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Hydrothermal Synthesis of Smectite from Zeolite (제올라이트로부터 스멕타이트 수열 합성에 대한 연구)

  • Chae, Soo-Chun;Kim, You-Dong;Jang, Young-Nam;Bae, In-Kook;Ryu, Kyung-Won;Lee, Sung-Ki
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.301-310
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    • 2006
  • Smectites were synthesized from Na-P type and Na-A type zeolites by the hydrothermal synthetic method, and their physicochemical properties were studied. The optimal synthetic conditions for producing smectite were $290^{\circ}C$, 72 hr and $75{\sim}100kgf/cm^2$ in autogenous pressure. pHs of initial reaction solutions for the synthesis of smectites from Na-P type and Na-A type zeolite s were pH 6 and pH 10, respectively. The synthetic smectite was confirmed as $12{\AA}$-beidellite by a series of analysis such as X-ray diffraction analysis with random and oriented mounts, ethylene glycol treatment, and Greene-Kelly test, and their several physicochemical properties were studied.

Behavior of girth-welded buried steel pipes under external pressure (원주 용접된 압력 매설강관의 거동 분석)

  • Jeon, Juntai;Lee, Chinhyung;Chang, Kyongho
    • Journal of the Society of Disaster Information
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    • v.11 no.1
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    • pp.1-8
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    • 2015
  • This paper presents finite element (FE) analyses to clarify the effects of external pressure on the residual stresses in a girth-welded steel pipe. At first, FE simulation of the girth welding process is carried out to obtain the weld-induced residual stresses employing sequentially coupled three-dimensional (3-D) thermo-mechanical FE formulation. Then, 3-D elastic-plastic FE analyses incorporating the residual stresses and plastic strains obtained from the preceding FE simulation are performed to investigate the residual stress behavior in the girth-welded pipe under external pressure. The FE analysis results show that the hoop compressive stresses induced by the external pressure significantly alter the hoop residual stresses in the course of the mechanical loading.

Contamination structure and process on SUS 316 under UHV, HV and air (초고진공, 고진공, 대기압에서 SUS 316의 오염 구조와 오염 과정 연구)

  • 서지근;이규장;신용현;홍승수;정광화
    • Journal of the Korean Vacuum Society
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    • v.6 no.1
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    • pp.1-8
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    • 1997
  • The contamination structure and process on SUS 316 under various exposure conditions were investigated using x-ray photoelectron spectroscopy. The metal-oxide, metal-H-oxides, CO, COH, and $C_xH_y$ are the main components of contaminants on the SUS surface. The compositional profiles of the contaminants are shown to be $C_xH_y$/CO(COH)/metal-oxide on SUS. The contamination proceeds in two steps. The oxidation of the metallic constituents followed by adsorption of hydrocarbons. Under UHV conditions the contamination is mainly due to the oxidation, and, as the exposure time increases, the oxidation continues. In HV or higher pressure, most of the oxides are formed almost immediately after exposure and as the exposure time increases the contamination of hydrocarbons continues to grow. For the SUS sample exposed to atmosphere, the metal oxide is distributed deep inside the surface with an exponentially decreasing concentration, and its thickness is nearly in the order of photoelectron mean free path. It is also seen that the Fe oxide is segregated over Cr oxide in the highly oxidized samples.

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Analysis of the Uncertainty of Compressive Forces Acting on the Patella by Using Multi-Body Modeling and Muscle Mechanics (다물체 모델링과 근의 특성을 이용한 무릎뼈에 가해지는 압력의 불확실성 추정 연구)

  • NamGoong, Hong;Yoo, Hong-Hee
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.7
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    • pp.785-790
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    • 2011
  • The goal of this study is to estimate the force acting on the knee joint in the human body by using the Hilltype muscle model based on a musculoskeletal model of the human lower extremity in the sagittal plane. For estimating the force applied, the human leg is modeled using multi-body modeling. This leg model comprises biarticular muscles acting on two joints of the upper and lower limbs, and the muscles include some of the major muscles such as the hamstring. In order to analyze the uncertainty of the applied forces acting on the knee joint, statistical distributions of human body, leg part, parameters are required and to obtain the parameter's statistical characteristic of the part sample survey method is employed. Finally, by using the sensitivity information of the parameters, the force acting on the knee joint can be estimated.

