• Title/Summary/Keyword: 초기소재

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A study on the functional coatings using silicone resin of Architectural membrane structures products (건축용 막구조 제품의 실리콘 기능성 코팅에 관한 연구)

  • Choi, Yun-Sung;Lee, Jang-Hun;Yoon, Nam-Sik;Kim, Su-Hong;Yoo, Gu-Geun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.106-106
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    • 2012
  • 막구조(Membrane structure)란 건축분야에서 "fabric structure" 또는 tension structure"와 같이 사용되는 용어로 코팅된 직물(coated fabrics)을 주재료로 사용하는 구조를 말한다. 특히 구조체로서 연성의 막을 이용 이것에 초기 장력을 주어 강성을 늘림으로서 외부하중에 대하여 안정된 형태를 유지하는 장점을 갖고 있다. 초기 창안된 독일의 온화한 기후에 적용되는 반면 한국이나 일본에는 60m/sec를 넘나드는 태풍의 피해와 많은 적설량을 보이는 기후적 제약으로 발달되지 못하였다. 그러나 최근 새로운 소재의 막구조 제품 개발과 구조해석 방법 및 시공기술 등이 개발되어 보편화되어지고 있는 실정이다. 막구조용 재료로 사용되는 섬유소재는 주로 Polyester직물을 기재로 한 PVC 코팅 제품으로 일반 PVC 막재는 장력이 약하고, 광선에 의한 물성이 쉽게 변화되어 내구연한이 5~15년에 불과하다. 유리섬유나 아라미드섬유 등으로 제직한 기재에 고내열 실리콘이나 PTFE 수지를 코팅한 제품은 약품에 대한 내구성이 높고 자외선에 대해서는 매우 큰 저항성을 가지기 때문에 내구연한이 10년에서 30년 까지도 향상된다. 그러나 실리콘 코팅막은 세계적으로 가장 좋은 막재로 알려졌으나 자정능력(Self Cleaning)에 문제가 발생되어 사용량이 감소 추세라고 할 수 있다. 일반적인 코팅 가공의 경우 MEK, Toluene, DMF 등과 같은 유기용제를 다량 사용함에 따라 작업환경 및 대기오염, 화재 위험 등의 문제점이 있으며 특히 가공시 잔류되는 유기용제의 심각성이 대두되고 있는 상황이다. 이와 같이 코팅 가공제 자체를 친환경적인 물질로 대체하여 각종 환경규제에 대응하고 유해 폐기물의 발생을 줄일 수 있는 코팅 가공제 및 가공기술 개발이 절실하다. 이에 본 연구에서는 Glass-Fiber, Aramid 등의 슈퍼 섬유와 고 강력 섬유 등을 이용하여 PTFE 코팅제품과 비슷한 수준의 성능을 부여하는 무용제형 실리콘 코팅 수지를 개발하고 내구성능 향상, Self Cleaning성, 난연성, 자외선 차단, 인장강도 및 인열 강도의 향상 등 다양한 기능성을 부여하는 최적의 환경 친화적 코팅 공정 기술을 개발하여 차세대 건축용 막구조 제품을 개발하고자 한다.

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Study on Weight Reduction of Urban Transit Carbody Based on Material Changes and Structural Optimization (도시철도차량 차체의 경량화를 위한 소재 변경 및 구조체 최적화 연구)

  • Cho, Jeong Gil;Koo, Jeong Seo;Jung, Hyun Seung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.9
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    • pp.1099-1107
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    • 2013
  • This study proposes a weight reduction design for urban transit, specifically, a Korean EMU carbody made of aluminum extrusion profiles, according to size optimization and useful material changes. First, the thickness of the under-frame, side-panels, and end-panels were optimized by the size optimization process, and then, the weight of the Korean EMU carbody could be reduced to approximately 14.8%. Second, the under-frame of the optimized carbody was substituted with a frame-type structure made of SMA 570, and then, the weight of the hybrid-type carbody was 3.8% lighter than that of the initial K-EMU. Finally, the under-frame and the roof-panel were substituted with a composite material sandwich to obtain an ultralight hybrid-type carbody. The weight of the ultralight hybrid-type carbody was 30% lighter than that of the initial K-EMU. All the resulting carbody models satisfied the design regulations of the domestic Performance Test Standard for Electrical Multiple Unit.

