• Transactions of the Korean hydrogen and new energy society
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• v.17 no.3
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• pp.347-352
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• 2006

분자전해질연료전지 내의 다공성 기체확산층은 반응가스의 확산과 전자이동통로의 역할을 수행할 뿐만 아니라 전기화학반응에 의해 공기극에서 생성된 수분(기상 혹은 액상)을 반응면으로부터 분리판 채널 방향으로 이동시켜 배출시키는 중요한 역할을 한다. 따라서 물관리를 통한 성능향상을 위해서는 기체 확산층의 구조 및 재료특성에 대한 심도 릴은 연구가 필요하다. 실제 단위전지 체결시 기체확산층은 분리판의 리브(rib)에 의해 눌리게 되며, 그 부분의 기공 크기 분포의 변화를 야기한다. 또한 리브 전단부분에서 탄소 섬유가 손상을 입으며, 탄소 섬유를 감싸고 있는 PTFE coating이 벗겨지게 되어 표면화학적 특성이 달라진다. 본 연구에서는 단위전지 체결 시 분리판에 의해 눌리는 기체확산층의 기공 크기 분포 변화를 측정하였으며, 기공의 소수성에서 친수성으로의 변화를 알아보았다. Mercury 기공 측정기와 PMI 기공 측정기는 큰 기공 분포의 변화에, 질소의 흡/탈착을 이용한 BET 방식은 작은 크기의 기공 분포 변화 관찰에 사용되었다. 체결압에 의한 탄소섬유의 구조적 변화와 아울러 표면의 습윤 정도의 변화를 XPS와 물/알콜 Uptake를 이용해 알아보았다. 이 연구를 바탕으로 물관리를 통한 연료전지 성능 향상을 위한 최적 GDL 선정에 기반이 되는 자료를 도출하였다.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.1-6
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• 2024

As the demand for hydrogen electric vehicles for commercial vehicles increases, the durability of PEMFCs must increase more than five times that of passenger cars, so research and development to improve durability is urgent. When the PEMFC membrane electrode assembly (MEA) undergoes chemical degradation, the MEA thickness decreases and pinholes occur. In this study, changes in the performance and durability of the MEA were measured while increasing the clamping pressure of the unit cell after open circuit voltage (OCV) holding, an accelerated chemical degradation experiment. As the clamping pressure increased, the resistance of the polymer membrane and the membrane/electrode contact resistance decreased, improving the I-V performance and reducing the hydrogen permeability. As the hydrogen permeability decreased, the OCV increased. When the pinhole area was removed and the MEA clamping pressure was increased, the hydrogen permeability decreased sharply, confirming that the local degradation has a large effect on the performance and durability of the entire cell. When the pinhole was removed and re-clamping and OCV holding was evaluated, it was confirmed that the durability improved according to the decrease in membrane resistance and hydrogen permeability.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.11
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• pp.1009-1014
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• 2013

In the present study, using a variation of rib height, the transient response and the performance are investigated. The cell voltage is acquired according to the current density change($0.8A/cm^2$ to $1.0A/cm^2$) under same stoichiometry and relative humidity. The different level of undershoots appeared at the different clamping pressure(1.5MPa and 2.0MPa) and different rib height. At 1.5MPa clamping pressure, rib manufactured cut at $100{\mu}m$ height goes to steady state faster than reference plate and has lower maximum undershoot voltage. But performance is lower than reference plate due to increasing contact resistance.

• Journal of the Korean Electrochemical Society
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• v.10 no.4
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• pp.306-310
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• 2007

Characteristics of GDL (Gas Diffusion Layer) mainly determine the gas diffusion and water removal in a cell, thereby changing the performance and affecting durability of PEFC. To optimize the water management and understand the two phase flow in a GDL, it is important to study the behaviors of GDL micro structure under the real operating condition. In the clamped condition of cell, the GDL beneath the rib is more compressed than beneath the channel. Many researches on physical, electrochemical, mechanical behaviors of gas diffusion layer has been conducted. However, changes in surface properties under clamped condition have rarely studied. In present study, the morphology of broken connections of carbon fibers and detachment of PTFE coatings on the fibers were shown from the microscopic observations. In addition, changes in wetting properties of GDL by compression were investigated by using XPS and liquid uptake methods. The hydrophobic characteristics of GDL surface beneath the rib of the flow field plate are changed due to the deformation of micro structure.

