• Resources Recycling
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• v.22 no.4
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• pp.38-45
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• 2013

The porous ceramic beads using mine tailing were prepared and applied to catalytic converter for NOx/SOx removal. Catalytic support was used synthesized mesoporous silica (SBA-15) which coated on surface. Internal structure for porous ceramic beads was composed of three-dimensional network structure and porosity was about 80%. In addition, the specific surface area for mesoporous silica(SBA-15) coated on converter was significantly increased 55 $m^2/g$ compared with 0.8 $m^2/g$ before coating. NOx/SOx removal experiment was performed using $V_2O_5$ and $V_2O_5$/CuO converter. NOx conversion ratio for $V_2O_5$/CuO converter was approximately increased 10% compared to $V_2O_5$ converter. In addition, catalytic converter of $V_2O_5$/CuO was shown to remove 95% of NOx and 90% of SOx at reaction temperature of $350^{\circ}C$, space velocity of 10000 $h^{-1}$ and $O_2$ concentrations of 5%, respectively.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.1
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• pp.115-124
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• 2002

The optimum design of auto-catalyst needs a good compromise between the pressure drop and flow distribution in the monolith. One of the effective methods to achieve this goal is to use the concept of radially variable cell density. However, there has been no study of evaluating the usefulness of this method on light-off catalyst. We have computationally investigated the effectiveness of variable cell density technique applied to the light-off catalyst using a three-dimensional integrated CFD model. in which transient chemical reacting calculations are involved. Computed results show that variable cell density technique can reduce the accumulated emissions of CO and HC during the early 100sec of FTP cycle by 86.78 and 80.87%, respectively, The effect of air-gap between the monoliths has been also examined. It is found that air-gap has a beneficial effect on reducing pressure drop and cold-start emissions.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.113.1-113.1
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• 2010

본 연구에서는 중 소형 SOFC에 적용할 수 있는 연료 변환 시스템으로 자체 기동 및 독립운전이 가능한 천연가스 자열개질(ATR) 반응기를 $10Nm^3/hr$급으로 개발하고자한다. 설계된 천연가스 자열개질기는 자열개질 촉매를 코팅한 금속 모노리스형 촉매체를 반응기 내에 장착함으로써 반응열을 신속하게 제거 또는 공급할 수 있는 시스템으로 구성되었다. 이는 금속 모노리스의 뛰어난 열전도 능력에 의해 반응기 내의 촉매층 전체 온도 분포를 균일하게 유지할 수 있는 저에너지형 자열개질 반응기이다. 또한 빠른 기동 특성을 실현하기 위하여 전기 발열식 촉매체(EHC ; Electically Heated Catalyst)를 장착한 start-up 시스템을 적용하여 천연가스 자열개질 반응기의 신속한 기동과 장치 간편화를 실현하였으며, 합성 syngas의 배열 회수를 위한 최적 열교환 시스템을 설계/적용함으로써 에너지 효율 향상을 도모하였다. 이와 같은 촉매 및 구조 시스템을 가지는 천연가스 자열개질 반응용 소형 연료변환 시스템을 원통형의 이중관 구조로 구성하고, 독립운전 모드로 개발함으로써 소형 SOFC의 연료 변환장치의 적용에 용이하게 하고자 한다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.3
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• pp.197-202
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• 2014

The efficiency of a catalytic converter depends on the flow distribution across a system's chemically active substrate. If irregularities or non-uniform flow patterns exist, the system's conversion efficiency decreases, whereas the manufacturing cost increases. Therefore, it is important to analyze the internal flow of a catalytic converter. In this study, flow pattern measurements along the minor axis were recorded at the mid and exit planes of a ceramic honeycomb catalytic converter at flow rates of 37.8 l/s and 94.4 l/s. Flow distributions of the measurement plans were compared with an automotive company's computed velocity profiles. Measurements along the minor axis showed uneven velocity profiles. The ${\upsilon}$-velocity components between the honeycomb bricks were small but somewhat erratic opposite the intake side of the converter, however, they became flatter in measurements recorded near the intake entrance. For almost all velocity values, the computer model suggested velocities greater than the measured values.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.3
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• pp.419-427
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• 2013

