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The Prediction of Vapor-Liquid Equilibrium Data for Ethanol/3-methyl-1-butanol System at Constant Temperature (정온하에서 Ethanol/3-methyl-1-butanol계의 기-액평형치 추산)

  • Lee, Joon-Man;Park, Young-Hae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.2055-2061
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    • 2013
  • Recently, an understanding of new sources of liquid hydrocarbons such as bio-ethanol is economically very important. Successful design of distillation columns in a separation process depend on the availability of accurate vapor-liquid equilibrium data. For the binary system of Ethanol/3-methyl-l-butanol mixture, isothermal Vapor-liquid equilibrium data were measured at temperature of 50, 55, 60, 65, 70, 75 and $80^{\circ}C$. An empirical relation to predict Vapor-liquid equilibrium data was obtained from the above measured data. The predicted values are compared with the measured ones to be in a good agreement within accuracy of ${\pm}0.0005$, ${\pm}0.0022$.

The Prediction of Vapor-Liquid Equilibrium Data for Methanol/3-methyl-1-butanol System at Constant Temperature (정온하에서 Methanol/3-methy-1-butanol계에 대한 기-액 평형치의 추산)

  • Kim, Jong-Shik;Lee, Joon-Man
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.749-754
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    • 2005
  • For the binary system of methanol/3-methyl-1-butanol mixture vapor-liquid equilibrium data were measured isothermally at 50, 55, 60, 65, and $70^{\circ}C$. An empirical relation to predict vapor-liquid equilibrium data was obtained from the above measured data. The predicted values compared with the measured ones were in a good agreement, within accuracy ${\pm}0.0007$. The excess molar volume, measured for the binary system of methanol/3-methyl-1-butanol mixture, was positive $V^Eover$ the entire composition range. The maximum values were shown to be about $0.096cm^3/mol$ at x= 0.683.

Ocean Wave Forecasting and Hindercasting Method to Support for Navigational Safety of Ship (선박의 항행안전지원을 위한 파랑추산에 관한 연구)

  • Shin, Seung-Ho;Hashimoto, Noriaki
    • Journal of Navigation and Port Research
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    • v.27 no.2
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    • pp.111-119
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    • 2003
  • In order to improve navigational safety of ships, an ocean wave prediction model of high precision within a short time, dealing with multi-directional random waves from the information of the sea surface winds encountered at the planned ship's course, was introduced for construction of ocean wave forecasting system on the ship. In this paper, we investigated a sea disaster occurred by a stormy weather in the past. We analyzed the sea surface wind first and then carried out ocean wave hindercasting simulations according to the routes the sunken vessel. From the result of this study, we concluded that the sea disaster was caused by rapidly developed iou pressure system Okhotsk Sea and the predicted values by the third generation wave prediction model(WAM) was agreed well with the observed significant wave height, wave period, and directional wave spectrum. It gives a good applicability for construction of a practical on-board calculation system.

Ocean wave forecasting and hindercasting method to support for navigational safety of ship (선박의 항행안전지원을 위한 파낭추산에 관한 연구)

  • 신승호;교본전명
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2003.05a
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    • pp.147-156
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    • 2003
  • In order to improve navigational safety of ships, on ocean wave prediction model of high precision within a short time, dealing with multi-directional random waves from the information of the sea surface winds encountered at the planned ship's course, was introduced for construction of ocean wave forecasting system on the ship. In this paper, we investigated a sea disaster occurred by a stormy weather in the past. We analyzed the sea surface winds first and then carried out ocean wave hindercasting simulations according to the routes of the sunken vessel. From the result of this study, we concluded that the sea disaster was caused by rapidly developed low pressure system in Okhotsk Sea and the predicted values by the third generation wave prediction model(WAM) was agreed well with the observed significant wave height, was period, and directional wave spectrum. It gives a good applicability for construction of a practical on-board calculation system.

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A Study on Estimation of Energy required for Fin Unfolding (공력면 전개에 필요한 전개 에너지의 추산에 관한 연구)

  • Jung, Suk-Young
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.3
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    • pp.283-292
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    • 2009
  • Considering an integral equation governing the motion of unfolding fin, an algebraic equation was acquired to get estimated minimum deployment energy required for the successful fin unfolding under the given wind condition. To complete the integration of moment, some approximations had to be introduced particularly to frictional moment and aerodynamic damping for which deployment angular speed of the unfolding fin was modelled as a function of deployment angle only with assumed profile using expected maximum angular speed. Technique for the estimation of the minimum required deployment energy was finalized by introducing the ideal deployment angular speed representing work done by the fin unfolding device alone during fin unfolding and was confirmed by comparing results from simulation with various aerodynamic conditions and profiles of the hinge torque.

Flash Points of the Binary Solutions Using Cleveland Open Cup Tester (클리브랜드 개방식 장치를 이용한 2성분계의 인화점)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Fire Science and Engineering
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    • v.25 no.1
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    • pp.57-62
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    • 2011
  • The flash point is one of the most significant combustion properties of flammable liquids in industrial processes when evaluation process safety, In this paper, Cleveland open cup tester is used to measure the flash points for the two binary systems (n-propanol + formic acid and acetic acid + propionic acid). The measured flash points were compared with the values calculated by the Raoult's law and the optimization method using van Laar and Wilson equations. The calculated values based on the optimization method were found to be better than those based on the Raoult's law.