• Composites Research
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• v.36 no.6
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• pp.422-428
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• 2023

The electrical contact resistance between the bipolar plate (BP) and the carbon felt electrode (CFE), which are in contact by the stack clamping pressure, has a great impact on the stack efficiency because of the relatively low clamping pressure of the vanadium redox flow battery (VRFB) stack. In this study, a polyethylene (PE) composite-CFE hybrid bipolar plate structure is developed through a local heat welding process to reduce such contact resistance and improve cell performance. The PE matrix of the carbon fiber composite BP is locally melted to create a direct contact structure between the carbon fibers of CFE and the carbon fibers of BP, thereby reducing the electrical contact resistance. Area specific resistance (ASR) and gas permeability are measured to evaluate the performance of the PE composite-CFE hybrid bipolar plate. In addition, an acid aging test is performed to measure stack reliability. Finally, a VFRB unit cell charge/discharge test is performed to compare and analyze the performance of the developed PE composite-CFE hybrid BP and the conventional BP.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.150-152
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• 2007

직렬로 연결 된 다층의 단위전지 집합으로 구성되는 고체 고분자 연료전지의 적층전지는 에서 발생 할 수 있는 단위전지 간 전압손실과 압력구배를 최소화하기 위해 적층전지 내의 단위전지 외에 부품 및 재료를 추가하여 전압손실과 압력구배를 줄이는 방법에 대한 연구를 진행하였다. 체결압 구배를 최소화하기 위해 부드러운 층으로 이루어진 외곽부분과 딱딱한 층으로 이루어진 중심부를 가지는 필름을 전류집합체 뒤쪽에 첨가하였고， 분리판과 전류집합체 사이에서 발생 할 수 있는 전압손실을 방지하기 위해 높은 전기 전도성을 가지며, 평활도를 유지 할 수 있는 재료로 구성 된 복합층을 전류집합체와 분리판 사이에 첨가하였다. 압력구배 측정 및 다층전지 성능테스트 중 단전지간 전압손실을 측정하여 기 제작 된 첨가층들에 대한 영향의 정도를 파악하였다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.21-25
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• 2017

The umbilical system used for launch vehicle is to connect all ground supply lines (Pneumatic, hydraulic and electrical) to launch vehicle and disconnect those at few second before launch vehicle lift-off (or simultaneously with launch vehicle lift-off). During launch preparation stage, all umbilical shall be securely connected and also at separation stage, separation of all umbilical line shall be guaranteed. Therefore finding an appropriate connection force is a key factor on development of umbilical system. According to these design requirement, various kind of umbilical system has been developed from early stage of space development till today. In this paper, various kind of umbilical system developed so far is introduced according to its feature and operational concept. Also, umbilical system used for KSLV-II is introduced

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.36 no.7
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• pp.642-650
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• 2008

In this paper, structural behavior of Gasket and GDL of a PEMFC stack is studied to improve the performance and to secure the safety. In the Gasket analysis Mooney-Rivlin strain energy function is used to consider hyperelasticity of load and displacement. The material properties is determined by testing specimens of the gasket at uni-axial and equi-biaxial mode and compared with finite element analysis results. By measuring a thickness change, the material property of GDL is determined. The pressure drop of a unit cell is measured along the channel for the clamping force. A cross sectional change of channel base on the experimental data is obtained experimentally and compare with FEM analysis results.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.40 no.12
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• pp.1063-1069
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• 2012

In present paper, we used magnesium alloy having a lower density and higher electrical conductivity for bipolar plate to reduce the weight of PEM fuel cell. The silver was coated to prevent corrosion and form passivation film on the metal surface with sputtering. In acid proof evaluation for setting optimal coating conditions, the homogeneity of coating thickness was improved by coating with the thickness of 3 ${\mu}m$ which not indicated any micro cracks and the temperature $180^{\circ}C$. The performance test and evaluation based on the clamping pressure and channel depth to determine the configuration of bipolar plate for assembling single cell was implemented. And then we assembled single cell with this bipolar plate and implemented the performance test to ensure and compare the current-voltage performance followed as several factors such as coating or non-coating, the change of clamping pressure, the change of channel depth, etc. As these results, the maximum power density of single cell with the coated bipolar plate was 192 $mW/cm^2$ and it was confirmed that the power density per unit mass was better than existing metal bipolar plate.

• Journal of the Korean Society for Railway
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• v.14 no.3
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• pp.240-247
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• 2011

Finite element analysis was undertaken to investigate the effect of freezing force of water unexpectedly penetrated into inserts used in railway sleeper on pullout capacity of anchor bolts for fixing base-plate onto concrete sleeper. Based on the in-situ investigation and measurement of geometry of railway sleeper and rail-fastener, the railway sleeper was modeled by 3D solid elements. Nonlinear and fracture properties for the finite element model were assumed according to CEB-FIP 1990 model code. And the pullout maximum load of anchor bolt obtained from the model developed was compared with experimental pullout maximum load presented by KRRI for verification of the model. Using this model, the effect of position of anchor bolt, amount of fastening force applied to the anchor bolt, and compressive strength of concrete on pull-out capacity of anchor bolts installed in railway sleeper was investigated. As a result, it is found that concrete railway sleepers could be damaged by the pressure due to freezing of water penetrated into inserts. And the pullout capacity of anchor bolt close to center of railway is slightly greater than that of the others.