• Title/Summary/Keyword: 첨도

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Preparation of Hydrazine Impregnated Adsorbents and Selective Adsorption Properties for Carbonyl Compounds in Cigarette Mainstream Smoke (Hydrazine 첨착 흡착제의 제조 및 담배 주류연 중 카보닐 화합물의 선택 흡착 특성)

  • Lee, John-Tae;Park, Jin-Won;Lee, Jeong-Min;Rhee, Moon-Soo;Hwang, Keon-Joong;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.210-216
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    • 2006
  • To use the filter materials for selective removal of carbonyl compounds in cigarette mainstream smoke, hydrazine such as 2,4-dinitrophenylhydrazine (2,4-DNPH) and dansylhydrazine (DAH) impregnated adsorbents were prepared with perchloric acid or phosphoric acid as an accelerator in hydrazone formation reaction. Changes of molecular structure and morphology of adsorbents in various of impregnator were investigated by FTIR/ATR and SEM. Impregnation amount caused by reaction time, acid type and impregnation reagent, and the adsorption properties of carbonyl compounds in cigarette mainstream smoke were studied. Amounts of impregnation increased with increasing reaction time. The removal amount for vapor phase carbonyl compounds by 2,4-DNPH impregnated adsorbent was higher than that of dansylhydrazine impregnated adsorbent. The selectivity of 2,4-DNPH impregnated polyacrylic type adsorbent was superior to those of other adsorbents. This result indicates that the 2,4-DNPH impregnated polyacrylic adsorbent is applicable to cigarette filter material because of its fast reactivity and porosity.

Time-series Analysis of Precision the Domestic Boring Investigation Data (국내 시추조사 자료 정밀도 시계열 분석)

  • Jang, Yonggu;Kim, Youngsun;Chae, Deokho;Cho, Wanjei
    • Journal of the Korean GEO-environmental Society
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    • v.16 no.3
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    • pp.15-21
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    • 2015
  • Since the introduction of 'the rule for computerizing subsoil investigation results and its application' in 2007, the DB construction of the national geotechnical information by Ministry of Land, Transport and Maritime Affairs (MOLTMA) has been performed. According to the Integrated DB Center of National Geotechnical Information, there have been 180 thousands borehole information stored in the system. In this study, the time-series analyses of precision on the most used information, the depth of stratum and ground water level, were performed to evaluate the effect of the initiation of the rule established in 2007. The precisions were evaluated based on the statistical analyses using kurtosis and normal distribution. Based on the results, the increase of precision after 2007 and the affirmative effects of the rule established in 2007 are confirmed. Furthermore, the precision of the regional information can be achieved with the precision analyses on the information from various areas.

Entrainer-Enhanced Semi-Batch Reactive Distillation for Synthesis of Butyl Acetate (부틸 아세테이트 합성을 위한 공비첨가제 사용 반회분식 반응증류)

  • Yang, Jeongin;Jeon, Hyeongcheol;Han, Myungwan
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.341-352
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    • 2017
  • Butyl acetate is produced from acetic acid and butanol via an esterification reaction in a reactive distillation column. Entrainer can be used for efficient removal of produced water from the reaction region, leading to significant improvement of the column performance. Batch reactive distillation has clear advantages over continuous one in terms of flexibility and adaptability in a small plant. We studied batch and semi-batch reactive distillation processes through process simulation and pilot-scale experiments. We investigated process configuration and type of entrainer for improvement of the column performance and suggested a novel cyclic operation strategy using the semi-batch reactive distillation column. The cyclic strategy was shown to give relatively high production rate and stable operation.

Modification of Surface Flow Analysis Algorithm in SWAT (SWAT 모형의 지표유출해석 알고리즘 개선)

  • Lee, Jeongwoo;Kim, Nam Won;Lee, Jeong Eun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.3
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    • pp.417-426
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    • 2016
  • SWAT model usually underestimates daily peak discharges. To resolve this problem, in this study, the algorithm related with the surface flow simulation was modified by partitioning excessive infiltration based on the relative length between overland flow time of concentration and percolation travel time in soil water zone and by computing time of concentration varying with the amount of surface flow. The modified SWAT was applied to the Chungju dam watershed to assess the increasing effects of daily peak discharges. The daily peaks simulated by the modified SWAT were on average 10% higher than those by original SWAT for the peaks above $5,000m^3/s$. The modified SWAT was found to be able to more accurately reproduce daily peaks, particularly showing increase rates of 9.9%, 18.6% and 12.6%, respectively, for top three peaks that occurred in the years of 1990, 2002, and 2006.

Unusual Waveform Detection Algorithm in Arrhythmia ECG Signal (부정맥 심전도 신호에서 특이 파형 검출)

  • Park, Kil-Houm;Kim, Jin-Sub;Ryu, Chunha;Choi, Byung-Jae;Kim, Jungjoon
    • Journal of the Korean Institute of Intelligent Systems
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    • v.23 no.4
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    • pp.292-297
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    • 2013
  • In this paper, unusual waveform detection algorithm based on Refractory Period in arrhythmia ECG signal is proposed. Most of arrhythmia ECG signals consist of unusual waveforms with average 10% rate. Thus tremendous benefit can be obtained in terms of time and cost by providing unusual waveform samples reduced more than 90% to medical staffs who have to monitor and analyze for a long time. The proposed algorithm detects the R-peak using the features of R wave and variable refractory period. For the detected R-peak, unusual waveforms are found using means and standard deviation of electric potential and kurtosis of the R-peaks which are not included in unusual waveform. The proposed algorithm was applied to all records of the MIT-BIH arrhythmia database and showed more than average 90% of compression ratio.