The Different Types of Residuals in Nonlinear Regression Models (비선형 모델에 있어서의 다양한 종류의 잔차들에 관한 연구)

  • Kang, Chang Wook
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.12 no.19
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    • pp.31-37
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    • 1989
  • The recursive residuals are obtained by the iterative processes as descrbed in section 2. They may require more efforts and time to compute and may face difficultie in ordering of data. But we can investigate each case to be deleted and gather more informations on each case. The recursive residuals are much more effective with conjecture of cusum technique. We suggest to use the predicted residual for the construction of recursive residuals in nonlinear regression models. The assessment of influence and leverage by the connection with recursive residuals will be necessary.

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Reproduction of Extreme Waves Caused by Typhoon MAEMI with Wave Hindcasting Method, WAM (II) - Characteristics of extreme waves generated by Typhoon MAEMI in the south coast of Korea - (제3세대 파랑추산모형을 이용한 태풍 '매미'의 극한파랑 재현 (II) - 태풍 '매미'가 야기한 우리나라 남해안 일대의 극한파랑 특성 -)

  • Shin Seung-Ho;Hong Keyyong
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2004.11a
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    • pp.219-225
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    • 2004
  • Following a preceding study if Shin et al.(2004), wave fields for a month if September if 2003 are simulated based on the modified WAM cycle 4 model that enables the precise wave hindcasting with fine spatial meshes, and characteristics of extreme waves at the south roast if Koreo are analyzed The accuracy if applied wave model is verified by comparing computed wave parameters and corresponding ones measured at Ieodo ocean research station. The wave hindasting if typhoon 'Maemi' with an hour time interval reveals the extreme wave characteristics at 4 primary locations if south coast of Korea as follows: 1) At the front sea of Chaguido in the south of Jeju-do, the maximum significant wave height, moon wave period and mean wave direction appear to be 7.41m, 13.65s and $6.4^{\circ}$, respectively at 16:00 KST if Sep. 12, 2003. 2) At the entrance of Masan Bay, 12.50m, 13.65s and $1.2^{\circ}$ at 21:00 KST if Sep. 12. 3) At the front sea of Suyoung Bay, 13.85m, 13.81s and $0.2^{\circ}$ at 22;00 KST if Sep. 12. 4) At the front sea of Ulsan port, 11.00m, 13.25s and $28^{\circ}$ at 23:00 KST if Sep.

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Reproduction of Extreme Waves Caused by Typhoon MAEMI with Wave Hindcasting Method, WAM (II) - Characteristics of extreme waves generated by Typhoon MAEMI in the south coast of Korea - (제3세대 파랑추산모형을 이용한 태풍 ‘매미’의 극한파랑 재현 (II) - 태풍 ‘매미’가 야기한 우리나라 남해안 일대의 극한파랑 특성 -)

  • Shin, Seung-Ho;Hong, Key-Yong
    • Journal of Navigation and Port Research
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    • v.28 no.8
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    • pp.745-751
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    • 2004
  • Following a preceding study of Shin et al.(2004), wave fields for a month of September of 2003 are simulated based on the modified WAM cycle 4 model that enables the precise wave hindcasting with fine spatial meshes, and characteristics of extreme waves at the south coast of Korea are analyzed The accuracy of applied wave model is verified by comparing computed wave parameters and corresponding ones measured at Ieodo ocean research station. The wave hindcasting of typhoon 'Maemi' with an hour time interval reveals the extreme wave characteristics at 4 primary locations of south coast of Korea as follows: 1) At the front sea of Chaguido in the south of Jeju-do, the maximum significant wave height, mean wave period and mean wave direction appear to be 7.41m, 13.65s and $6.4^{\circ}$ respectively at 16:00 KST of Sep. 12, 2003. 2) At the entrance of Masan Bay, 12.50m, 13.65s and $1.2^{\circ}$ at 21:00 KST of Sep. 12. 3) At the front sea of Suyoung Bay, 13.85m, 13.81s and $0.2^{\circ}$ at 22;00 KST of Sep. 12. 4) At the front sea of Ulsan port, l1.00m, 13.25s and $2.8^{\circ}$ at 23:00 KST of Sep. 12.

A Study on the Methods to Improve High-Wave Reproducibility during Typhoon (태풍 내습 시의 고파 재현성 개선방안 연구)

  • Jong-Dai, Back;Kyong-Ho, Ryu;Jong-In, Lee;Weon-Mu, Jeong;Yeon-S., Chang
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.34 no.6
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    • pp.177-187
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    • 2022
  • This study estimates the design wave in the event of a typhoon attack at Busan new port using the wind field, the revised shallow water design wave estimation method proposed by the Ministry of Oceans and Fisheries in 2020, and proposed a reliable method of calculating the shallow water design through verification with the wave observation data. As a result of estimating typhoon wave using the wind field and SWAN numerical model, which are commonly used in the field work, for typhoon that affected Busan new port, it was found that reproducibility was not good except typhoons KONG-REY(1825) and MAYSAK(2009). In particular, in the case of typhoon MAEMI(0314), which had the greatest impact on Busan new port, the maximum significant wave height was estimated to be about 35.0% smaller than that of the observed wave data. Therefore, a plan to improve the reproducibility of typhoon wave was reviewed by applying the method of correcting the wind field and the method of using the Boussinesq equation numerical model, respectively. As a result of the review, it was found that the reproducibility of the wind field was not good as before when the wind field correction. However as a method of linking wind field data, SWAN model results, and Boussinesq numerical model, typhoon wave was estimated during typhoon MAEMI(0314), and the maximum significant wave was similar to the wave observations, so it was reviewed to have good reproducibility.