The catalytic converters for automobile exhaust systems are manufactured by inserting a mat-wrapped substrate into a stainless steel can. A residual pressure that is too high will initiate a fracture in the substrate. In contrast, a residual pressure that is too low will fail to hold the substrate in the acceleration or deceleration phase. Both the process capability and mat pressure on the substrate are predicted while considering the effect of the statistical variation in the dimensions of the parts. The validity of the solutions is then confirmed. A program using EXCEL combines a finite element analysis and process capability analysis in one program.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.11
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• pp.1471-1476
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• 2011

The catalytic converter in the front part of an automobile's exhaust system converts toxic exhaust gas into nontoxic gas. The substrate in the central part of the converter has a circular or oval-shaped cross section and fine lattice-shaped walls. In the canning process, the substrate is wrapped in mats and inserted into a can. During this process, mat pressure is induced, which may cause brittle fracturing in the substrate. In this paper, a finite element program for determining the mat pressure distribution was developed to avoid these fractures. The program was created in Microsoft EXCEL, so the input and output procedures are relatively simple. It was assumed that the substrate is rigid, the mat is material nonlinear, and the can is linear elastic. The can is modeled as a beam element to resist both bending and uniform tension/compression. The number of elements is fixed to 35, and the number of iterations, to 20. The solutions are compared to ABAQUS solutions and found to be in good agreement.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.12
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• pp.1596-1607
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• 2000

The optimal design of auto-catalyst needs a good compromise between the pressure drop and flow uniformity in the substrate. One of the effective methods to achieve this goal is to use the concept of radially variable cell density. But this method has not been examined its usefulness in terms of chemical behavior and conversion performance. In this work, two-dimensional performance prediction of catalyst coupled with turbulent reacting flow simulation has been used to evaluated the benefits of this method n the flow uniformity and conversion efficiency. The results showed that two cell combination of 93cpsc and 62 cpsc was the most effective for improved pressure drop and conversion efficiency due to balanced space velocity and efficient usage of geometric surface area of channels. It was also found that large temperature difference between the bricks in case that the edge of the frontal face of brick has too much lower cell density(less than 67% of cell density of the center of the brick). This study has also demonstrated that the present computational results show the better prediction accuracy in terms of CO, HC and NO conversion efficiencies compared to those of conventional 1-D adiabatic model by comparison with experimental results.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.5
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• pp.55-65
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• 1998

A numerical and experimental study of three-dimensional steady incompressible non-reacting flow inside various dual-monolith catalytic converters has been conducted for achievement of performance improvement, reduction of light-off time and longer service life by improving the flow uniformity within the monolith. In this study, the effects of curvature of inlet exhaust pipe and monolith brick length on the flow uniformity and pressure drop within monolith were numerically investigated. The computations are confirmed by measurements of steady flow. The agreement between computations and experiment was relatively good. The result of this study shows that curvature of inlet exhaust pipe and monolith brick length gave a great effect on the flow uniformity and the shorter the brick length, the lower flow uniformity and the less pressure drop.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.5
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• pp.107-120
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• 1999

Catalytic converters are the most fascinating and complicated chemical reactors. They are most often operated in the transient state with respect to composition, flow rate, temperature, etc. The mathermatical model developed in this work accounts for simultaneous heat and mass transfer, chemical reaction, and multi dimensional flow characteristics to analyze the light-off performance of monolithic catalytic converter with comparable mass flow rate. To validate the mathematical model, comparison between experimental and numerical results has been performed. The numerical results show a good agreement with experimental data. It is forund that inflow rate shows major effect on the characteristics of termal response of catalytic converter.

• Proceedings of the KAIS Fall Conference
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• 2009.12a
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• pp.163-166
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• 2009

현재 자동차 검사 또는 정비 현장에서는 특정 삼원촉매변환기가 요구 내구 수명을 제대로 만족시키지 못하여 파손되는 사례가 발생되고 있다. 이러한 삼원촉매장치의 경우 배기가스 변환 효율이나 압력강하 등은 엔진 효율 측면에서 만족되지만 열적 내구성은 만족되지 못한다. 본 연구에서는 열유동 해석 및 구조 해석을 통하여 국내 승용차용 삼원촉매 변환기의 대한 열적 안전성에 대하여 검토하였다.