• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.6
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• pp.499-505
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• 2004

The objective of this study is to investigate the effect of supercooling repression on the TMA clathrate by adding ethylene glycol. For this purpose, phase change temperature, supercooling, specific heat, latent heat and rate of volume change were measured and evaluated experimentally for heat source temperatures of -6$^{\circ}C$, -7$^{\circ}C$, -8$^{\circ}C$. The results show that supercooling was decreased. Thus the experimental results are expected to be used for the increase of coefficient of performance of low temperature thermal storage system in the building.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1663-1666
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• 2003

TMA clathrate that is used by PCM of ice storage system in this research creates hydrate crystallization at higher temperature than pure water, and application is expected as PCM because having comparative big dormant temperature without phase separation phenomenon. In case this research uses TMA clathrate by PCM, choose admixture by purpose to control or remove subcooling of TMA clathrate and evaluated experimentally. Subcooling is improved and can expect contraction of freezing machine running time and increase of coefficient of performance as that add admixture to TMA clathrate conclusively. Also, may supply thermal storage system that apply low temperature potential heat thermal storage material that subcooling is improved more extensively laying stress on medium size building and small size building, can expect allowance through localization of ice storage system.

• Economic and Environmental Geology
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• v.38 no.6 s.175
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• pp.717-729
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• 2005

Peak cooling load of large buildings is generally greater than their peak heating load. Internal and solar heat gains are used fur selection of adquate equipment in large building in cold winter climate like Canada and even Korea. The cost of geothermal heat exchanger to meet the cooling loads can increase the initial cost of ground source heat pump system to the extend less costly conventional system often chosen. Thermal ice storage system has been used for many years in Korea to reduce chiller capacity and shift Peak electrical time and demand. A distribution system designed to take advantage of heat extracted from the ice, and use of geothermal loop (geothermal heat exchanger) to heat as an alternate heat source and sink is well known to provide many benifits. The use of thermal energy storage (TES) reduces the heat pump capacity and peak cooling load needed in large building by as much as 40 to $60\%$ with less mechanical equipment and less space for mechanical room. Additionally TES can reduce the size and cost of the geothermal loop by 1/3 to 1/4 compared to ground coupled heat pump system that is designed to meet the peak heating and cooling load and also can eliminate difficuties of geothermal loop installation such as space requirements and thermal conditions of soil and rock at the urban area.

• Solar Energy
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• v.13 no.2_3
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• pp.65-78
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• 1993

An overdose of fossil fuel for greenhouse heating causes not only the high cost and low quality of agricultural products, but also the environmental pollution of farm village. To solve these problems it is desirable to maximize the solar energy utilization for the heating of greenhouse in winter season. In this study phase change materials were selected to store solar energy concentratively for heating the greenhouse and their characteristics of thermal energy storage were analyzed. The results were summarized as follows. The organic $C_{28}H_{58}$, and the inorganic $CH_3COONa{\cdot}3H_2O\;and\;Na_2SO_4{\cdot}10H_2O$ were selected as low temperature latent heat storage materials. The equation of critical radius was derived to define the generating mechanism of the maximum latent heat of phase change materials. The melting point of $C_{28}H_{58}$ was $62^{\circ}C$, and the latent heat was $50.0{\sim}52.0kcal/kg$. The specific heat of liquid and solid phase was $0.54{\sim}0.69kcal/kg^{\circ}C$ and $0.57{\sim}0.75kcal/kg^{\circ}C$ respectively. The melting point of $CH_3COONa{\cdot}3H_2O$ was $61{\sim}62^{\circ}C$, the latent heat was $64.9{\sim}65.8$ kcal/kg and the specific heat of liquid and solid phase was respectively $0.83kcal/kg^{\circ}C$ and $0.51{\sim}0.52kcal/kg^{\circ}C$. The melting point of $Na_2SO_4{\cdot}10H_2O$ was $30{\sim}30.9^{\circ}C$, the latent heat was 53.0 kcal/kg and the specific heat of liquid and solid phase was respectively $0.78{\sim}0.89kcal/kg^{\circ}C$ and $0.50{\sim}0.7kcal/kg^{\circ}C$ When the urea of 21.85% was added to control the melting point of $Na_2SO_4{\cdot}10H_2O$ and the phase change cycles were repeated from 0 to 600, the melting point was $16.7{\sim}16.0^{\circ}C$ and the latent heat was $36.0{\sim}28.0kcal/kg^{\circ}C$.