고밀도 알루미늄 박막 코팅과 특성 분석

  • Yang, Ji-Hun;Jeong, Jae-In;Jang, Seung-Hyeon;Park, Hye-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.45-45
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    • 2011
  • 알루미늄과 그 합금은 내부식성(corrosion resistance)이 좋고, 밀도가 낮아 높은 연료소비 효율을 필요로 하는 항공기와 자동차 같은 운송수단의 내-외장 소재로 사용되고 있다. 또한 알루미늄의 높은 내부식성을 이용하여 철강소재의 부식을 방지하는 보호막으로도 폭 넓게 사용된다. 물리기상증착(physical vapor deposition)으로 알루미늄을 코팅하면 박막 성장 초기단계에서 핵(nucleus)을 형성하고, 형성된 핵을 중심으로 주상 구조(columnar structure)로 박막이 성장하는 것이 일반적으로 알려진 방식이다. 주상 구조의 알루미늄 박막은 주상정과 주상정 사이에 필연적으로 공극(pore)이 존재하게 되어 부식을 일으키는 물질이 박막으로 침투하게 되고, 부식 물질과 모재가 반응하여 공식(pitting corrosion)이 발생한다. 본 연구에서는 스퍼터링(magnetron sputtering)을 이용하여 치밀한 조직을 갖는 알루미늄 박막을 코팅할 수 있는 공정을 개발하고, 치밀한 알루미늄 조직이 내부식성에 어떠한 영향을 미치는지 평가하였다. 기판은 냉연강판(cold rolled steel sheet)이 사용되었으며, 알루미늄 타겟의 순도는 99.999%, 크기는 직경 4"이었다. 냉연강판은 진공용기(vacuum chamber)에 장착하기 전에 계면활성제를 이용하여 표면에 존재하는 기름성분을 제거하였으며, 진공용기에 장착한 후에는 아르곤 가스를 이용하여 발생시킨 글로우 방전으로 표면에 존재하는 산화물을 제거하였다. 알루미늄 박막의 조직에 영향을 미치는 공정변수를 확인하기 위해서 스퍼터링 파워, 공정 온도, 공정 압력, 외부 자기장 세기 등의 공정 조건을 변화시켜 코팅을 실시하였다. 실험을 통해서 얻어진 최적 조건으로 알루미늄을 코팅할 경우, 알루미늄 bulk의 밀도와 비교하여 약 94.7%의 밀도를 갖는 알루미늄 박막을 코팅할 수 있었다. 알루미늄 박막이 약 3 ${\mu}$m의 두께로 코팅된 냉연강판의 내부식성 평가(salt spray test, 5% NaCl) 결과, 평가를 시작한 후 72시간 후에도 적청이 발생하지 않았다.

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Postbuckling of Composite Cylinders under External Hydrostatic Pressure (외부 수압을 받는 복합재 원통의 후좌굴 연구)

  • Son, Hee-Jin;Choi, Jin-Ho;Cho, Jong-Rae;Cho, Sang-Rae;Kweon, Jin-Hwe
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.3
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    • pp.196-203
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    • 2007
  • The postbuckling behavior and failure of composite cylinders subjected to external hydrostatic pressure are investigated by a finite element method and test. A nonlinear finite element program, ACOS, is used for the postbuckling progressive failure analysis of composite cylinders. A total of 5 carbon/epoxy composite cylinders were fabricated and tested to verify the finite element results. For comparison, analyses by MSC/NASTRAN and MSC/MARC are additionally conducted. Among the softwares, the finite element program, ACOS, predicts the buckling loads the best with about 11 to 26% deviation from experimental results except for one specimen. While the finite element analysis shows global buckling modes with 4 waves in hoop direction, in the experiments the local buckling appears first and results in the final failure without global buckling.

