• Title/Summary/Keyword: 총함량분석

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The physico-chemical properties, mineralogical characteristics and heavy metal distribution of soils in Jeju island (제주도 대표토양의 이화학 및 광물학적 특성과 중금속원소의 분포)

  • Chon Chul-Min;Ahn Joo-Sung;Kim Kue-Young;Park Ki-Hwa
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.194-197
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    • 2006
  • 제주도 대표토양을 대상으로 이들의 모재 및 토양단면의 토양 특성을 조사하고, 제주도 대표토양의 주요 유해 중금속 원소의 총 함량을 분석하여 그 분포특성과 이화학 및 광물학적 특성을 비교 평가하였다. 주성분분석 결과 전형적인 화산회토의 특성을 보이는데 하부 층위에서 Si, Al, Fe 함량의 증가 및 표토에서의 염기용탈을 보여주었다. 현무암질 모재 기원임을 보여주는 ferromagnesian 광물들이 주로 관찰되었으며 심토에서는 상당량의 깁사이트가 관찰되는 것이 특징인데 이는 표토에서 과잉 생성된 알루미늄이 하부토양으로 이동하여 이차적으로 생성집적된 것으로 판단된다. 중금속 총함량 분석결과, Zn, Ni, Co, Cr의 함량이 세계 토양 내 함량범위를 초과하였으며 향후 진행될 연구에서 제주도 화산회 토양의 주 점토구성광물인 알로페인을 비롯한 점토광물 및 비정질 물질에 대한 특성 및 정량적 조사와 중금속원소별 화학적 형태 파악을 위한 연속추출분석 등을 수행하여 중금속원소의 존재상을 규명하고 지표 토양 및 지하수 환경으로의 중금속 이동성을 평가하고자 한다.

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A Study on Sequential Extraction of Heavy Metals from Marine Dredged Sediment at Busan New Port (부산 신항만 준설퇴적물로부터 중금속의 연속추출에 관한 연구)

  • Kim, Myoung-Jin;Jang, Mi-Jeong
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.2
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    • pp.93-102
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    • 2011
  • In this study, experiments on total digestion and sequential extraction were conducted in order to understand total metal contents, and mobility, bioavaliability and toxicity of metals in marine dredged sediment from Busan New Port. The total concentrations of arsenic and heavy metals in the dredged sediment were relatively low as follows: Al (2.36~2.96 wt.%), As (1.6~3.3 mg/kg), Ba (30.0~33.8 mg/kg), Cd (0.12~0.18 mg/kg), Cr (27.5~35.0 mg/kg), Cu (11.3~15.0 mg/kg), Fe (2.91~3.51 wt.%), Mn (324~408 mg/kg), Ni (18.8~23.8 mg/kg), Pb (23.8~31.3 mg/kg), and Zn (70.0~86.3 mg/kg). In addition, it was found that most of Al (87.5~95.9%), As (74.1~93.8%), Ba (71.8~77.6%), Cr (69.5~94.3%), Cu (50.0~78.7%), Fe (70.8~87.6%), Ni (64.5~75.3%), Pb (53.4~64.3%), and Zn (62.5~81.7%) existed in the residual fraction, meaning that those elements might come from natural sources. On the other hand, Cd and Mn were present mainly in the non-residual fraction. Due to low concentrations of toxic heavy metals and high percentage of residual fraction, it could be possible to reuse the dredged sediment for bricks, pavement base material, etc.

Environmental Assessment of Contaminated Soils around Abandoned Mines using The Current Soil Quality Standards

