• Title/Summary/Keyword: 초기 공극 결함

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Changes of Physicochemical Properties of Paper Mill Sludge and Sewage Sludge Mixed with Various Ratios of a Bulking Agent During Composting (공극개선재의 혼합비율에 따른 제지·하수슬러지의 퇴비화과정중 이화학성 변화)

  • Yu, Young-Suk;Chang, Ki-Woon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.2
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    • pp.45-57
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    • 1998
  • The object of this experiment was to determine the optimum mixing ratio of paper mill sludge and sewage sludge with woodchips as a bulking agent. The bulking agent was mixed with the mixture of paper mill sludge and sewage sludge(2:1 by dried weight) at the rates of 0(W-0), 20(W-20), 33(W-33), and 50(W-50)% on volume basis, and then the mixtures were composted by forced aerated static pile. The changes of physicochemical properties of the mixtures were measured during the composting in order to evaluate the maturity of composts. The temperatures of W-30 and W-50 treatments increased rapidly as soon as the composting started, and reached $60^{\circ}C$ in the fifth day of composting. Reduction of hot water soluble C/N ratio of W-33 and W-50 treatments showed faster than that of W-0 and W-20 treatments at early stage of the composting. The contents of hot water soluble $NO_3{^-}-N$ showed little change in the early stage of the composting in all treatments, but increased rapidly after 20 days of the composting, and the contents of W-0 among all treatments were lower than the others. The G.I. values of W-50 treatment were over 80 before 20 days after starting the composting, those of W-0 treatment were over 80 after 30 days. As a result of evaluation of compost, W-33 and W-50 treatments were found very reasonable at the mixing ratio of a bulking agent. But it is very difficult to aerate compost pile for W-50 treatment than W-33 treatment due to intensified fluctuation of temperature. Considering cost, availability of a bulking agent, and productivity of compost, W-33 treatments more efficient than W-50 treatment.

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Coupled T-H-M Processes Calculations in KENTEX Facility Used for Validation Test of a HLW Disposal System (고준위 방사성 폐기물 처분 시스템 실증 실험용 KENTEX 장치에서의 열-수리-역학 연동현상 해석)

  • Park Jeong-Hwa;Lee Jae-Owan;Kwon Sang-Ki;Cho Won-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.2
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    • pp.117-131
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    • 2006
  • A coupled T-H-M(Thermo-Hydro-Mechanical) analysis was carried out for KENTEX (KAERI Engineering-scale T-H-M Experiment for Engineered Barrier System), which is a facility for validating the coupled T-H-M behavior in the engineered barrier system of the Korean reference HLW(high-level waste) disposal system. The changes of temperature, water saturation, and stress were estimated based on the coupled T-H-M analysis, and the influence of the types of mechanical constitutive material laws was investigated by using elastic model, poroelastic model, and poroelastic-plastic model. The analysis was done using ABAQUS, which is a commercial finite element code for general purposes. From the analysis, it was observed that the temperature in the bentonite increased sharply for a couple of days after heating the heater and then slowly increased to a constant value. The temperatures at all locations were nearly at a steady state after about 37.5 days. In the steady state, the temperature was maintained at $90^{\circ}C$ at the interface between the heater and the bentonite and at about $70^{\circ}C$ at the interface between the bentonite and the confining cylinder. The variation of the water saturation with time in bentonite was almost same independent of the material laws used in the coupled T-H-M processes. By comparing the saturation change of T-H-M and that of H-M(Hydro-Mechanical) processes using elastic and poroelastic material mod31 respectively, it was found that the degree of saturation near the heater from T-H-M calculation was higher than that from the coupled H-M calculation mainly because of the thermal flux, which seemed to speed up the saturation. The stresses in three cases with different material laws were increased with time. By comparing the stress change in H-M calculation using poroelasetic and poroelasetic-plastic model, it was possible to conclude that the influence of saturation on the stress change is higher than the influence of temperature. It is, therefore, recommended to use a material law, which can model the elastic-plastic behavior of buffer, since the coupled T-H-M processes in buffer is affected by the variation of void ratio, thermal expansion, as well as swelling pressure.