A Study on Factors Influencing User's Satisfaction of OTT Service (OTT 서비스의 이용만족도에 영향을 미치는 요인에 관한 연구)

  • Lee, heesung;Jin, Haiyan;Hwang, HaSung
    • Journal of Internet Computing and Services
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    • v.18 no.6
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    • pp.93-100
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    • 2017
  • In multi-media, multi-channel era, video viewing using various digital devices via the Internet, not the existing broadcasting network, is emerging as a new broadcasting viewing behavior. OTT service is regarded as the main service of this change of viewing behavior. It is a video service that can seamlessly use any content desired by the user at any time, at any time, any device, any contents, if the Internet connection is available. The purpose of this study is to investigate the factors affecting the satisfaction of OTT service by applying the technology acceptance model (TAM). As a result of analyzing through 303 questionnaires of the early users of OTT service, social pressure, perceived popularity, perceived cost, user reputation, individual innovation, and esthetics set as external factors in this study are partially affects perceived usefulness, perceived ease of use, and perceived enjoyment. In addition, perceived usefulness, ease of use, and enjoyment are directly influencing satisfaction. Based on these results, we discuss the theoretical and practical implications and propose future research direction.

A Characteristics of Shear Strength and Deformation of Decomposed Granite Soil (화강토의 전단강도 및 변형특성)

  • 박병기;이강일
    • Geotechnical Engineering
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    • v.13 no.4
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    • pp.177-198
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    • 1997
  • Since decomposed granite soil shows various characteristics of shear behavior dependent on initial conditions such as weathering degree and grain breakage, it is nacessary to invert ligate stress -strain relationship and changes of shear characteristics for different initial conditions. Associated with abovefnentioned view, direct shear tests, and triaxial compression tutsts(Ef, CD) were carried out in this study for undisturbed and disturbed compacted weathered granite samples obtained from 4 construction work sites with the various weathering degree and components of parent rocks. The deformation behavior of undisturbed samples under small confining stress shows hardening to softening, which is similar to that of over nsolidated clay whereas disturbed weathered granite soils do hardeningfonstant regardless of weathering degree, which is also similar to sedimentary clay. Conventional direct shear-tests for undisturbed samples show a tendency to overestimate cohesion. It is possidle to approximate stress ratio(q/p') and volumetric increment ratio(dv/ds) in the triaxital compression tests by an equation, ($dv/d\varepsilon,=\alpha(M-\eta))$ irrespective of moisture content, weathering degree and disturbance.

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TREATMENT OF PRIMARY AND PERMANENT TEETH WITH THE AIR-ABRASIVE TECHNOLOGY (Air abrasion 기술을 이용한 유치 및 영구치의 수복)

  • Cho, Hyun;Lee, Kwang-Hee;Kim, Dae-Eop;Song, In-Kyung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.29 no.2
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    • pp.210-216
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    • 2002
  • Air abrasion technology can prepare enamel and dentin for bonding, similar to etching by acidic gels and solutions. Longer treatment can excavate pit and fissures, preparing the tooth for immediate placement of bonded resin materials. Although not appropriate for every clinical situation, the air abrasive technology minimizes heat, vibration and bone-conducted noise associated with conventional means of caries removal since the cutting is accomplished by air pressure. Also, patients treated with the air-abrasion technology rarely request anesthesia. Air abrasion technology was more effective in treating early carious lesions and stains compared to lesions where caries had already progressed to produce soft dentin and the strong air stream and noise caused by the evacuation system was a major discomfort to pediatric patients, and the experience and skillfulness of clinician should be required for accurate and proper tooth preparation.

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Decomposition of PET in High Pressure Subcritical Water (고압 아임계수 내에서 PET의 분해)

  • Chung, Seung-Hee;Lee, Jung-Hoon;Shim, Jae-Jin;Kim, Jae-Seong;Kim, Sunwook
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.709-714
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    • 2002
  • To investigate the decomposition kinetics of poly(ethylene terephthalate) the high pressure molten-polymer injector has been devised. Using the experimental apparatus equipped with batch reactor and high pressure molten-polymer injector the decomposition of PET has been performed at constant pressure of 250 bar and 300, 320, $340^{\circ}C$, respectively. At each temperature conditions the conversions after initial 1 minute have shown very high values such as 76-90%. As the temperature increases the conversion reaches more than 98% at 10 minutes. Based on the second order reaction model the reaction rate constants have been obtained. We can calculate the conversions within 2% errors utilizing optimized rate constants. The activation energy for the decomposition of PET at subcritical conditions has shown to be 54.4 kJ/mol.