• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.39 no.4
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• pp.348-353
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• 2011

Characteristics of cryogenic single jet flow were investigated. Liquid nitrogen was injected into a high-pressure chamber and formed single jet. Ambient condition around jet was changed from subcritical to superctirical condition of nitrogen. Injector geometries also were changed. A shape of the jet and core diameter were measured by flow visualization technique, and core spreading angle was calculated. Flow instability was found at atmospheric pressure condition. As ambient pressure increased, core spreading angle was increased and maintained after certain pressure.

• Journal of the KSME
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• v.56 no.9
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• pp.38-43
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• 2016

초임계 난류유동이 활용되고 있는 가장 대표적인 시스템은 액체로켓연소기이다. 액체로켓엔진은 목적하는 임무에 따라 추력이 결정되고 엔진의 추력이 결정된다. 이러한 추력을 결정하는 핵심부품이 분사기(injector)이다. 실용 인공위성을 발사하기 위한 액체로켓엔진의 연소기는 수백 개의 분사기를 통해 연료와 산화제가 혼합되는 구조를 가지고 있다. 따라서 로켓연소기의 연소특성 및 성능은 분사기의 혼합특성에 좌우된다. 그러므로 단일 분사기의 연료/산화제 혼합특성에 대한 많은 실험과 해석연구가 진행되고 있다. 그런데 초임계압력에서는 액체의 표면장력이 사라지게 되어 독특한 혼합특성을 가지고 있기 때문에 성능을 높여주기 위하여 초임계 압력을 선택할 경우 분사기에 대한 연구가 선행되어야 한다. 이 글에서는 이러한 초임계 작동압력에서 분사기에 대한 연구들을 소개하고자 한다.

• Applied Biological Chemistry
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• v.41 no.5
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• pp.363-366
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• 1998

Supercritical fluid(SCF) carbon dioxide was used to extract safflower yellow pigments from Carthamus tinctorius L. In this work, supercritical fluid extractions were performed at various conditions; pressure (2000, 3000, 4000, 5000 psig), temperature $(40,\;50,\;60,\;70,\;80^{\circ}C)$ and co-solvent $(0,\;3,\;6,\;10,\;14\;wt%\;H_2O)$. Total concentrations of safflower yellow pigments extracted were determined by spectrophotometric method. A maximum yield of yellow pigments was obtained at 4000psig, $60^{\circ}C$ and 10% co-solvent. The extraction yield of pigments was also closely related to moisture content of the raw material. Extraction yield of safflower yellow pigments by SCF extraction at optimized conditions was 6% higher than that by solvent extraction. Supercritical carbon dioxide was proved to be suitable for the extraction of safflower yellow pigments from Carthamus tinctorius L.

• Journal of the KSME
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• v.55 no.7
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• pp.37-41
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• 2015

이 글에서는 초임계 유체 이용기술의 일환으로서 바이오매스의 초임계수 가스화 기술을 소개하였다. 초임계수 가스화 기술의 원리와 특징, 가스화 반응조건, 그리고 기술개발 현황을 정리한 다음, 향후 이 기술의 상용화를 위하여 극복해야 할 과제를 제시하였다.

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.171-174
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• 2001

초임계유체(supercritical fluid, SCF)는 친환경적 용매로서 고분자 합성과 기능화를 비롯하여 RESS(rapid expansion of supercritical solution)와 초임계염색 등의 섬유공정 분야에서 연구자들의 흥미로운 관심을 받아 오고 있다. 초임계유체는 기체와 액체의 중간적인 특성을 가지면서도 가스와 같이 우수한 확산력을 가지며 또한 아주 낮은 점도를 갖는다. SCF 중에서 비교적 온화한 조건(31.1℃의 임계온도, 73.8기압의 임계압력, Figure 1)에서 초임계상태를 가질 수 있는 이산화탄소가 가장 많이 이용되고 있는데 이는 자원이 풍부하며 쉽게 회수하여 사용할 수 있어 응용 면에서 유리하다. (중략)

