• Title/Summary/Keyword: 철(II)

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매복지치 (II)

  • Lee, Sang-Cheol;Kim, Yeo-Gap
    • The Journal of the Korean dental association
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    • v.15 no.9
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    • pp.724-727
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    • 1977
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Characteristics of the TCE removal in FeO/Fe(II) System (FeO/Fe(II) 시스템에서 TCE의 제거 특성)

  • Sung, Dong Jun;Lee, Yun Mo;Choi, Won Ho;Park, Joo yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.1B
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    • pp.149-152
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    • 2008
  • The reaction between iron oxide and ferrous iron is known to be the adsorption of ferrous iron onto the oxide surfaces that produces Fe(II)-Fe(III) (hydr)oxides and ferrous oxide oxidized to ferric ion which is the reducing agent of the target compounds. In our investigations on DS/S using ferrous modified steel slag, the results did not follow the trends. FeO and Fe(II), the major component of steel slag, were used to investigate the degradation of TCE. Degradation did not take place for the first and suddenly degraded after awhile. Degradation of TCE in this system was unexpected because Fe(II)-Fe(III) (hydr)oxides could not be produced in absence of ferric oxide. In this study, the characteristics of FeO/Fe(II) system as a reducing agent were observed through the degradation of TCE, measuring byproducts of TCE and the concentration of Fe(II) and Fe(III). Adsorption of ferrous ion on FeO was observed and the generation of byproducts of TCE showed the degradation of TCE by reduction in the system is obvious. However it did not correspond with the typical reducing mechanisms. Future research on this system needs to be continued to find out whether new species are generated or any unknown mineral oxides are produced in the system that acted in the degradation of TCE.

Oxidation of a substrate by O2 in Fe(II) catalysis for the reversible oxidation effected by heme (헴에 의한 가역산화 때문에 철(II) 촉매에서 산소에 의한 기질의 산화)

  • Lee, Yong-Hee;Park, Bong-Jin;Suh, Myung-Gyo;Lee, Young-Sei
    • Journal of the Korean Society of Industry Convergence
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    • v.6 no.4
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    • pp.347-353
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    • 2003
  • Fe(II)하에서 분자산소에 의한 기질의 산화는 헴에 의해 나타난 가역산화반응에 의해서 대단한 생물학적 흥미가 있다. 적당한 조건하에서 산화되어진 리간드로서 염인 피리딘이나 아마이드, 그리고 두 가지 종류의 Fe(II)-acac나 Fe(II)-sal의 complex와 산화되는 기질의 성질이 비라디칼 조건하에서 안정하다는 것을 알았다.

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IMPLEMENTATION OF MPEG-II AUDIO ENCODER USING ADSP-21020 (ADSP-21020을 이용한 MPEG-II 오디오 인코더의 구현)

  • Kim, Jae-Young;Lee, Byung-Chul;Lee, Key-Seo;Chung, Chin-Hyun
    • Proceedings of the KIEE Conference
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    • 1995.07b
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    • pp.977-979
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    • 1995
  • MPEG-II is the international standard of compression for digital image and digital audio that is the most important in the multimedia environment. Now many researchers are developing relevant systems. MPEG-II consists of video, audio, system and the other part. In this paper, we have designed and demonstrated two channel audio encoder system that processes the audio compression part, and excutes layer II for complexity and psychoacoustic model II, with ADSP-21020 of Analog Device.

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The Skarnification and Fe-Mo Mineralization at Lower Part of Western Shinyemi Ore Body in Taeback Area (태백지역 신예미 서부광체 하부의 스카른화작용 및 철-몰리브덴 광화작용)

