• Journal of Energy Engineering
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• v.24 no.3
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• pp.150-163
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• 2015

Gasification technology is one of the representative next-generation fossil fuel utilization technologies, converting low grade fossil fuels such as coal, heavy residue oil, pet-coke into highly clean and efficient energy sources. Accordingly, related market demand for gasification technology is ever increasing steadily and rapidly. A few years ago, conventional pulverized coal utilization technology had an edge over the gasification technology but the most significant technical barrier of limited capacity and availability has been largely overcome nowadays. Futhermore, it will be more competitive in the future with the advancement of related technologies such as gas turbine, ion transfer membrane and so on. China has recently completed a commercialization-capable large-scale coal gasification technology for its domestic market expansion and foreign export, rapidly becoming a newcomer in the field and competing with existing US and EU technical leadership at comparable terms. Techno-economic aspect deserves intensive attention and steady R&D efforts need to continue in organized, considering that gasification technology is quite attractive combined with $CO_2$ capture process and coal to SNG plant is economically viable in Korea where natural gas is very expensive. In the present paper, recent technology development and commercialization trend of many leading companies with coal gasification expertise have been reviewed with significant portion of literature cited from the recently held '2014 Gasification Technology Conference'.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.106-106
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• 2011

소수력은 온실가스 배출량이 적은 친환경 청정에너지원이면서 지역의 분산전원에 기여할 수 있는 유용한 자원으로 평가되고 있다. 이러한 여건은 소수력발전 사업이 전력의 smart grid 구축 효과로 인해 가장 큰 효율성을 달성할 수 있을 것으로 기대된다. 국내 소수력발전은 1500Mw의 부존량을 가진 것으로 평가되고 있으나 계절적 편중으로 인한 가동률 부족, 경제성 부족 등으로 활발한 보급이 이루어지지 않고 있다. 특히 신재생에너지 확대 전략에도 불구하고 지원금 등 경제적 인센티브 부족으로 인해 민간부문의 참여는 상당히 저조하다. 그럼에도 불구하고 수력에너지는 환경친화적이고 잠재성이 큰 신재생에너지로 온실가스 저감과 에너지 확보에 기여할 수 있다. 특히 수력에너지는 민간투자의 어려움이 존재하므로 정부의 장기적인 기술개발투자 및 효율성 확대 정책이 중요하다. 본 연구에서는 소수력 확대의 경제 환경적 효과를 평가해보기 위해 연산일반균형모형 (CGE :Computable General Equilibrium Model)을 구축한다. 본 연구는 다음과 같이 수행되었다. 첫째, 수력발전부문과 수도사업을 구분하고 사회회계행렬을 작성하였으며, 전력부문에서 수력발전을 포함한 다단계 생산구조를 가정하였다. 둘째, 일반균형모형 방정식 체계를 작성하고 모형의 파라미터 추정 등 보정(Calibration) 작업을 수행하였다. 셋째, 국가 중기 온실가스저감 시나리오를 적용한 전망을 수행하고 소수력 확대(투자지원) 시나리오를 구축한다. 본 연구는 저감수단으로 탄소세를 부과하였다. 끝으로, 소수력 발전 보급 확대의 경제적, 환경적 파급효과를 계산하였다. 분석결과, 소수력 발전 잠재 성장을 반영한 수력에너지 비중은 약 2020년에 약 4.5% 까지 증가하는 것으로 나타났다. 이로 인한 온실가스 저감 기여분은 약 3%에 이르는 것으로 계산 되었다. 또한 수도사업과 비에너지 제조업의 산업비중은 증가하였다. 이러한 결과는 소수력 발전 확대가 화석연료 대체를 통한 지속가능한 에너지 수요에 기여하고 지역개발과 물산업 발전 등 경제적 파급효과 등을 유발할 수 있음을 시사한다. 또한 본 연구에서 고려하지 못한 소수력 기술 개발은 에너지 대체 촉진으로 인한 온실가스 저감과 녹색성장에 기여할 것이다.

• Clean Technology
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• v.2 no.1
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• pp.53-59
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• 1996

For the development of biocatalysts and processes for microbial desulfurization of petroleum, more than 60 microbial strains capable of DBT(Dibenzothiophene) degradation were isolated from oil-polluted soils through 3 months of continuous and enrichment cultures. Among them, A23-3 strain could grow on DBT as the only sulfur source, while hexadecane was not utilized as a carbon source. The rate of desulfurization by A23-3 in a DBT-glucose medium was satisfactory. The addition of yeast extract or trace metal solution accelerated the rate of desulfurization about 4.5~6.5 times. In case of actual diesel oil treatment, the specific rate of DBT degradation was $0.045g-DBT\;per\;g-cell{\cdot}hour$. A number of aromatic compounds heavier than $C_{14}$ in diesel oil were also degraded by A23-3. A23-3 strain was evaluated as a good catalyst for the production of low-sulfur, low-aromatic clean diesel oil.

• Clean Technology
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• v.14 no.2
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• pp.71-86
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• 2008

In this review we discussed the effective ways to catalytically derive value-added chemicals from propane which has been utilized only as an energy source so far. Among various propane-derived products, the most valuable chemicals such as propylene and acrylonitrile were mainly focused herein. Propylene could be manufactured through oxidative dehydrogenation of propane using $O_2,\;CO_2$, etc. as an oxidant for the purpose of overcoming thermodynamic limitations of propane dehydrogenation. On the other hand, propane ammoxidation would be an alternative to propylene ammoxidation for producing acrylonitrile since propane is much cheaper than propylene as a starting material. Although effective $MoVTeNbO_x$ catalysts have been developed fur propane ammoxidation in recent years, more detailed studies should be thoroughly performed. In carrying out both oxidative dehydrogenation and ammoxidation of propane fur a long period, the most critical issue is definitely considered to find out the most active and selective catalysts, which makes it possible to commercialize both reactions into economically viable processes.

