• Economic and Environmental Geology
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• v.30 no.6
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• pp.505-517
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• 1997

Lead and zinc mineralization of the Kwangsin mine was formed in quartz and carbonate veins that filled fault-related fractures in the limestone-rich Samtaesan Formation of the Chosun Supergroup and the phyllite-rich Suchangni Formation of unknown age. A K-Ar date of alteration sericite indicates that the Pb-Zn mineralization took place during Late Cretaceous (83.5 Ma), genetically in relation to the cooling of the nearby Muamsa Granite (83~87 Ma). Mineral paragenesis can be divided into three stages (I, II, III): (I) the deposition of barren massive white quartz, (II) the main Pb-Zn mineralization with deposition of white crystalline quartz and/or carbonates (rhodochrosite and dolomite), and (III) the deposition of post-ore barren calcite. Mineralogic and fluid inclusion data indicate that lead-zinc minerals in middle stage II (IIb) were deposited at temperatures between $182^{\circ}$ and $276^{\circ}C$ from fluids with salinities of 2.7 to 5.4 wt. % equiv. NaCl and with log $fs_2$ values of -15.5 to -11.8 atm. The relationship between homogenization temperature and salinity data indicates that lead-zinc deposition was a result of fluid boiling and later meteoric water mixing. Ore mineralization occurred at depths of about 600 to 700 m. Sulfur isotope compositions of sulfide minerals (${\delta}^{34}S_{CDT}=9.0{\sim}14.5$ ‰) indicate a relatively high ${\delta}^{34}S_{{\Sigma}S}$ value of ore fluids (up to 14 ‰), likely indicating an igneous source of sulfur largely mixed with an isotopically heavier sulfur source (possibly sulfates in surrounding sedimentary rocks). There is a remarkable decrease of calculated ${\delta}^{18}O$ value of water in hydrothermal fluids with increasing paragenetic time: stage I, 14.6~10.1 ‰; stage IIa, 5.8~2.2 ‰; stage IIb, 0.8~2.0 ‰; stage IIc, -6.1~-6.8 ‰, This indicates a progressive increase of meteoric water influx in the hydrothermal system at Kwangsin. Measured and calculated hydrogen and oxygen isotope values indicate that the Kwangsin hydrothermal fluids was formed from a circulating (due to intrusion of the Muamsa Granite) meteoric waters which evolved through interaction mainly with the Samtaesan Formation (${\delta}^{18}O=20.1$ to 24.9 ‰) under low water/rock ratios.

• Journal of the Korean GEO-environmental Society
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• v.9 no.6
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• pp.21-29
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• 2008

As household and industrial wastes continue to rapidly increase every year, the demands for landfill sites are also increasing. However, the construction of landfill sites causes many problems due to the high costs of liners, while the leachate from the landfills generates secondary contamination of surrounding lands and groundwater. The purpose of this study is to determine the proper mixing ratio to meet the liner conditions (must be less than $1{\times}10^{-7}cm/sec$), using the local soil as the main material and using fly ash, bentonite, and cement as the mixing materials. The possibility of using this mixture as the liner for landfill sites was examined. To determine the proper mixing ratio, this study conducted basic physical properties tests, compaction tests, consolidation tests, and uniaxial compression tests. It was found that the higher the ratio of bentonite, the lower the coefficient of permeability, and the higher the ratio of fly ash, the higher the coefficient of permeability. The reason for this is that, while bentonite expands and fills pores, fly ash cannot fill the pores because the particles have a round shape and do not have adhesion. In conclusion, the optimum coefficient of permeability that meets the landfill liner condition was obtained when the ratio of bentonite was 15% or higher. If fly ash was mixed, the landfill liner condition was met when the ratio of bentonite was 15% or higher and the ratio of fly ash was 20% or lower.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.10
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• pp.1825-1832
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• 2000