Electrochemical Behavior of Si/Cu/Graphite Composite Anode for Lithium Secondary Battery (리튬이차전지용 Si/Cu/Graphite 복합체 음극의 전기화학적 거동)

  • Kim, Hyung-Sun;Chung, Kyung-Yoon;Cho, Won-Il;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.12 no.2
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    • pp.162-166
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    • 2009
  • The carbon-coated Si/Cu powders were synthesized by mechanical ball-milling and hydrocarbon gas decomposition methods at high temperature. The carbon-coated Si/Cu powder was used as anode for lithium secondary battery and its electrochemical behavior was investigated. In addition, the carbon-coated Si/Cu/graphite composite anode material was prepared using natural graphite powder and their electrochemical characteristics were compared with natural graphite anode. The specific capacity of carbon-coated Si/Cu anode increased to the initial 10 cycles. The carbon-coated Si/Cu/graphite composite anode exhibited the reversible specific capacity of 450mAh/g and the first cycle efficiency of 81.3% at $0.25mA/cm^2$. The cycling performance of the composite anode was similar to that of pure graphite anode except the reversible specific capacity value.

Finite Element Based Edge Crack Analysis of Silicon-Steel Sheet in Cold Rolling (실리콘 강판 압연시 에지크랙 발생에 관한 유한요소해석)

  • Byon, Sang-Min;Lee, Jae-Hyun;Kim, Sang-Rok;Jang, Yun-Chan;Na, Doo-Hyun;Lee, Jong-Bin;Lee, Gyu-Taek;Song, Gil-Ho;Lee, Sung-Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.6
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    • pp.511-517
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    • 2009
  • In this paper an finite element approach for the edge crack analysis of silicon-steel sheet during cold rolling is presented. Based on the damage mechanics, the proposed approach follows the analysis steps which are composed of damage initiation, damage evolution and fracture. Through those steps, we can find out the initiation instant of crack and resulting propagated length and shape of the crack. The material constants related to fracture is experimentally obtained by tension tests using standard sheet-type specimen and notched sheet-type specimen. To evaluate the prediction accuracy, we performed a pilot rolling test with a initially notched sheets. It is shown that the results obtained by the approach converged to the experimental one concerning about the direction and length of propagated crack. The capability of the proposed one is demonstrated through the application to the actual silicon-steel rolling mill.

Electrochemical Characteristics of Artificial Graphite Anode Coated with Petroleum Pitch treated by Solvent (용매 처리 석유계 피치로 코팅된 인조 흑연 음극소재의 전기화학적 특성)

  • Jo, Yoon Ji;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.5-10
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    • 2019
  • In this study, electrochemical characteristics of artificial graphite coated with petroleum pitch using solvent method as anode material of lithium ion battery were investigated. As the solvent, n-hexane, toluene, tetrahydrofuran and quinoline were used. The surface of the prepared anode material was analyzed by SEM and TEM. Also the electrochemical performances of the prepared anode materials were performed by constant current first charge/discharge, cycle, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DEC=1:1 vol%). The coating thickness of the prepared graphite was about 100-500 nm and the graphite coated with THF solvent had a smoother surface than that using other solvents. It was found that pitch-coated graphite (THF) show the low initial irreversible capacity (51 mAh/g), the high discharge capacity (360 mAh/g) and coulombic efficiency (99%).

A Study on Mineral Carbonation of Chlorine Bypass Dust with and without Water Washing (수세 유무에 따른 염소 바이패스 분진의 광물 탄산화 연구)

  • Hye-Jin Yu;Woo Sung Yum
    • Resources Recycling
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    • v.32 no.6
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    • pp.18-24
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    • 2023
  • This study undertook initial investigations into the carbonation of chlorine bypass dust, aiming to apply it as a raw material for cement and as an admixture for concrete. Various experimental methods, including XRD(X-ray diffraction), XRF(X-ray fluorescence), and particle size distribution analyses, were employed to verify the physical and chemical properties of chlorine bypass dust, with and without water washing. The mineral carbonation extent of chlorine bypass dust was examined by considering the dust type, stirring temperature, and experiment duration. Notably, a higher degree of mineral carbonation was observed in water-washed bypass dust than its non-water-washed counterpart, indicating an elevated calcium content in the former. Furthermore, an augmented stirring temperature positively impacted the initial stages of mineral carbonation. However, divergent outcomes were observed over time, contingent upon the specific characteristics of dust types under consideration.

Effect of Dietary Anti-oxidant Supplementation on Telomere Length and Egg Quality in Laying Hens (산란계에 항산화물질 급여가 텔로미어 함량 및 난질에 미치는 영향)