• Solar Energy
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• v.9 no.1
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• pp.53-61
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• 1989

In the present investigation, experiments on the melting of a phase change material were performed to research heat transfer phenomena generated by means of conduction and natural convection in the vertical tube at inward melting. The phase change material used in the experiments is 99 percent pure n-Docosane paraffin which is measured melting temperature of $42.5^{\circ}C$, latent heat of 37.5 cal/g, heat conductivity of $0.1505W/m^{\circ}C$. Experiments were performed both in the no-subcooling which is initiating it at melting temperature of phase change material, and in the subcooling which means to initiate it under melting temperature of phase change material, in order to compare and investigate the horizontal temperature history, vertical temperature history, ratio of melting and melted mass, figure of the melting front in the vertical tube. In the experimental results, heat transfer from tube wall to phase change material were due to conduction at early stage and due to natural convection with the passage of time, and then occurred melting downward from surface by volumetric expansion. Natural convection affects temperature distribution in the tube, ratio of melting and melted mass, figure of the melting front and then progress rapidly in case of nosubcooling compared to subcooling.

• Journal of the KSME
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• v.18 no.3
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• pp.18-24
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• 1978

열고환기에는 boiler와 같이 다량의 열 energy를 취급하는 것을 비롯하여 가정용 냉장고, 냉방기 기와 같이 비교적 적은 양의 열 energy를 취급하는것, 가종 고온 gas-gas 열교환기, 초전도송전 등의 초저온기기에 부속되는 저온열교환기 혹은 배열회수, 태양열이용을 위한 장치에 포함되는 열교환기등이 있으며, 그 종류와 내용에 있어서 다양하다. 따라서 새 형식의 열교환기 혹은 우수 한 전열특성을 갖는 표면, 형상을 갖는 전열관의 연구, 개발은 한층더 절실하게 요망된다. 최근주 목을 받고 있는 열교환기용전열관중에는 관축방향을 따라 표면을 파상으로 가공한 것(corrugate 식)과 축과 평형이 되게 만든 좁은 흠을 갖는 관(fluted tube)등이 있는데 이들에 있어서는 다같 이 표면의 요철에 의한 면부근의 난동을 촉진시켜서 우수한 대류열전달의 특성을 갖도록 하고 있다. 한편 응축과 비등등의 상변화를 동반하는 열전달에 대해서는 세구, 기공질금속층, 세공등을 갖는 면에 관해서 새로운 관심이 집중되고 있다. 이 후자의 전열면은 유축열전달에서는 평활면보 다 약10배의 높은 열전달율을 가지며 불등열전달에서는 벽면과 액의 온도차는 평활면의 경우보다 약1/5의 값을 갖는다. 동시에 한계열유속은 5활이상으로 증가시킬 수 있음이 알려져 있다. 따라서 본론에서는 후자의 전열면중에서 최근에 알려진 비약적으로 높은 전열성능을 갖는 전열면에 관해 서 소개하기로 한다.