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A Study on Change in Cement Mortar Characteristics under Carbonation Based on Tests for Hydration and Porosity (수화물 및 공극률 관측 실험을 통한 시멘트모르타르의 탄산화 특성 변화에 대한 연구)

  • Kwon, Seung-Jun;Song, Ha-Won;Park, Sang-Soon
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.613-621
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    • 2007
  • Due to the increasing significance of durability, much researches on carbonation, one of the major deterioration phenomena are carried out. However, conventional researches based on fully hardened concrete are focused on prediction of carbonation depth and they sometimes cause errors. In contrast with steel members, behaviors in early-aged concrete such as porosity and hydrates (calcium hydroxide) are very important and may be changed under carbonation process. Because transportation of deteriorating factors is mainly dependent on porosity and saturation, it is desirable to consider these changes in behaviors in early-aged concrete under carbonation for reasonable analysis of durability in long term exposure or combined deterioration. As for porosity, unless the decrease in $CO_2$ diffusion due to change in porosity is considered, the results from the prediction is overestimated. The carbonation depth and characteristics of pore water are mainly determined by amount of calcium hydroxide, and bound chloride content in carbonated concrete is also affected. So Analysis based on test for hydration and porosity is recently carried out for evaluation of carbonation characteristics. In this study, changes in porosity and hydrate $(Ca(OH)_2)$ under carbonation process are performed through the tests. Mercury Intrusion Porosimetry (MIP) for changed porosity, Thermogravimetric Analysis (TGA) for amount of $(Ca(OH)_2)$ are carried out respectively and analysis technique for porosity and hydrates under carbonation is developed utilizing modeling for behavior in early-aged concrete such as multi component hydration heat model (MCHHM) and micro pore structure formation model (MPSFM). The results from developed technique is in reasonable agreement with experimental data, respectively and they are evaluated to be used for analysis of chloride behavior in carbonated concrete.

Variation of Physical and Microstructural Properties of Limestone caused by Artificial Freezing and Thawing (인공 동결-융해 풍화에 따른 석회암의 물성 및 미세구조 변화 분석)

  • Park, Jihwan;Park, Hyeong-Dong
    • Tunnel and Underground Space
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    • v.25 no.5
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    • pp.435-449
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    • 2015
  • Physical and microstructural properties of Pungchon and Maggol limestone were investigated quantitatively during 50 cycles of artificial freezing and thawing test. There were decrease in dry weight and P,S-wave velocity, and increase in absorption rate in both rock types. Porosity, pore volume, equivalent diameter, throat thickness and pore orientation were analyzed using X-ray computed tomography images. Porosity increased, and initiation and expansion of pores were investigated as weathering progresses. Physical and microstructural variation in Maggol limestone was larger than that of Pungchon limestone because Maggol limestone has more pores and microcracks at initial state. As this study analyzes physical and microstructural properties of rock specimens comprehensively, it can be applied to further rock weathering study and can be used as fundamental data of construction and resource development in cold regions.

Modeling on Ultrasonic Velocity in Concrete Considering Micro Pore Structure and Loading Conditions (공극구조 및 하중조건에 따른 콘크리트의 초음파 속도 모델링)

  • Kim, Yun Yong;Oh, Kwang-Chin;Park, Ki-Tae;Kwon, Seung-Jun
    • The Journal of the Korea Contents Association
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    • v.15 no.3
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    • pp.415-426
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    • 2015
  • For a long time, evaluation of soundness and strength in concrete has been performed through ultrasonic velocity(UV), which is essential work in field assessment. Porosity in concrete is a major parameter indicating durability and strength, and UV passing concrete depends on porosity variation. In this paper, a modeling on UV through concrete is carried out considering porosity and the results are verified with those from test. Additionally UV in concrete under compression/tension loading condition is measured and UV modeling with loading condition is performed. Up to 50% of loading ratio, UV slightly increases and greatly drops at peak load in compression region, however it fluctuates in tensile region due to micro cracking in matrix. The proposed model shows a reasonable agreement with test results in control and compression region, and needs modification for tensile region considering micro cracks and local aggregate interlocking.

Effect of Fractionated Organic Matter on Membrane Fouling (분류된 천연유기물질을 이용한 막 오염 특성 평가)

  • Lee, Byung-Gu;Son, Hee-Jong;Roh, Jae-Soon;Hwang, Young-Do;Jung, Chul-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1321-1326
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    • 2005
  • As a results of this research, the Nakdong River consisted of 43% of hydrophobic fraction, 39% of hydrophilic fraction, and 18% of transphilic fraction. The hydrophobic fraction in this raw water was mostly fulvic acid. Fulvic acid comprised of 62% and the rest was humic acid(38%). There was more carboxylic acid functional roup(64%) than phenolic group(36%). HPI-N and HPI-C comprised of 17% and 22% in the hydrophilic portion, respectively. The results of the membrane fouling test using UF membrane according to NOM fractions. HPI-N caused more fouling than HPI-C. Humic acid caused more fouling than fulvic acid probably due to higher adsorption capacity. Since humic acid has higher adsorption capacity than fulvic acid, it would be more adsorbed onto the membrane pores. The carboxylic acid functional group caused more fouling than the phenolic group.