Column experiments were conducted by using soil columns, to investigate feasibility and efficiency of in-situ ozone enhanced remediation for diesel-contaminated soil. The injection of gaseous ozone into soil column revealed the enhanced decomposition of ozone due to the catalytic reaction between ozone and metal (e.g., Fe, Mn etc.) oxides as evidenced by as much as 25 times shorter half-life of ozone in a sand packed column than in a glass beads packed column. Substantial retardation in the transport of and the consumption of ozone were observed in the diesel contaminated field soil and sand packed columns. After 16 hrs ozonation, 80% of the initial mass of diesel (as diesel range organic) concentration of $800{\pm}50mg/kg$, was removed under the conditions of the flow rate of 50mL/min and $6mg-O_3/min$. Whereas, less than 30% of diesel was removed in the case of air injection. Analysis of the residual TPH(total petroleum hydrocarbon) and selected 8 aliphatics of diesel compounds in the inlet and the outlet of the column confirmed that diesel nonselectively reacted with ozone and then shifted to lower carbon numbered molecules. Water content also was found to be an important parameter in employing ozone to the hydrocarbon-contaminated soil.

• The Korean Journal of Petroleum Geology
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• v.1 no.1 s.1
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• pp.15-27
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• 1993

Seismic reflection profiles from the eastern continental margin of Korea delineate three major Neogene sedimentary basins perched on the shelf and slope regions: Pohang-Youngduk, Mukho and Hupo basins. The stratigraphic and structural analyses demonstrate that the formation and filling of these basins were intimately controlled by two phases of regional tectonism: transtensional and subsequent contractional deformations. In the Oligocene to Early Miocene, back-arc opening of the East Sea induced extensional shear deformation with dextral strike-slip movement along right-stepping Hupo and Yangsan faults. During the transtensional deformation, the Pohang-Youngduk Basin was formed by pull-apart opening between two strike-slip faults; in the northern part, block faulting caused to form the Mukho Basin between basement highs. As a result of the back-arc closure, the stress field was inverted into compression at the end of the Middle Miocene. Under the compressive regime, two episodes (Late Miocene and Early Pliocene) of regional deformation led to the destruction and partial uplift of the basin-filling sequences. In particular, during the second episode of compressive deformation, the Hupo fault was reactivated with an oblique-slip sense, which resulted in an opening of the Hupo Basin as a half-graben on the downthrown fault block.

• 한국지구과학회:학술대회논문집
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• 2010.04a
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• pp.98-98
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• 2010

