• Title/Summary/Keyword: 철입자

Search Result 625, Processing Time 0.029 seconds

Preparation and Characterization of Unsaturated Poly(3-hydroxyalkanoate) Nanoparticles (불포화 폴리히드록시알칸오에이트 나노입자의 제조 및 특성)

  • 한정현;김승수;신병철;이영하;홍성욱
    • Polymer(Korea)
    • /
    • v.27 no.6
    • /
    • pp.542-548
    • /
    • 2003
  • Nanoparticles with unsaturated poly(hydroxyalkanoate)s (UPHAs) biosynthesized with Pseudo-monas oleovorans were prepared by spontaneous emulsification solvent diffusion method. The influence of nanoparticle formation was investigated with various experimental parameters such as sonication conditions, sol-vent, surfactant and polymer contents, etc. The physical and chemical properties of UPHAS and its nanoparticles were characterized using $^1$H- and $\^$13/C-nuclear magnetic resonance spectroscopies, attenuated total reflection infrared spectroscopy, differential scanning calorimetry and gel permeation chromatography. The morphology of particles was observed using scanning electron microscope and the size and distribution of nanoparticles were measured with electrophoretic light scattering spectrophotometer. The mean diameter of particles decreased with increasing sonication amplitude and time. The addition of ethanol into UPHAS chloroform solution decreased the particle size presumably due to increased solvent diffusion into water phase. The particle size increased with increased the concentration of UPHAS solution. Under the 2-4% poly(vinyl alcohol) (PVA) aqueous solution the minimum mean diameter of particles was shown. The higher degree of hydrolysis and degree of polymerization of PVA increased the mean diameter of particles.

An update technology trend in iron oxide (산화철산업(酸化鐵産業)의 개발동향(開發動向))

  • Sohn, Jin-Gun
    • Proceedings of the Korean Institute of Resources Recycling Conference
    • /
    • 2005.11a
    • /
    • pp.47-58
    • /
    • 2005
  • From the world wide globalization of iron oxide industy, the global trade in iron oxide is changed rapidly and the production of iron oxide is increasing in China, currently. Iron oxide have a broad range of applications from construction materials to medical area. Therefore, it is expected that nanoparticulate iron oxides have many applications, too. There is a series of interesting applications are introduced, but in entirely different fields as they are known from conventional iron oxide.

  • PDF

Microbial Synthesis of Cobalt-Substituted Magnetite Nanoparticles by Iron Reducing Bacteria (미생물을 이용한 나노입자의 코발트로 치환된 자철석의 합성)

  • Yul Roh;Hi-Soo Moon
    • Journal of the Mineralogical Society of Korea
    • /
    • v.14 no.2
    • /
    • pp.111-118
    • /
    • 2001
  • The use of bacteria as a novel biotechnology to facilitate the production of nanoparticles is in its infancy. Cobalt-substituted magnetite nanoparticles were synthesized by a thermophilic iron(III)-reducing bacterium, TOR-39, under anaerobic conditions using amorphous Fe(III) oxyhydroxides plus cobalt ( $Co^{2+}$ and $Co^{3+}$ ) as an electron acceptor and organic carbon as an electron donor. Microbial processes produced copious amounts of nm-sized cobalt substituted magnetites. Chemical analysis and X-ray powder diffraction analysis showed that cobalt was substituted into biologically facilitated magnetites. Microbially facilitated synthesis of the cobalt-substituted magnetites may expand the possible use of the specialized ferromagnetic particles.

  • PDF

Structure and Experimental Results of Automatic Insulation Greenhouse (자동단열온실의 구조 및 운전특성)

  • 이종원;이석건;이현우
    • Proceedings of the Korean Society for Bio-Environment Control Conference
    • /
    • 1994.05a
    • /
    • pp.88-91
    • /
    • 1994
  • 최근 국내에서도 시설원예가 급격하게 보급되고 있는 실정이다. 하지만, 시설원예가 에너지 소비형의 농경방식이라 지적되고 있는바 에너지절약형 온실의 개발이 필요할 것으로 판단되어, 본 실험실에서는 본 연구와 관련하여 비닐하우스의 벽체를 이중으로 하여 이중벽사이에 단열입자를 송풍기의 케이싱내로 직접 통하게하는 직송방식으로 충전ㆍ회수하는 실험을 실시한 바가 있으며, 그 결과 외기온의 평균이 -4.9$^{\circ}C$인 겨울철 야간에 입자를 충전한 이중비닐 하우스의 내부온도는 평균 9.8$^{\circ}C$로 단열성이 우수함을 알 수 있었다.(중략)

  • PDF

Magnetic anisotropy of Sr-ferrite powder produced via mechanical alloying (Mechanical alloying법으로 제조한 Sr-ferrite 분말의 자기적 이방성)

  • 배재원;손성우;정국철;황동하;권해웅
    • Proceedings of the Korean Magnestics Society Conference
    • /
    • 2002.12a
    • /
    • pp.90-91
    • /
    • 2002
  • 영구자석 재료용 Sr-ferrite의 제조에 mechanical alloying (기계적 합금화)기술을 적용해서 초미세 결정립으로 구성된 고보자력의 Sr-ferrite를 제조해서 높은 보자력을 실현할 수 있는 것으로 보고하고 있다[1]. 그러나 이 새로운 방법으로 제조한 Sr-ferrite는 높은 보자력을 갖기는 하지만, 대단히 미세한 결정립들이 결합하여 입자를 구성하고 있어 자장을 가해서 입자를 배향시키기가 어렵다. 따라서 이 재료는 등방성 분말로 밖에 이용할 수 없는 결정적인 문제점이 있다. (중략)