Weathering of Rock Specimens Exposed to Recurrent Freezing and Thawing Cycles (동결-융해 풍화에 의한 암석 물성 변화 양상과 추정에 관한 연구)

  • Ryu, Sung-Hoon;Song, Jae-Joon
    • Tunnel and Underground Space
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    • v.22 no.4
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    • pp.276-283
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    • 2012
  • Changes in rock properties due to freezing and thawing cycles ranging from $-20^{\circ}C$ to $10^{\circ}C$ were checked for the typical Korean rocks: granite (weathered), limestone, sandstone, tuff, shale and basalt. The porosity, seismic velocity, shore hardness and specific gravity were measured every 10 cycles for each type of rock up to 40 cycles. The specific gravity was rarely changed. Granite (w), shale and basalt decreased gradually in their shore hardness and seismic velocity values, these values for limestone, sandstone and tuff changed only a very little. The porosity increased in the granite (w), shale and basalt, whereas in the others it did not change. Due to the low tensile strength with high porosity, granite (w), shale and basalt were susceptible to the F-T cycles. A linear regression equation was calculated based on the experiment results according to properties and types of rock. The relationship between the freeze-thaw sensitivity (=initial porosity/initial tensile strength) and the coefficients of the regression equation was examined. With additional experimental data, the coefficients of the regression equation can be estimated using the F-T sensitivity. This makes it possible to predict the properties of rock as affected by freeze-thaw weathering by only measuring the initial properties without knowledge of the regression equation coefficients for each type of rock.

Effect of Gelatin Particles on Cell Proliferation in Polymer Scaffolds Made Using Particulate Leaching Technique. (Particulate Leaching 기법을 사용한 Polymer Scaffold 상의 세포증식에 있어서 젤라틴 입자의 효과)

  • 서수원;신지연;김진훈;김진국;길광현
    • Journal of Biomedical Engineering Research
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    • v.25 no.1
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    • pp.1-4
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    • 2004
  • On the background of general idea and technique of bioscience, medicine and engineering, tissue engineering aim at maintenance, improvement and repair of human body function through manufacturing and transplantation of artificial tissue and organ exchangeable human body. Basic material used in the area is scaffold that aid tissue and organ formation. Making scaffold, solvent-casting and particulate leaching technique is widely used in manufacturing of porous polymer scaffold. There are many types of particle including salt and gelatin. Salt is a most commonly used particulate because it is easily available and very easy to handle and gelatin particle is another candidate for this method because it is known as a material, which enhances cell attachment and proliferation. But there is no comparative study of two kinds of materials. In this study we compared the biocompatibility of the two scaffolds made from salt(salt scaffold) and gelatin particle (gelatin scaffold). These results demonstrated that gelatin scaffold showed better attachment of cells at the initial stage and better proliferation of cells. The better performance of gelatin scaffold is contributed to the better connection of pores in the same porosity.

Prediction for Pore Structure of Cement Mortar Exposed to Freezing-Thawing Action by Ultrasonic Pulse Velocity Measurement (초음파 속도 측정을 통한 동결·융해 작용을 받는 시멘트 모르타르의 공극 구조 예측)

  • Pang, Gi-Sung;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.421-426
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    • 2017
  • In this paper, the effect of freezing-thawing action on the dynamic modulus and porosity was examined by ultrasonic pulse velocity (UPV) measurement. UPV was measured every 30 cycles during the freezing-thawing test, and dynamic modulus and porosity of cement mortar were calculated by relationship among UPV, porosity and dynamic modulus. Porosity analysis was also performed to compare with calculated porosity by mercury intrusion porosimetry (MIP). From the test, it was found that dynamic modulus of cement mortar was decreased 13% after 300 cycles. The calculated porosity was increased about 30% compared with the initial porosity before freezing-thawing action. The calculated porosity showed similar increase tendency with the porosity measured by MIP. So, it can be concluded that the porosity change of cementitious materials by freezing-thawing action can be predicted by UPV measurement.

Hydration Properties of Cement Matrix using Electrolysis Alkaline Aqueous and Ground Granulated Blast Furnace Slag (전기분해 알칼리 수 및 고로슬래그 미분말 혼입 시멘트 경화체의 수화 특성)

  • Jung, Yoong-Hoon;Kim, Ho-Jin;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.185-190
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    • 2021
  • Cement has been used as a main material in the modern construction industry. However, it has been pointed out as a main cause of global warming due to carbon dioxide generated during manufactured. Recently, research that replacing cement substitute to industrial by-products such as Blast Furnace Slag which is by-producted in steelworks. When Blast Furnace Slag is used as a cement substitute, it shows a problem of lower initial strength, which is caused by glassy membrane on the particle surface. In this study, we used Electrolysis Alkaline Aqueous to improve the usability and problem of lower initial strength. As a result of the experiment, cement matrix using Blast Furnace Slag and Alkaline Aqueous showed initial strength and hydrate product were developed than that using general mixing water. Also, as a result of porosity analysis, It was confirmed that cement matrix using Alkaline Aqueous and Blast Furnace Slag has a tighter structure in internal porosity and porosity distribution than using general mixing water.