그라우팅은 지반의 공학적인 강도증가를 통한 지지력 향상 및 암반의 투수성 저감을 통해 지하수 유동을 억제하기 위하여 대규모 토목공사 현장의 균열암반 및 댐 또는 제방 등의 지역에서 많이 시행되고 있다. 본 연구는 균열암반지역에서 그라우팅 효과 확인을 위하여 보통 포틀랜드 시멘트(OPC)와 마이크로 시멘트(MC)를 사용하여 그라우팅을 수행하였으며, 그라우팅 전후에 물리검층(시추공영상촬영, 초음파 텔레뷰어검층)을 이용하여 그라우팅 효과 정도를 파악하였다. 연구지역은 경상북도 영주시 평은면 지역으로, 지질은 선캠브리아기 안구상편마암에 시대미상의 흑운모 화강암이 관입을 하였고, 이를 제4기의 충적층이 부정합으로 피복되어 있다. 그라우팅은 일반구간과 단층대구간으로 구분하여 실시하였으며, 두 구간의 이격거리는 서로의 간섭을 피하기 위해 약 40m 간격으로 선정하였다. 주입재(OPC, MC)는 5개의 주입공에서 triangle 방향으로 주입하였으며, 주입정도를 확인하기 위하여 각 구간에 2공씩 확인시추를 하였다. 두 개의 site중 일반구간의 보통 포틀랜드시멘트 주입결과 평균주입량은 48.2kg/공이며 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 1.62kg/m이며, 마이크로시멘트의 평균주입량은 49.6kg/공이며 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 3.86kg/m로 나타났다. 단층대 구간에서는 보통 포틀랜드시멘트의 평균주입량이 40.0kg/공이며, 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 2.75kg/m이며, 마이크로 시멘트는 평균주입량이 56.5kg/공, 주입 1m당으로 환산하면 Lugeon값 10미만의 지층에서는 3.15kg/m로 나타났다. 마이크로시멘트의 주입압은 보통 포틀랜드시멘트에 비해 상대적으로 낮았으며, 그라우팅 개선효과 역시 상대적으로 양호한 것으로 나타났다. 그라우팅 효과확인을 위한 물리검층의 초음파텔레뷰어 해석결과 상대암반강도는 주입전 $250{\sim}750\;kgf/cm^2$, 주입후는 $400{\sim}800\;kgf/cm^2$으로 그라우팅에 의한 암반강도의 상승을 확인할 수 있었고, 시추공영상촬영 분석에서는 시추코어만으로 얻기 힘든 시멘트 충진구간을 직접 확인할 수 있었다. 초음파텔레뷰어의 경우 파쇄대의 분포 및 암반강도 측정을 통한 그라우팅 파악은 가능하였으나 파쇄대 충진물을 확인할 수가 없는 단점이 있었고 이를 시추공영상촬영을 통해 보완할 수 있었다. 다만 물리검층의 경우 그라우팅에 의한 공의 손실로 동일공에 의한 반복 조사가 아닌 경우가 대부분이어서 그라우팅 효과에 대한 정확한 비교가 어려웠으며 추후 이를 보완하기 위한 계속적인 연구가 필요할 것으로 사료된다.

• Journal of the Microelectronics and Packaging Society
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• v.16 no.3
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• pp.19-24
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• 2009

Formation of an adhesion/barrier layer and a seed layer by sputtering techniques followed by electroplating has been one of the most widely used methods for the filling of through-Si via (TSV) with high aspect ratio for 3-D packaging. In this research, the adhesion and diffusion-barrier properties of the $TaN_x$ film deposited by reactive sputtering were investigated. The adhesion strength between Cu film and $SiO_2$/Si substrate was quantitatively measured by $180^{\circ}$ peel test and topple test as a function of the composition of the adhesive $TaN_x$ film. As the nitrogen content increased in the adhesive $TaN_x$ film, the adhesion strength between Cu and $SiO_2$/Si substrate increased, which was attributed to the increased formation of interfacial compound layer with the nitrogen flow rate. We also examined the diffusion-barrier properties of the $TaN_x$ films against Cu diffusion and found that it was improved with increasing nitrogen content in the $TaN_x$ film up to N/Ta ratio of 1.4.

• Clean Technology
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• v.28 no.4
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• pp.285-292
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• 2022

Adsorption tower systems based on activated carbon adsorption towers have mainly been employed to reduce the emission of volatile organic compounds (VOCs), a major cause of air pollution. However, the activated carbon currently used in these systems has a short lifespan and thus requires frequent replacement. An approach to overcome this shortcoming could be to develop metal oxide photocatalysis-activated carbon composites capable of degrading VOCs by simultaneously utilizing photocatalytic activation and powerful adsorption by activated carbon. TiO₂ has primarily been used as a metal oxide photocatalyst, but it has low economic efficiency due to its high cost. In this study, ZnO particles were synthesized as a photocatalyst due to their relatively low cost. Silver nanoparticles (Ag NPs) were deposited on the ZnO surface to compensate for the photocatalytic deactivation that arises from the wide band gap of ZnO. A microfluidic process was used to synthesize ZnO particles and Ag NPs in separate reactors and the solutions were continuously supplied with a pack bed reactor loaded with activated carbon powder. This microfluidic-assisted pack bed reactor efficiently prepared a Ag-ZnO-activated carbon composite for VOC removal. Analysis confirmed that Ag-ZnO photocatalytic particles were successfully deposited on the surface of the activated carbon. Conducting a toluene gasbag test and adsorption breakpoint test demonstrated that the composite had a more efficient removal performance than pure activated carbon. The process proposed in this study efficiently produces photocatalysis-activated carbon composites and may offer the potential for scalable production of VOC removal composites.