  • PDF

Influence of ramp reset pulses on discharge images and luminous efficiency in AC-PDP

  • 안정철
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2000.02a
    • /
    • pp.197-197
    • /
    • 2000
  • AC-PDP의 구동 요소 중 중요한 것은 벽전하와 그로부터 유도되는 벽전압, 그리고 프라이밍입자(priming partical)의 밀도 변화라고 할 수 있다. 패널의 초기화가 전구간의 방전을 좌우하기 때문에 초기화 펄스의 기울기에 따른 방전현상을 이해하고자 각 구간에서의 전기-광학적 특성과 함께 휘도와 효율의 관점에서 연구 조사하였다. 본 실험에서 사용한 reset 펄스파형은 셀의 방전개시전압과 인가전압사이의 차이가 적고, 초기 프라이밍 입자와 단위시간당 전자에 공급되는 에너지가 적은 램프형태의 초기화 펄스를 사용하였다. 실험장치는 VDS(versatile driving simulator)시스템을 이용하였다. 실험결과 reset의 기울기가 커질수록 반응시간이 빨라지며, 약방전의 형태를 고속이미지로 확인하였다.

  • PDF

Petrological Characteristics and Deterioration phenomena of the rocks consisting the Naju-Dongmunoi-Seogdanggan(Stone Stele) (나주동문외석당간 구성암석의 암석학적 특징과 훼손양상)

  • Lee, Sang-Hun
    • Journal of Conservation Science
    • /
    • v.19
    • /
    • pp.57-66
    • /
    • 2006
  • The rock consisting the Naju-Dongmunoi-Seogdanggan (Stone Stele)(Treasure number 49) is biotite granite of medium to coarse grains which might be taken from nearby area. The rock is mainly composed of quartz, plagioclase, alkali feldspar and biotite. Due to strong weathering grail peel-off and surface exfoliation are well developed. The rock surface is changed into pale brown or pale black colors according to weathering, organism and weathering product of iron band. Major deterioration phenomena are grain peel-off, surface exfoliation, cracks and damage which may be originally classified into weathering, effect of weathering product of iron band, organisms, structural unstabilities and impact.

  • PDF

Preparation of Cellulose Nanoparticles Loaded with Vitamin E Acetate (비타민 E 아세테이트가 봉입된 셀룰로오스 나노입자의 제조)

  • 남다은;정택규;김승수;신채호;신병철
    • Polymer(Korea)
    • /
    • v.28 no.2
    • /
    • pp.128-134
    • /
    • 2004
  • Cellulose nanoparticles loaded with vitamin I acetate were prepared by modified spantaneous emulsification solvent diffusion method. After cellulose derivatives were dissolved in mixed acetone/ethanol organic solvent with vitamin E acetate, cellulose nanoparticle suspensions were dispersed in poly(oxyethylene sorbitane monooleate) solution using ultrasonicator. Particle size and loading amount of vitamin I acetate were measured by particle size analyser and UV-spectrometer, respectively. The stability of nanoparticle was determined by measuring the change of the particle size at room temperature for 30 days and the morphology was observed by SEM. Morphology of cellulose nanoparticles was spherical and particle size was not changed at room temperature for 30 days. The optimum condition for the preparation of cellulose nanoparticles was 1% w/v cellulose nitrate with 8% w/v poly(oxyethylene sorbitane monooleate) solution. It showed that particle size and loading amount of vitamin E acetate was 65nm and 71%, respectively.

Photoelectrochemical Performance of Hematite Nanoparticles Synthesized by a DC Thermal Plasma Process (DC 열플라즈마를 이용하여 제조된 산화철 나노입자의 광 전기화학적 물분해 효율 증가연구)

  • Lee, Chulho;Lee, Dongeun;Kim, Sunkyu;Yoo, Hyeonseok;Choi, Jinsub
    • Applied Chemistry for Engineering
    • /
    • v.26 no.3
    • /
    • pp.306-310
    • /
    • 2015
  • In this research, hematite nanoparticles were synthesized by DC thermal plasma process to increase the overall surface area. The effect of binders on hematite electrodes was investigated by changing the type and composition of binders when preparing electrodes. Nitrogen gas was also added to the DC thermal plasma process in order to dope the hematite with N for enhancing photoelectrochemical properties of hematite nanoparticles. The efficiency of water splitting reaction was measured by linear sweep voltammetry (LSV) under solar simulator. In LSV measurements, the onset potential and maximum current density at a fixed voltage were measured. The durability of electrodes was checked by repeating LSV measurements. CMC (carboxymethyl cellulose) binder with 50 : 1 composition exhibits the highest current density of $12mA/cm^2$ and CMC binder with 20 : 1 composition, showing the initial current density of $3mA/cm^2$, endures 20 times of repetitive LSV measurements. Effects of nitrogen doping on hematite nanoparticles were proven to be insignificant.