as filler in the formation of composites with desirable properties for conventional green tire. Herein, mesoporous silica immobilized zinc oxide nanoparticle with desirable properties for rubber compounds was investigated. Composites with homogeneous dispersion were obtained in the absence of dispersants. The dispersion stability was controlled through varying the molar ratio, ageing time and mixing order of the reactants. A superior dispersion was achieved in the sample obtained using 0.03 mol of zinc precursor as it had the smallest grain size (50.5 nm) and then immobilized in silica aged for 10 days. Moreover, the specific surface area of this sample was the highest ($649m^2/g$).

• Journal of the Computational Structural Engineering Institute of Korea
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• v.30 no.6
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• pp.485-493
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• 2017

In this study, the collision analysis of SCP(Sandwich Concrete Panel) composing the outer tank of LNG storage was performed and its collision behavior was analyzed. For the same collision energy value proposed in BS7777 code, the collision conditions are composed by using two types of missiles and various collision speeds. Nonlinear dynamic analysis models were constructed to perform numerical analysis on the various collision conditions. Also, the collision behavior was analyzed assuming that the second collision with the same collision energy occurs at the same point after the first collision. As a result of the analysis, it was found that with smaller missile and low collision speed had caused larger deformation. The collision energy dissipated in ratio of about 6: 4 in the outer steel plate and the inner filling concrete. In the results of double collision analysis, the final collisional deformation was dominated by the size of the second missile, and the amount of deformation due to the second collision was smaller than that of the first collision because of the membrane behavior of the steel plates. In the offset double collision cases, the largest deformation occurs at the secondary collision point regardless of the offset distance.

• Geophysics and Geophysical Exploration
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• v.13 no.4
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• pp.349-356
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• 2010

Analysis of high-resolution seismic profiles acquired from the southeastern continental shelf of Korea reveals that the late Quaternary transgressive deposits consist of six seismic units created in response to sea-level rise. These units with different seismic facies and geometry can be grouped into two distinct depositional wedges (paralic and marine) bounded by a ravinement surface. The paralic component underlying the ravinement surface consists of the sediment preserved from shoreface erosion and contains incised-channel fill, ancient beach-shoreface deposit and estuarine deposit. The top of paralic unit is truncated by a ravinement surface and overlain by marine component. The marine component consists of the sediment produced through shoreface erosion during landward transgression and contains mid-shelf sand sheet, mid-shelf sand ridge and inner shelf sand sheet. Such transgressive stratigraphic architecture of six sedimentary units is controlled by a function of lateral changes in the balance among rates of relative sea-level rise, sediment input and marine processes at any given time.