• Journal of the Korean Institute of Gas
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• v.20 no.3
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• pp.52-58
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• 2016

In this study, evaluation method for LNG plant FEED is suggested and its validity is confirmed using a well-known decision making technique of Analytic Hierarchy Process (AHP). It is a pairwise comparison technique which can be used when multiple options must be considered for a single decision making problem. In order to develop an objective decision methodology, various decision parameters, sub-parameters as well as the concept of scale of assessment were introduced, and its consistency among these parameters was also checked by calculating the consistency index (C.I.). The methodology suggested in this article will contribute in evaluation of LNG plant FEED with less bias and subjectivity associated with the decision making procedure.

• Environmental and Resource Economics Review
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• v.15 no.2
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• pp.355-386
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• 2006

This paper analyses recent regional development policies being carried out in Japan and the U.S. Such policies are formed on the sustainability principle aiming at the realization of circula-flow economy and zero waste society. The study here illuminates Japan's Eco-town project and three cases of eco-industrial developments in Minnesota. Such projects have gone from improving industry competitiveness through constructing clean production systems on the company level to improving national competitiveness through constructing a 'circular society' on the government level. Japan included the realization of a 'circular society' as its government's top agenda because it recognized that environmental pollution stems from the inefficient use of natural resources. Eco-town project is a regional development policy specifically reflecting such recognition. The eco-efficiency based city development approaches in Minnesota are but small examples of the new wave in regional development in the developed countries. We need to go beyond emphasizing eco-friendly and ethical management to just the companies. The government itself needs to design national policies based on environmental sustainability.

• Resources Recycling
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• v.21 no.4
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• pp.44-52
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• 2012

The purpose of this study is to confirm the possibility of obtaining high grade coal from fixed carbon 20.68% coal. Also, the mineralogical, physical/chemical and liberation characteristics was found with the aim of decrease in ash amount, during the pre-processing of clean coal technology. In this study, batch flotation and microbubble column flotation that was appropriate for the processing of fine particles was used with the variation in kinds and quantity of frother, collector and depressant. Also grinding time, air flow rate and feeding rates were examined. As a result of batch flotation, using pulp density 20%, collector DMU-101+dodecyl amine(100 mL/ton), frother pine oil (200 mL/ton), depressant sodium silicate(1 kg/ton), obtained the result of ash rejection 81.55% and combustible recovery 70.23%. In result of microbubble column flotation, the result was ash rejection 83.85% and combustible recovery 70.42% under the condition of pulp density 5%, grinding time 5 min. collector DMU-101+DDA(100 mL/ton), frother AF65(5.4 L/ton), depressant SMP(3.5 kg/ton), wash water(360 mL/min.) and air flow rate(1,197 mL/min.).

• Clean Technology
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• v.18 no.3
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• pp.287-294
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• 2012

In this study, performances of two cleaning methods were analyzed and a cleaning system was designed to develop a cleaning process of electronic components to remanufacture old laser copy machine. First, plasma cleaning as a dry cleaning method was executed to test cleaning ability. In cleaning of printed circuit board (PCB) by plasma, some damages were found near the metal parts, and considering the productivity, this method was not adequate for the cleaning of electronic components. With 4 different cleaning agents, ultrasonic cleaning tests were executed to select an optimal cleaning agent, aqueous agents showed superior cleaning performance compared to semi-aqueous and non-aqueous agents. Cleaning with aqueous cleaning agent A and 28 kHz ultrasonic frequency can be completed in 30 sec to 1 min. Finally, an ultrasonic cleaning system was constructed based on the pre-test results. Optimal cleaning conditions of 40 kHz and $50^{\circ}C$ were found in the field test. The productivity and economic efficiency in remanufacturing of laser copy machine are expected to increase by adapting developed ultrasonic cleaning system.

• Clean Technology
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• v.24 no.2
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• pp.99-104
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• 2018

In this work, we performed the methanation reaction using synthesis gas ($H_2/CO_2$) for the process to produce synthetic natural gas (SNG) for $4^{th}$ methanation reactor in SNG process proposed by RIST-IAE. Experimental conditions were changed with temperature, pressure and space velocity. At this time, $CO_2$ conversion, $CH_4$ selectivity and $H_2$ concentration after reaction were investigated. As a result, $CH_4$ selectivity by the $CO_2$ methanation increased with lower space velocity and higher pressure. On the other hand, in the case of temperature, the maximum value was shown at $320^{\circ}C$. From these results, it was found that the optimum condition of the fourth reactor suitable for the SNG process was obtained.

• Clean Technology
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• v.20 no.1
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• pp.57-63
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• 2014

In this work, we performed the methanation with steam and synthesis gas of a low $H_2/CO$ ratio to develop a process for producing SNG (synthetic natural gas). In this experiment conditions, the water gas shift reaction and the methanation reaction take place at the same time, and insufficient supply of steam might cause the deactivation of the catalyst. Therefore, the reaction characteristics with the amount of steam was performed, and the methanation on syngas containing $CO_2$ of the high concentration were studied. As a result, the temperature in the catalyst bed decreased by the supply of steam, and the methanation and the water gas shift reaction occurred at the same time. Although methane yield slightly decreased at the methanation using syngas containing $CO_2$ of the high concentration, the long-term operation (1,000 h) in the experimental conditions of this study indicates that this condition is suitable for the new commercial scale SNG process.