  • Ahn, Joo-Sung;Kim, Kyoung-Woong
    • Journal of Environmental Policy
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    • v.2 no.1
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    • pp.87-105
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    • 2003
  • 토양오염기준은 토지이용별 또는 오염노출경로별 오염토양의 조사, 평가 및 복구를 위한 유용한 지침으로 이용될 수 있다. 이 연구에서는 한국을 포함한 몇몇 국가의 토양오염기준을 특히 중금속에 주안점을 두고 검토하였다. 또한 국내 일부 폐광산 지역의 환경오염 조사결과를 토양오염기준과 비교하며 평가하였다. 영국, 네덜란드, 독일, 캐나다, 일본 등의 국가에서는 복구우선순위 선정과 인체건강 및 생태계 보전을 위한 오염토양의 선별수단으로 토양오염기준을 개발하여 왔다. 국내에서는 1996년 토양환경보전법(시행규칙)의 시행에 따라 토양 오염기준 설정과 특정토양오염유발시설의 관리, 정기적 토양오염도 조사를 실시하고 있으며 이후 2001년 보완 개정되어 토양오염물질의 확대적용과 토양오염 조사, 관리 및 복원 방법의 보완이 이루어진 바 있다. 그럼에도 불구하고 현 중금속(Cd, Cu 및 Pb)의 오염기준을 적용할때 폐광산 지역의 폐기물과 이에 오염된 토양의 경우 다량의 중금속을 함유하고 있지만 오염지역으로 규정되지 않을 수도 있다. 이 연구 결과, 0.1N 염산용출법은 중금속의 토양 내 화학적 형태 중 일부 교환성 및 환원성 형태만을 추출하며 황화물 형태를 충분히 용출하지 못하고 있는 것으로 나타났다. 또한 장기적인 환경조건 변화에 따른 토양 내 중금속의 용출성 변화를 평가하기 위해서는 강산추출법이 요구되어진다. 따라서 폐광산지 역의 중금속에 의한 토양오염의 타당한 환경평가 결정을 위해 현 분석기법 외에 총함량 분석방법의 병행적용과 이에 따른 새로운 오염기준 설정 등이 필요한 것으로 제시되었다.

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A Study on the Heavy Metal Contamination of paddy Soil in the Vicinity of the Seosung Pb-Zn Mine (서성 연-아연광산 주변 농경지 토양의 중금속 오염 연구)

  • 황은하;위수민;이평구;최상훈
    • Journal of Korea Soil Environment Society
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    • v.5 no.2
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    • pp.67-85
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    • 2000
  • Fifty seven soil samples were collected from the paddy soil filled with tailings in the vicinity of the Seosung Pb-Zn mine. Those samples were analyzed for As, Cd, Co, Cr, Cu, Pb, and Zn in order to investigate heavy metal pollution levels in the paddy soil. Analyses of the soil samples were carried out using Inductively Coupled Plasma Atomic Emission Spectrometry(ICP-AES) . Paddy soils show pH range from 6.55 to 8.26. X-ray diffraction analyses of the paddy soil indicate that the soils consist predominantly ankerite, siderite, quartz, mica, and clay minerals with minor amounts of amphibole and chlorite. The mineral composition of the waste rocks consists of massive galena, sphalerite, and minor amounts of pyrite, arsenopyrite, chalcopyrite, calcite, siderite, Pb-sulfosalt, and marcasite. The paddy soils were significantly contaminated by heavy metals(average concentrations, As: 334.4 ppm, Cd: 37.6 ppm, Co: 15.7 ppm, Cu: 214.1 ppm, Pb: 4,612 ppm, and Zn: 4,468 ppm).

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A Study on the Composition of Cordyceps militaris Extract and Mycelium (동충하초 추출물과 균사체의 성분분석에 관한 연구)

  • 차월석;조배식;박세영
    • Journal of Life Science
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    • v.14 no.5
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    • pp.727-731
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    • 2004
  • The composition of fruit body extract and mycelium in Cordyceps militaris has been investigated to determine the nutritional value. The nutritional compositions of fruit body extract were as follows; the content of crude fat, carbohydrate, crude protein were 0.16%, 3.10% and 1.05%, respectively. And content of crude fat, carbohydrate, crude protein in mycelium were 14.01 %, 54.70% and 20.54%, respectively. Potassium concentration in 1.36 g/100ml sample of fruit body extract was high up to 79.09 mg/100 g and Ca, P, Mg, Na, Mn, Zn and Cu were followed. As well, potassium concentration in 0.50 g/100 ml sample of mycelium was high up to 1,679.96 mg/100 g and P, Mg, Ca, Na, Fe, Mn, Zn and Cu were followed. There were 21 and 22 amino acids in fruit body extract and mycelium, respectively. The total content of 21 amino acids in fruit body extract was 223.78 mg/100 ml. It is more than 147.40 mg/100 ml which total content of 22 amino acid in mycelium. But the total content of essential amino acids in mycelium were higher than fruit body extract. The total content of 10 vitamin in fruit body and mycelium were 13.88 mg/100 g and 221.23 mg/100 g respectively, and the total content of vitamin in mycelium was sixteen times as more as fruit body extract.