  • Lee, M.H.;Lee, S.H.;Kim, Y.J.;Ko, Y.H.;Jang, I.S.;Moon, Y.S.;Choi, Y.H.;Sohn, S.H.
    • Korean Journal of Poultry Science
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    • v.35 no.3
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    • pp.267-274
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    • 2008
  • There are many kinds of anti-oxidant materials in natural plant resources. The Siberian ginseng and Eucommia are well known as anti-oxidant and medicinal plants. To investigate the effect of their anti-oxidant-like activity on telomere quantity and egg quality, diets containing Siberian ginseng leaf and Eucommia leaf at 0.5% and 1% were given Hyline Brown commercial laying hens during two periods of age: 20 to 30 wks and 60 to 70 wks. The amount of telomere in lymphocyte, liver, ovary, heart and lung was analyzed by quantitative fluorescence in situ hybridization using telomeric DNA probe. Egg weight, albumin height, Haugh unit, egg yolk color, egg shell color, egg shell thickness, egg shell weight and egg shell density were measured to analyze egg quality. The chickens consuming diets Siberian ginseng and Eucommia had higher telomeric DNA in lymphocytes than control chickens in younger layers whereas no significant differences were detected in all target cells analyzed from older layers. Egg quality was increased in younger hens with dietary supplementation as determined by egg weight, albumin height and Haugh unit but there were no effects in older hens. These results imply that dietary supplementation of Siberian ginseng and Eucommia in layers improves bio-activity and egg quality at early laying stage.

Electrochemical Performance of Graphite/Silicon/Pitch Anode Composites Bonded with Graphite Surface PVP and Silica Amine Function Group (흑연 표면의 PVP와 실리카의 아민 작용기로 결합된 흑연/실리콘/피치 음극 복합소재의 전기화학적 성능)

  • Lee, Su Hyeon;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.118-123
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    • 2019
  • In this study, the electrochemical characteristics of Graphite/Silicon/Pitch anode composites were analyzed to improve the low theoretical capacity of graphite as a lithium ion battery. The Graphite/Silica composites were synthesized by bonding silica onto polyvinylpyrrolidone coated graphite. The surface of used silica was treated with (3-Aminopropyl)triethoxysilane(APTES). Graphite/Silicon/Pitch composites were prepared by carbonization of petroleum pitch, the fabrication processes including the magnesiothermic reduction of nano silica to obtain silicon and varying the mass ratio of silica. The Graphite/Silicon/Pitch composites were analysed by XRD, SEM and XRD. Also the electrochemical performances of Graphite/Silicon/Pitch composite as the anode of lithium ion battery were investigated by constant current charge/discharge, rate performance, cyclic voltammetry and electrochemical impedance tests in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC:DMC:EMC=1:1:1 vol%). The Graphite/Silicon/Pitch anode composite (silica 28.5 in weight) has better capacity (537 mAh/g). The cycle performance has an excellent capacity retention to 30th cycle of 95% and the retention rate capability of 98% in 0.1 C/0.2 C.

The effect of silica composite properties on DLP-stereolithography based 3D printing (실리카 복합소재의 물성에 따른 DLP 3D printing 적용 연구)

  • Lee, Jin-Wook;Nahm, Sahn;Hwang, Kwang-Taek;Kim, Jin-Ho;Kim, Ung-Soo;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.2
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    • pp.54-60
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    • 2019
  • Recently, various composite materials for additive manufacturing are interested to expand the application field of 3D printing. 3D printing technique was mainly developed using polymer, and ceramic materials for 3D printing are still in the early stage of research due to the requirement of high solid content and post treatment process. In this study, silica particles with various diameters were surface treated with silane coupling agent, and synthesized as silica composite with photopolymer to apply DLP 3D printing process. DLP is an additive manufacturing technology, which has high accuracy and applicability of various composite materials. The rheological behavior of silica composite was analyzed with various solid contents. After DLP 3D printing was performed using silica composites, the printing accuracy of the 3D printed specimen was less than about 3 % to compare with digital data and he bending strength was 34.3 MPa at the solid content of 80 wt%.

Electrochemical Performance of Pitch coated Nano Silicon Sheets / Graphite Composite as Anode Material (피치로 코팅된 Nano Silicon Sheets/Graphite 음극복합소재의 전기화학적 특성)

  • Lee, Tae Heon;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.487-492
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    • 2021
  • In this study, the electrochemical properties of pitch coated silicon sheets/graphite anode materials were investigated. Using NaCl as a template, silicon sheets were prepared through the stöber method and the magnesiothermic reduction methode. In order to synthesize the anode composite, the silicon sheets and graphite were combined with SDBS. The pitch coated silicon sheets/graphite was synthesized using THF as a solvent for the anode material composite. The physical properties of the prepared anode composites were analysed by XRD, SEM, EDS and TGA. The electrochemical performances of the prepared anode composites were performed by the current charge/discharge, rate performance, cyclic voltammetry and EIS tests in the electrolyte LiPF6 dissolved solvents (EC:DMC:EMC=1:1:1 vol%). As the silicon composition of silicon sheets/graphite composite material increased, the discharge capacity also increased, but the cycle stability tended to decrease. The anode material of pitch coated silicon sheets/graphite composite (silicon sheets:graphite=3:7 weight ratio) showed the initial discharge capacity of 1228.8 mAh/g and the capacity retention ratio of 77% after 50 cycles. From these results, it was found that the cycle stability of pitch coated silicon sheets/graphite was improved.