H2S Adsorption Characteristics of KOH Impregnated Activated Carbons (KOH 첨착 활성탄에서 황화수소의 흡착 특성)

  • Choi, Do-Young;Jang, Seong-Cheol;Gong, Gyeong-Tack;Ahn, Byoung-Sung;Choi, Dae-Ki
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.280-285
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    • 2006
  • Adsorption characteristics of $H_{2}S$ on KOH impregnated activated carbon were evaluated using dynamic adsorption method in a fixed bed. The pore properties, including BET's specific surface area, pore volume, pore size distribution, and mean pore diameter of these KOH impregnated activated carbons, were characterized from $N_{2}$ adsorption/desorption isotherms. Adsorption equilibrium data were correlated with Langmuir and Freundlich isotherms. The adsorption of $H_{2}S$ onto the KOH impregnated activated carbon is better fitted by the Langmuir isotherm. An increase in the content of oxygen affects the performance of KOH impregnated activated carbon to the greatest extent.

Chitinase Activity and Textural Property of Leek Added Kimchi During Fermentation (부추첨가 김치의 발효과정 중 chitinase 활성과 조직감)

  • 김유경;이귀주
    • Korean journal of food and cookery science
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    • v.15 no.2
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    • pp.102-107
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    • 1999
  • Several ingredients of kimchi including chinese cabbage, garlic, leek, big green onion, and small green onion were assayed for their chitinase activities. Kimchi with various leek contents (4, 8, 12%) were fermented at 15$^{\circ}C$ for 9 days and the chitinase (EC 3.2.1.14) activity and textural properties were determined. The chitinase activity of the ingredients was in the order of garlic>leek>small green onion>chinese cabbage>big green onion. During fermentation, the chitinase activity of kimchi juice appeared more prominent than that of kimchr tissue, however, it was decreased in all kimchi samples among which the control sample showed a remarkable drop. The activity of chitinase in kimchi tissue increased until 3rd or 5th day of fermentation and then decreased. The puncture force of all kimchi samples decreased and those of leek-added kimchi were higher than those of control. The above results suggested that the addition of leek for kimchi preparation could contribute to the improvement of textural qualities of kimchi due to chitinase activities of leek during fermentation.

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Particle Shapes and Optical Property of Synthesized ZnO with Amine Additives (아민첨가제를 사용하여 합성된 ZnO의 입자형상 및 광학적 특성)

  • Hyeon, Hye-Hyeon;Hyun, Mi-Ho;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.23-29
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    • 2016
  • Zinc oxide of hexagonal wurzite, is known as n-type semiconductor. It has a wide band gap energy of 3.37 eV and large exciton binding energy of 60 meV. It can be widely applied to gas sensors, laser diodes, dye-sensitized solar cells and degradation of dye waste. The use of microwave hydrothermal synthesis brings a rapid reaction rate, high yield, and energy saving. Amine additives control the different particle shapes because of the chelate effect and formation of hydroxide ion. In this study, zinc nitrate hexahydrate was used as zinc precursor. In addition, ethanolamine, ethylenediamine, diethylenetriamine, and hexamethylenetetramine are used as shape control agent. The pH value was controlled as 11 by NaOH. The shapes of zinc oxide are star-like, rod, flower-like, and circular cone. In order to analyze physical, chemical, and optical properties of ZnO with diverse amine additives, we used XRD, SEM, EDS, FT-IR, UV-Vis spectroscopy, and PL spectroscopy.

R-wave Detection Algorithm in ECG Signal Using Adaptive Refractory Period (ECG 신호에서 적응적 불응기를 이용한 R-wave 검출 알고리즘)

  • Kim, Jung-Joon;Kim, Jin-Sub;Park, Kil-Houm
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.5
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    • pp.242-250
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    • 2013
  • In this paper, R-wave detection algorithm using refractory period to reflect the depolarization and repolarization of the myocardial cells of the heart is proposed. The proposed algorithm detects R-peaks using the features of R-wave and variable refractory period. First, the proposed algorithm extracts candidate R-peaks that have a relatively high potential and calculates the refractory period based on the kurtosis and potential for candidate R-peaks. Next, R-peak is determined by morphological features of the R-wave within the refractory period. In addition, due to less computation in the proposed algorithm, real-time processing is possible. The algorithm is applied to all records of the MIT-BIH arrhythmia database and the obtained results show a competitive detection rate of over 99.7%.

Distribution fitting for the rate of return and value at risk (수익률 분포의 적합과 리스크값 추정)

  • Hong, Chong-Sun;Kwon, Tae-Wan
    • Journal of the Korean Data and Information Science Society
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    • v.21 no.2
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    • pp.219-229
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    • 2010
  • There have been many researches on the risk management due to rapid increase of various risk factors for financial assets. Aa a method for comprehensive risk management, Value at Risk (VaR) is developed. For estimation of VaR, it is important task to solve the problem of asymmetric distribution of the return rate with heavy tail. Most real distributions of the return rate have high positive kurtosis and low negative skewness. In this paper, some alternative distributions are used to be fitted to real distributions of the return rate of financial asset. And estimates of VaR obtained by using these fitting distributions are compared with those obtained from real distribution. It is found that normal mixture distribution is the most fitted where its skewness and kurtosis of practical distribution are close to real ones, and the VaR estimation using normal mixture distribution is more accurate than any others using other distributions including normal distribution.