Physicochemical Characteristics of Tailings from the Various Types of Mineral Deposits (광상유형에 따른 광물찌꺼기의 물리화학적 특성)

  • Lee, Pyeong-Koo;Youm, Seung-Jun;Jung, Myung-Chae;Lee, Jin-Soo;Kwon, Hyun-Ho
    • Economic and Environmental Geology
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    • v.43 no.3
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    • pp.235-248
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    • 2010
  • To construct the standard methods for evaluation of physicochemical characteristics of tailings in Korea, specific gravity, paste pH, grain size, mineral compositions and heavy metal concentrations of total 26 tailings from 21 metallic mines were analyzed. Specific gravity of tailings ranged from 2.61 to 4.31 (avg. 3.04), and sand and silt grain were dominant in the tailings. Ranges of paste pH were 2.1-9.5 in tailings (7.1-9.2 at magmatic, skarn and hydrothermal replacement deposits and 2.1-9.5 at hydrothermal vein deposits). Additionally, hydrothermal vein deposits could be reclassified into three categories: (1) paste pH>7.0, (2) 4.0

Effects of Amendments on Heavy Metal Uptake by Leafy, Root, Fruit Vegetables in Alkali Upland Soil (염기성 밭 토양에서 안정화제에 의한 엽채류, 근채류, 과채류 작물들의 중금속 전이 특성)

  • Kim, Min-Suk;Min, Hyun-Gi;Lee, Sang-Hwan;Kim, Jeong-Gyu
    • Ecology and Resilient Infrastructure
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    • v.7 no.1
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    • pp.63-71
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    • 2020
  • Various types of amendments have been studied for heavy metal stabilization in soil. However, researches on the effect of amendments on alkali soil and their effects on the plants at various edible parts are insufficient. The aim of this study was to evaluate the stabilization efficiency of heavy metals and their transfer into edible parts of food crops. Abandoned mine area was selected and 3 types of amendments (lime stone, LS; steel slag, SS; acid mine drainage sludge, AMDS) was applied with 3% (w/w). in field. After 6 month aging, Chinese cabbage (leafy), bok choy (leafy), garlic (root) and red pepper (fruit) were transplanted and cultivated. For chemical assessment, total concentration and bioavailability using Mehlich-3 solution were determined. For biological assessment, fresh weight and heavy metal uptakes were analyzed. It was revealed that AMDS reduced bioavailability most effectively, resulting in the decrease in heavy metal concentration in edible parts of all crops. When explaining the heavy metal uptake of plants, the bioavailability was more appropriate than the total contents of soil heavy metals. Therefore, bioavailability-based further research and management practices should be carried out continuously for the sustainable environment management, safe crop production, and human health risk reduction.

Pollution and Ecological Risk Assessment of Trace Metals in Surface Sediments of the Ulsan-Onsan Coast (울산-온산연안 표층퇴적물 내 미량금속 오염도 및 생태위해성 평가)