• Geophysics and Geophysical Exploration
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• v.4 no.4
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• pp.133-144
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• 2001

An effective seismic reflection technique for mapping the cavities and bedrock surface in carbonate rocks is described. The high resolution seismic reflection images were successfully registered by using the hydrophones employed in the stream-water driven trench, and were effectively focused by applying optimal data processing sequences. The strategy included enhancement of the signal interfered with the large-amplitude scattering noise, through pre- and post stack processing such as time-variant filtering, bad-trace editing, residual statics, velocity analysis, and careful muting after NMO (normal moveout) correction. The major reflections including the bedrock surface were mapped with the desired resolution and were correlated to the seismic crosshole tomographic data. Shallow major reflectors could be identified and analyzed on the AGC (auto gain control)-applied field records. Three subhorizontal layers were identified with their distinct velocities; overburden (<3000 m/s), sediments (3000-4000 m/s), limestone bedrock (>4000 m/s). Taking into account of no diffraction effects in the field records, gravel-rich overburdens and sediments are considered to be well sorted. Based on the images mapped consistently on the whole survey line and seismic velocity increasing with depth, this area probably lacks in sizable cavities (if any, no air-filled cavities).

• Geophysics and Geophysical Exploration
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• v.13 no.4
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• pp.349-356
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• 2010

Analysis of high-resolution seismic profiles acquired from the southeastern continental shelf of Korea reveals that the late Quaternary transgressive deposits consist of six seismic units created in response to sea-level rise. These units with different seismic facies and geometry can be grouped into two distinct depositional wedges (paralic and marine) bounded by a ravinement surface. The paralic component underlying the ravinement surface consists of the sediment preserved from shoreface erosion and contains incised-channel fill, ancient beach-shoreface deposit and estuarine deposit. The top of paralic unit is truncated by a ravinement surface and overlain by marine component. The marine component consists of the sediment produced through shoreface erosion during landward transgression and contains mid-shelf sand sheet, mid-shelf sand ridge and inner shelf sand sheet. Such transgressive stratigraphic architecture of six sedimentary units is controlled by a function of lateral changes in the balance among rates of relative sea-level rise, sediment input and marine processes at any given time.

• 한국지구물리탐사학회:학술대회논문집
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• 2002.09a
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• pp.46-66
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• 2002

High-resolution multichannel seismic data were collected in the coastal area near the Gori nuclear power plant to investigate Quaternary fault pattern and timing. A 12 channel streamer, a sparker, and a portable recorder were used for data acquisition. Because the group interval of the streamer was 6.25 m and the sparker can generate acoustic waves with the frequency content of up to 500 Hz, the data show a significant improvement both in horizontal and vertical resolution. The area surveyed is covered with 30-40 m thick Holocene sediments that constitute the mud belt along the southeastern coast of Korea. The survey area is characterized by the well discriminated Pleistocene and Holocene boundary and shallow gas-charged zones. A number of Quaternary faults were found in the sediment column, that are nearly vertical and extend north-south. The Quaternary faults, arranged at a spacing of a few hundred meters, suggest that they were formed in response to compression, although some of them reveal extensional characteristics. Locally, faults disrupt Incised-channel fills that are interpreted to have formed in the early stage of transgression after the beginning of the Holocene. Seismic sections suggest that shallow gas in the mud belt sediments made its way upward through the fractured fault planes. The tectonism responsible for the opening of the East Sea has not persisted since the late Miocene, but vigorous Quaternary faulting activity in the vicinity of the southeastern Korean Peninsula indicates that tectonic stability has yet to be achieved in this region underlain by the hotter than normal mantle.