• Transactions of the Korean Society of Automotive Engineers
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• v.23 no.4
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• pp.428-435
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• 2015

This paper presents the experimental study of cabin thermal comfort using a cold storage heat exchanger in a vehicle air-conditioning system. Recent vehicle-applied ISG functions for fuel economy and emission, but when vehicles stop, compressors in the air-conditioning system stop, and the cabin temperature sharply increases, making passengers feel thermal discomfort. This study conducts thermal comfort evaluation in the vehicle, which is applied to a cold storage system for the climate control wind tunnel test and the vehicle fleet road test with various airflow volume rates and ambient temperatures blowing to the cold storage heat exchanger. The experimental results, in the cold storage system, air discharge temperature is $3.1-4.2^{\circ}C$ lower than current air-conditioning system when the compressor stops and provides cold air for at least 38 extra seconds. In addition, the blowing airflow volume to the cold storage heat exchanger with various ambient temperature was examined for the control logic of the cold storage system, and in the results, the airflow volume rate is dominant over the outside temperature. For this study, a cold storage system is economically useful to keep the cabin at a thermally comfortable level during the short period when the engine stops in ISG vehicles.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.4
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• pp.556-565
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• 1995

The physical model of interest is based upon the concentric cylinder, where the outside cylinder is filled with optically thick and high temperature phase change material(PCM). The fluid is flowing through the inside cylinder to transfer the appropriate energy. The fluid is flowing through the inside cylinder to transfer the appropriate energy. The governing equations for the phase change material including internal thermal radiation and for the turbulent transfer fluid have been employed and numerically solved. The optically thick phase change justifies the P-l spherical harmonics approximation, which is believed to be appropriate choice particularly for the much coupled problem like in this study. The solid/liquid interface, temperature distribution within the PCM and the heat flux from the PCM to the transfer fluid have been obtained and compared with those of laminar transfer fluid. The numerical results show that the turbulent transfer fluid accelerates the solid/liquid interface and results in the increase of heat transfer rate from the PCM. The internal thermal radiation within the PCM, however, does not always playa role to increase the heat transfer rate throughout the inside cylinder. It is believed that the combined heat flux has been picked up more in the inflowing area than in the pure conductive phase change material.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.2
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• pp.205-214
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• 1999

The objective of this paper is to investigate the thermal properties of TMA clathrate compound applicable to cold storage system for building air-conditioning. Especially, the test tube experiments are performed by comparing and analyzing the temperature of phase change, specific heat and subcooling characteristic according to the variation of density, temperature of heat source and charging quantity in TMA clathrate compound. The results are summarized as follows:1) $-15^{\circ}C$ is not proper as the temperature of heat source because the temperature of subcooling is above $8.3^{\circ}C$ 2) temperature of phase change is dropped as the temperature of heat source is lower, 3) the effect of subcooling suppression with about 8$^{\circ}C$ is confirmed when the temperature of heat source is $-10^{\circ}C$ in case of 26, 27, and 30wt%, while the temperature of subcooling is about $0^{\circ}C$ when the temperature of heat source is $-15^{\circ}C$ in case of 25, 26 and 30wt%. Thus, the effect of subcooling suppression is greater as the temperature of heat source is lower. Additionally, the concentrative study is needed on mass concentration causing the phase change without subcooling phenomenon when the temperature of heat source is $-15^{\circ}C$. Thus, it is concluded that TMA clathrate compound has enough thermal properties as the cold storage medium for building air-conditioning.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.8
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• pp.725-734
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• 2000

The objective of this paper is to investigate the thermal properties of TMA clathrate applicable to cold storage system for building air-conditioning. Especially, the test tube experiments are peformed by comparing and analyzing the temperature of phase change, specific heat and subcooling characteristic according to the variation of concentrations and temperature of heat source in TMA clathrate. The results are summarized as follows; 1) temperature of phase change is dropped as the temperature of heat source is lower, 2) the effect of subcooling suppression with about $9.3^{\circ}C$ is confirmed when the temperature of heat source is $-10^{\circ}C$ in case of 30wt%, while the temperature of subcooling is about $0^{\circ}C$ when the temperature of heat source is $-15^{\circ}C$ in case of 25, 29wt% and 30wt% . Thus, the effect of subcooling suppression is greater as the temperature of heat source is lower. Additionally, the concentrative study is needed on mass concentration causing the phase change without subcooling phenomenon when the temperature of heat source is $-15^{\circ}C$ Thus, it is concluded that TMA clathrate has proper properties as the cold storage medium for building air-conditioning.