  • Sun, Chul-In;Kim, Dong-Jae;Lee, Yong-Woo;Kim, Seong-Soo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.4
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    • pp.245-253
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    • 2015
  • Total acid digestion and 1 M HCl extraction methods were used to investigate the pollution status and the degree of ecological risk of trace metals in surface sediments from the Ulsan-Onsan coast. Total concentrations of trace metals (Cu, Cd, Pb, Zn, and Hg) were two-fold higher in surface sediments from Onsan coast than in those from Ulsan coast. The mean labile fractions of the total concentrations of Cd and Pb were 72% and 78%, respectively, indicating a high contribution from anthropogenic sources, whereas Cr, Li, Ni, and As in the residual fraction exceeded 80%, indicating a high contribution from natural sources. According to the results of assessment of trace metal pollution using the sediment quality guidelines in Korea, the concentrations of Cu, Pb, Zn, and Hg were higher than the values of the probable effects level (PEL) at some stations of Onsan coast, and the concentrations of Cr and Ni were lower than the values of the threshold effects level (TEL). The pollution level and ecological risk of the trace metals were analyzed using various indexes (EF, $I_{geo}$, m-PEL-Q, and ERI). Our results showed that the degree of pollution by trace metals (Cu, Cd, Pb, Zn, and Hg) on the Ulsan-Onsan coast was high, and Hg and Cd were the major potential ecological risk factors.

Southward Transport of Suspended Sediments during Summer Season in the Coastal Zone off Tae-An Peninsula, West Coast of Korea (하계동안 한국 서해 태안반도 연근해에서 부유퇴적물의 운반양상)

  • Choi, Jin-Yung;Park, Yong-Ahn
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.3 no.1
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    • pp.45-52
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    • 1998
  • The transport of suspended matter was interpreted in the coastal zone off Taean Peninsula during the summer (June) in 1996. Coastal waters were homogenous in water temperature and salinity, whereas offshore waters were characterzed by the strong thermocline. Mixing between coastal and offshore waters are negligeable, largely lessened, due to the existence of strong tidal front between the two water masses. In the offshore area, less saline coastal waters from the Kyunggi Bay are considered to be transported southward along the mid-depth layer of thermocline. Concentration of suspended matters was higher than 5 mg/l in the northern coastal area near the Kyunggi Bay, but generally less than 2 mg/l in the offshore area. Less saline waters along the mid-depth layer in the offshore area sustain maximum turbidities throughout the water column. Therefore suspended matters supplied from the coastal area of Kyunggi Bay are considered to be transported southward by the advective movement of less saline coastal waters. Mean particle size of the suspended matters shows 2~9 ${\mu}m$. Coarse grains (mean size larger than 7 ${\mu}m$) are predominant in the less saline coastal waters extending to the offshore mid-depth waters. Such size distributions of suspended matters together with the characteristics of water masses are considered to be an indicator for the southward movement of suspended matters derived from Kyunggi Bay.

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Seasonal Variation of Lipids and Fatty Acids of Sharp Toothed Eel(Muraenesox cinereus) (갯장어의 일반성분과 지방산의 계절적 변화)

  • 안창범;신태선
    • Journal of Life Science
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    • v.12 no.3
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    • pp.233-241
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    • 2002
  • Seasonal variation of uraenesox cinereus) muscle was investigated. Crude lipid content varied from 3.85 to 12.59 g/100g, comprising the highest content in November. The major fatty acids of total lipid, neutral lipid, and phospholipid were C16:0, C23:0, C16:1, C18:1, C20:5, and C22:6, but in phospholipid, Cl8:3n-6 was also the major fatty acid. The C22:6 content of the neutral lipid was much lower compared to that of the total lipid and phospholipid. The content of polyunsaturated fatty acids (ranged from 73.93 to 66.23%) in phospholipid was higher than that of any other lipid fraction. In glycolipid, C20:1 and C14:1 were higher compared to those of any other lipid fraction, but C20:5 and C22:6 were lower. The annual average ratio of n-3 to n-6 of total lipid, neutral lipid, phospholipid, and glycolipid was 10.82, 12.27, 6.63, and 6.50, respectively. The particular trend of seasonal variation of fatty acid composition was not showed in total and neutral lipid. However, the samples caught in September and November had a high crude lipid content with a significantly lower content of polyunsaturated fatty acids in phospholipid. Also, the content of monounsaturated fatty acids in glycolipid was lower in samples of September, November, and January.