• Korean Chemical Engineering Research
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• v.45 no.4
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• pp.384-390
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• 2007

In this study, electroless plating of copper was performed on PET film by using the blend of supercritical $CO_2$ and plating solution. The optimum volumetric ratio of supercritical fluid and plating solution was found to be 1:9 and dispersion property was poor at $CO_2$ vol% langer than 10%. Electroless plating of copper was best at $25^{\circ}C$ and 15 MPa. Role of added supercritical $CO_2$ is not to increase solubility but to disperse and maintain Cu-particles as the 1st particles.

• KSBB Journal
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• v.18 no.5
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• pp.385-392
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• 2003

Biodegradable poly (L-lactide) (L-PLA) solution in methylene chloride was precipitated into microparticles by using supercritical carbon dioxide modified with polar cosolvents. The effects of the amount of polar cosolvents, solution concentration, temperature, and solution flow rate on the formation of microparticles were investigated. The mean particle size was found to increase with the increase of solution concentration and flow rate. It was also observed that the particle size not only increases but the size distribution also becomes less uniform as the temperature increases. The percent recovery of microparticles was found to be 30∼40% at all experimental conditions. The supercritical carbon dioxide modified with methanol and ethanol was employed to enhance the recovery, resulting in significant improvement up to about 80 and 70%, for methanol and ethanol, respectively. Furthermore, the mean diameter of L-PLA microparticles was found to be less than 1 $\mu\textrm{m}$ for both cosolvents.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.19-23
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• 2010

Injection characteristics of a kerosene swirl injector of liquid rocket engine operating at supercritical environment have been investigated. Kerosene surrogate models are proposed to model the kerosene properties. Turbulent numerical model is based on large eddy simulation and contains Soave modification of Redlich-Kwong equation of state and Chung's model. Numerical analysis results at supercritical environment are compared with the one at transcritical condition. Differences of density and viscosity are analyzed at both liquid film and core gas in the swirl injector.

• Journal of Life Science
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• v.13 no.5
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• pp.569-575
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• 2003

Supercritical $CO_2$ extraction was applied to extraction of the valuable compound for benign prostatic hyperplasia from saw palmitto. Three levels of parameters, temperature $(35^{\circ}C,\; 60^<\circ}C)$, pressure 22∼30 Mpa and ethanol modified solvent concentration, were used as the independent variables of central composite to rotate the design. The extracting pressure and temperature interaction was significantly affected the extraction of valuable compounds. The ethanol was an efficient modifier to extract valuable compound by supercritical carbon dioxide. The optimal processing conditions were extracting pressure, 30 Mpa, extracting temperature, $60^<\circ}C$, ethanol modifier, 15% for extracts of the valuable compounds from saw palmitto. In conclusion, it was found that supercritical $CO_2$ extraction can successfully be applied to extract high quality extracts from saw palmitto.

• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.281-286
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• 2009

Bitumen extraction and sulfur removal from Athabasca oil sand were conducted using water in sub- and supercritical condition. Bitumen yield in micro reactor was investigated in the pressure range of 15~30 MPa, the temperature of 360 and $380^{\circ}C$ and water density $0.074{\sim}0.61g/cm^3$ for 0~120 min. Bitumen yield increased with reaction pressure irrespective of temperature and dramatically increased in especially supercritical region due to hydrogen formed from water gas shift reaction. Total amount of gas product decreased with reaction pressure but the portion of sulfur and hydrogen increased a little with increasing pressure to 25 and 30 MPa. It is seen that supercritical condition was favourable to the hydrogen formation and sulfur removal. Bitumen yield and sulfur removal from original oil sand reached a maximum 22% and 40% respectively in supercritical condition(the reaction time of 60 min at $380^{\circ}C$ and 25 or 30 MPa).