  • Seo, Ji-Eun;Kim, Chang-Seong;Park, Jung-Woo;Yoo, In-Kol;Kim, Nam-Hyuck;Choi, Seon-Gyu
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.1 s.51
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    • pp.35-46
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    • 2007
  • Shinyemi skarn deposits occur as Fe-Mo skarn type and Pb-Zn-Cu hydrothermal replacement type along the contact between Cretaceous Shinyemi granitoids and Cambro-Ordovician mixed limestone and dolostone sequence of the Choseon Supergroup. In the lower part of Western Shinyemi ore body two stages of skarn formation have been observed: the early, stage I (magnesian) skarn with Fe mineralization and the late, stage II(calcic) skarn with Mo mineralization. The stage I skarn spatially is overprinted by stage II skarn. The stage I skarn is predominantly composed of olivine, magnetite and diopside whereas, the stage II skarn is dominated by hedenbergite and garnet. The skarnification process occurred in two stages, both prograde and retrograde for stage I and stage II skarns. In stage I, the prograde skarns, mainly composed of anhydrous silicate minerals, were formed at relatively higher temperatures (about $400\;to\;550^{\circ}C$) under low $CO_{2}$ fugacity ($X_{CO2}<0.1$) conditions. On the other hand, the retrograde skarns that consisted of hydrous minerals were formed at lower temperatures (about $300\;to\;400^{\circ}C$).

Nitrate Reduction without Ammonium Release using Fe-loaded Zeolite

  • Lee Seunghak;Lee Kwanghun;Lee Sungsu;Park Junboum
    • Journal of Soil and Groundwater Environment
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    • v.10 no.1
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    • pp.1-5
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    • 2005
  • Nitrate reduction with zero valent iron $(Fe^0)$ has been extensively studied, but the proper treatment for ammonium byproduct has not been reported yet. In groundwater, however, ammonium is regarded as contaminant species, and particularly, its acceptable level is regulated to 0.5 mg-N/L. for drinking water. This study is focused on developing new material to reduce nitrate and properly remove ammonium by-products. A new material, Fe-loaded zeolite, is derived from zeolite modified by Fe(II) chloride followed by reduction with sodium borohydride. Batch experiments were performed without buffer at two different pH to evaluate the removal efficiency of Fe-loaded zeolite. After 80 hr reaction time, Fe loaded zeolite showed about $60\%$ nitrate removal at initial pH of 3.3 and $40\%$ at pH of 6 with no ammonium release. Although iron filing showed higher removal efficiency than Fe-loaded zeolite at each pH, it released a considerable amount of ammonium stoichiometrically equivalent to that of reduced nitrate. In terms of nitrogen species including $NO_3-N$ and $NH_4^+-N$, Fe-loaded zeolite removed about $60\%\;and\;40\%$ of nitrogen in residual solution at initial pH of 3.3 and 6, respectively, while the removal efficiency of iron filing was negligible.

Preparation of Cobalt-Substituted Iron Oxide Powder from Organometallic Precursors (Ⅱ) (유기금속 전구체로부터 코발트 치환 산화철 분말 제조 (Ⅱ))

  • Kim, Jeong Su;Gang, Han Cheol;Hong, Yang Gi
    • Journal of the Korean Chemical Society
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    • v.38 no.2
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    • pp.92-100
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    • 1994
  • Ultrafine cobalt-substituted iron oxide particles were prepared by the thermal decomposition and oxidation of the new organometallic precursor, $Co_xFe_{1-x}(N_2H_3COO)_2(N_2H_4)_2$ (x = 0, 0.01, 0.02, 0.03, 0.05, 0.10, 1.00). The organometallic precursors were synthesized by the reaction of Co(II) and Fe(II) ion in a mole ratio of x : 1-x with hydrazinocarboxylic acid, and characterized by quantitative analysis, elemental analysis and infrared spectroscopy. The mechanistic study on the thermal decomposition of the organometallic precursors was performed by TG-DTG and DSC. The cobalt-substituted iron oxide particles were obtained by the heat treatment of the precursors at $350^{\circ}C$ and $450^{\circ}C$ for six hours in air. The prepared iron oxide was found to have two phases such as ${\gamma}-Fe_2O_3$ and a mixture of ${\gamma}-Fe_2O_3\;and\;{\alpha}-Fe_2O_3$ at $350^{\circ}C$ and $450^{\circ}C$ respectively. The particle shape was equiaxial and the particle size was less than 0.05 ${\mu}m.$ The coercivity and squareness of the cobalt substituted iron oxide particles increased with increasing cobalt content. Both coercivity and squareness showed higher values at $450^{\circ}C.$

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